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921.
Validation of a European standard for the determination of hexavalent chromium in solid material 总被引:1,自引:0,他引:1
Tirez K Scharf H Calzolari D Cleven R Kisser M Lück D 《Journal of environmental monitoring : JEM》2007,9(7):749-759
A European standard for the determination of Cr(vi) in solid material has been elaborated in the framework of an international co-operation and finally validated in the course of an interlaboratory comparison. The procedure is based on the alkaline digestion prescribed by EPA method 3060A followed by ion chromatography and determines an operationally defined content of Cr(vi), including water-soluble and insoluble chromates. A preliminary robustness study was carried out in order to compare different extraction methodologies and to study the equivalency of different analytical methods for the determination of Cr(vi) in alkaline extracts of soil and waste materials. During an interlaboratory validation trial with 19 European laboratories a set of 4 samples (2 soil and 2 waste samples) was analysed to determine performance characteristics for different combinations of digestion and detection methods. With the procedures prescribed by the new European standard (EN 15192) acceptable results were obtained for both soil samples and one of the waste samples (sludge). However, for the second waste sample (fly ash) a large deviation in analytical results was observed. This indicates that particularly for waste materials a possible occurrence of strong matrix effects has to be considered and supplementary quality control data are needed in order to assess the validity of analytical results. The accuracy of the determination of Cr(vi) in solid matrices remains a challenging field in terms of maximum extraction efficiency and minimum species interconversion. 相似文献
922.
Schröder W Hornsmann I Pesch R Schmidt G Markert B Fränzle S Wünschmann S Heidenreich H 《Environmental monitoring and assessment》2007,133(1-3):495-505
The study was conducted to test the hypothesis that the regional variability of nitrogen (N) and metal accumulations in terrestrial ecosystems are due to historical and recent ways of landuse. To this end, two regions of Central Europe were selected for investigation: the Weser-Ems Region (WER) and the Euro Region Nissa (ERN). They were assumed to have land use-specific accumulation profiles. Thus, the metal and N accumulations in both regions were examined by means of geostatistically based comparative moss analysis. The sampling and chemical analysis of mosses were conducted in accordance with the convenient guidelines and methods, respectively. The spatial representativity of the sampling sites was computed by means of a land classification which was calculated for Europe by means of classification trees and GIS-techniques. The differences of deposition loads were tested for statistical significance with regard to time and space. The measurement values corroborated the decline of metal accumulation observed since the beginning of the European Metals in Mosses Surveys in 1990. The metal loads of the mosses in the ERN exceeded those in the WER significantly. The opposite holds true for the N concentrations: those in the WER were significantly higher than those in the ERN. The reduction of emissions from power plants, factories and houses was strongly correlated with the decline of deposition and bioaccumulation of metals. As proved by the European Metals in Mosses Surveys, this tendency is due to successful environmental policies. But no such success could be verified by monitoring the accumulation of N in mosses. 相似文献
923.
T. Lubjuhn Wolfgang Winkel Jörg Thomas Epplen Jörg Brün 《Behavioral ecology and sociobiology》2000,48(1):12-17
One of the most interesting aspects of the mating system of pied flycatchers is the regular occurrence of polygyny. Here we
present data on the reproductive success of polygynously paired pied flycatcher males compared to monogamous males based on
paternity analyses through DNA fingerprinting. Males paired with two females suffered a higher loss in reproductive output
per female compared to monogamous males due to (1) a greater proportion of unhatched eggs in their broods, (2) greater nestling
mortality and (3) a greater probability of being cuckolded. Nevertheless, the number of fledglings was significantly greater
for polygynous males. Based on the number of nestlings that returned for subsequent breeding seasons, however, the reproductive
success of monogamous and polygynous males did not differ significantly. These data raise the question as to why males attempt
polygyny.
Received: 16 August 1999 / Received in revised form: 15 March 2000 / Accepted: 18 March 2000 相似文献
924.
Jürgen Warrelmann Hartmut Kochler Tobias Frische Ingo Dobner Ulrich Walter Wolfgang Heyser 《Environmental Sciences Europe》2000,12(6):351-357
On the area of a former ordnance plant (‘Werk Tanne’, Clausthal-Zellerfeld, Germany), a field experiment for phytoremediation of TNT-contaminated soils has been carried out since May 1999. The concept is based on a stepwise degradation of TNT by white-rot fungi and mycorrhiza within the rhizosphere of site-specific seedlings. An appropiate site with contaminants in the surface-soil was prepared with a large-scale soil grader and subsequently divided into different experimental plots, including an uncontaminated control as well as a contaminated plot without treatment. Planting of the selected trees and shrubs (infected with mycorrhiza during nursery) and inoculation with wood chips (inoculated with white-rot fungi) is followed by a detailed monitoring of the experimental plots (chemical analyses, biotest-battery, ecological field indicators). For the evaluation of the results, multivariate methods are applied. 相似文献
925.
The fermentation activity of the yeastSaccharomyces cerevisiae is used as a bioindicator to detect aquatoxic effects. This is done by measuring the CO2 production of yeast cells after a multiplication period affected by toxic substances. The concentration of toxicants diminishing the fermentation by 20% is taken as a characteristic value (EC20). Organic compounds (unpolar and polar narcotics), inorganic salts (especially of heavy metals), surfactants and plant pesticides were tested. The results are compared so far as available with data of a ciliata assay usingTetrahymena pyriformis. A congruence of 90% and an equal sensibility of the assays resulted. The results of the yeast assay are therefore representative for ecotoxicological testing. The yeast assay is reproducible, easy to handle, and offers an alternative for sewage testing because sterile handling is not necessary. 相似文献
926.
Maternal investment in rhesus macaques (Macaca mulatta): reproductive costs and consequences of raising sons 总被引:1,自引:0,他引:1
Maternal investment in offspring is expected to vary according to offspring sex when the reproductive success of the progeny
is a function of differential levels of parental expenditure. We conducted a longitudinal investigation of rhesus macaques
to determine whether variation in male progeny production, measured with both DNA fingerprinting and short tandem repeat marker
typing, could be traced back to patterns of maternal investment. Males weigh significantly more than females at birth, despite
an absence of sex differences in gestation length. Size dimorphism increases during infancy, with maternal rank associated
with son’s, but not daughter’s, weight at the end of the period of maternal investment. Son’s, but not daughter’s, weight
at 1 year of age is significantly correlated with adult weight, and male, but not female, weight accounts for a portion of
the variance in reproductive success. Variance in annual offspring output was three- to fourfold higher in males than in females.
We suggest that energetic costs of rearing sons could be buffered by fetal delivery of testosterone to the mother, which is
aromatized to estrogen and fosters fat accumulation during gestation. We conclude that maternal investment is only slightly
greater in sons than in daughters, with mothers endowing sons with extra resources because son, but not daughter, mass has
ramifications for offspring sirehood. However, male reproductive tactics supersede maternal investment patterns as fundamental
regulators of male fitness.
Received: 23 July 1999 / Received in revised form: 23 February 2000 / Accepted: 13 March 2000 相似文献
927.
R. Wilson G. Peters J. Regel D. Grémillet K. Pütz M. Kierspel H. Weimerskirch J. Cooper 《Marine Biology》1998,130(4):559-566
Stomach temperature loggers have proved useful for the study of feeding activity in free-living seabirds, but their usage
has been restricted because they are frequently dislodged and lost during the seabirds' regular regurgitation of indigestible
prey remains. In the present study we examine the incidence of spontaneous regurgitation (pellet production) in free-living
seabirds, consider the effect this has on the likely retrieval of stomach temperature loggers and present a structural modification
of the logger housings which leads to a much lower incidence of regurgitation. Systems were tested on albatrosses, cormorants,
gannets and penguins.
Received: 15 July 1997 / Accepted: 31 October 1997 相似文献
928.
Jürgen Gadau Pia J. Gertsch Jürgen Heinze Pekka Pamilo Bert Hölldobler 《Behavioral ecology and sociobiology》1998,44(1):23-33
Multilocus DNA fingerprinting and microsatellite analysis were used to determine the number of queens and their mating frequencies
in colonies of the carpenter ant, Camponotus ligniperdus (Hymenoptera: Formicidae). Only 1 of 61 analyzed queens was found to be double-mated and the population-wide effective mating
frequency was therefore 1.02. In the studied population, 8 of 21 mature field colonies (38%) contained worker, male, or virgin
queen genotypes which were not compatible with presumed monogyny and therefore suggested oligogyny, i.e., the cooccurrence
of several mutually intolerant queens within one colony. Estimated queen numbers in oligogynous colonies ranged between two
and five. According to the results of the genetic analysis, most of the queens coexisting in oligogynous colonies were not
closely related. Pleometrosis is very rare and queenless colonies adopt mated queens both in the laboratory and field. Therefore,
the most plausible explanation for the origin of oligogynous colonies in C. ligniperdus is the adoption of unrelated queens by orphaned mature colonies. The coexistence of unrelated, but mutually intolerant queens
in C. ligniperdus colonies demonstrates that oligogyny should be considered as a phenomenon distinct from polygyny.
Received: 18 December 1997 / Accepted after revision: 20 June 1998 相似文献
929.
In dune slacks in The Netherlands, a decline of rare mesotrophic basiphilous plant species and their plant communities has
been observed in combination with an increase of more productive systems with common, taller acidophilous plant species. This
has been attributed to both natural and anthropogenic changes. In a humid climate with a precipitation surplus, as in The
Netherlands, the calcium carbonate content of a calcareous soil increases with depth. However, soils in coastal dune slacks,
may have a higher carbonate content in the topsoil horizon than in the underlying layers. Carbonates which buffer the pH can
prolong the presence of mesotrophic basiphilous plant communities which are of high conservation value.
To explain the occurrence of calcareous surface horizons in dune slacks, hydrological and micromorphological analyses were
carried out in three dune slacks. Two slacks are situated on the Wadden Sea islands in the northern part of The Netherlands;
one on Schiermonnikoog and one on Texel. The third slack is situated in the dunes on the island of Goeree in the southwestern
part of The Netherlands. In all three slacks, carbonate occurs as mollusc and gastropod fragments (silt- or sand-sized) and
as micritic nodules in the topsoil layer, due to aeolian deposition and sedimentation by water.In situ carbonate accumulation (calcitans and calcareous crusts) due to CO2 release in inundated and/or capillary rise of calcareous groundwater near, or at the soil surface. Accumulation of carbonate
also occurs as a result of biological activity by algae in the topsoil of the Goeree site. In general, hydrological processes
maintaining high levels of calcareous groundwater are a prerequisite for the maintenance of high carbonate levels in topsoils.
Such levels are necessary for the conservation and management of basiphilous pioneer vegetation. 相似文献
930.