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11.
Dust-particle migration around flotation tailings ponds: pine needles as passive samplers 总被引:1,自引:0,他引:1
Teper E 《Environmental monitoring and assessment》2009,154(1-4):383-391
The potential use of dust particles trapped on Scots pine needles for tracking dust migration around flotation tailings ponds in the Silesian-Krakowian ore district, Southern Poland was tested. 1-, 2- and 3-years old needles were studied using a scanning electron microscope and energy dispersive X-ray microanalysis. Particle sizes and morphologies, and the nature of the compounds hosting metals ions, were examined. A large majority of the particles examined are <10 microm in size. Almost 80% of particles represent respirable dust. All the components in the flotation wastes appear among the chemical compounds identified in particles on the pine needles. The quantity of the waste particles decreases with distance from the flotation tailings ponds. The analysis of dust particles on pine needles could be a useful method for estimating vectors and travel distances of suspended dust migrating around open flotation tailings ponds and around other point sources emitting dust particles with chemical compositions differing from the environmental background. 相似文献
12.
Mikołaj Urbanowski Paweł Socha Paweł Dąbrowski Wioletta Nowaczewska Anna Sadakierska-Chudy Tadeusz Dobosz Krzysztof Stefaniak Adam Nadachowski 《Die Naturwissenschaften》2010,97(4):411-415
An upper second permanent molar from a human was found alongside numerous tools of the Micoquian tradition and was excavated
in Stajnia Cave, which is located over 100 km North of the Carpathian Mountains in southern Poland. The age of these finds
has been established within a time-span of late Saalian to early Weichselian, most likely to OIS 5c or 5a, according to the
palaeontological, geological, archaeological and absolute dating of the layer from which they were obtained. An examination
of the morphology of the human molar indicates that this tooth exhibits many traits frequently occurring in Neanderthal upper
molars. Although the occurrence of derived Neanderthal traits in the Stajnia molar cannot be firmly established because of
degradation of its cusps, the presence of the above-mentioned features allows the assertion that this tooth belonged to a
Neanderthal. The age of the Stajnia tooth and the archaeological context of this find also indicate that this molar is of
Neanderthal origin. 相似文献
13.
Because they are used in a number of commercial preparations phenoxyacetic acids and their salts can occur in wastewater. During their degradation genotoxic substances may be created. The results of investigations of biodegradability and genotoxicity of some phenoxyherbicides are presented. Commercial formulations of 2,4-D (Aminopielik 720) and MCPA (Chwastox Extra) were the substrates studied. Biodegradation tests were conducted according to OECD guidelines for testing of chemicals--confirmatory test (OECD Method 303 A). Genotoxicity tests were conducted with Bacillus subtilis strains according to the method of [Chemical Mutagens, vol. 6, Plenum Press. New York, 1980, p. 149]. Genotoxicity of biodegradation products was also studied. Both commercial formulations were biodegradable. Aminopielik 720 was potentially genotoxic but only at great concentrations while Chwastox Extra was not genotoxic. Biodegradation products of neither compound were genotoxic. 相似文献
14.
Small effects of a large sediment contamination with heavy metals on aquatic organisms in the vicinity of an abandoned lead and zinc mine 总被引:1,自引:0,他引:1
Dariusz Ciszewski Urszula Aleksander-Kwaterczak Agnieszka Pociecha Ewa Szarek-Gwiazda Andrzej Waloszek Elżbieta Wilk-Woźniak 《Environmental monitoring and assessment》2013,185(12):9825-9842
The effects of the long-term contamination of water reservoirs with mine effluents were investigated at an abandoned mine site in Upper Silesia, southern Poland. The studies covered metal content and mobility in bottom sediments as well as water chemistry in relation to the content of metals in selected macrophytes and their physiology and the composition of phyto- and zooplankton communities. Although it is 40 years since mining ceased, reservoir sediments are still heavily contaminated with cadmium, zinc and lead with concentrations (mg/kg), which vary roughly between 130–340, 10,000–50,000 and 4,000–12,000, respectively. About 50–80 % of these elements are associated with the reducible phase, and only a small percentage, <10 %, is present in the most mobile exchangeable phase. Despite the high total metal concentration in sediments, their content in the submerged plants Myriophyllum spicatum and the emerged plants Phragmites australis was low. The observed effects of heavy metal contamination on photosynthetic activity in the leaves of P. australis were negligible, whereas those in M. spicatum show up only as a difference in the distribution of photosynthetic activity in leaves of different ages, which seems to be related to the very good water quality and to the generally small concentrations of metals in pond water. The physicochemical properties of water also seem to control the presence of planktonic species more than does sediment contamination. However, a shift toward groups of species known to be more resistant to heavy metals (diatoms, green algae and Rotifera) indicates some adaptative changes related to the long-lasting contamination of ponds. 相似文献
15.
Barbara Zielinska Eric Fujita John Sagebiel Greg Harshfield Ewa Uberna Terry Hayes 《Journal of the Air & Waste Management Association (1995)》2013,63(11):1038-1050
ABSTRACT In order to evaluate the existing risk to public health in Arizona related to hazardous air pollution, ambient air monitoring for selected hazardous air pollutants (HAPs) was carried out in 1994-1996 in several representative urban and rural areas of Arizona. A wide range of organic HAPs was monitored, requiring a variety of sampling and analysis methods. Stainless steel SUMMA canisters were used for collection of volatile hydrocarbons and halocarbons, which were analyzed by capillary gas chromatography with flame ionization and electron capture detection (GC-FID/ECD). Carbonyl compounds were collected using 2,4-dinitrophenylhydrazine-impregnated cartridges and analyzed by high performance liquid chromatog-raphy with ultraviolet detection. Semi-volatile and non-volatile polycyclic aromatic compounds were collected using a sampling train consisting of a filter followed by a PUF/XAD-4/PUF sandwich cartridge. Following extraction, samples were analyzed by capillary GC with mass spectrometric detection (GC-MS). Database software was developed for data processing and reporting functions. This paper describes the sampling strategy and the sampling and analysis methods employed in the monitoring program and presents a summary of all the results obtained during the duration of the sampling program. 相似文献
16.
The spin trapping technique with electron paramagnetic resonance (EPR) detection of spin adducts was applied for the investigation of the reaction of hydroxyl radicals, generated by the photolysis of hydrogen peroxide, with bicarbonate and carbonate anions. The results have been compared with those obtained for aqueous solutions of hydrogen peroxide as well as solutions containing phosphate buffers at pH values identical with those of the carbonate, and bicarbonate solutions. Both the carbonate, and bicarbonate anions quenched the hydroxyl radicals more efficiently than phosphate buffers. The effect depended on the anion concentrations, and it was most pronounced in the presence of carbonate. Rate constants for the reaction of OH with the investigated anions have been calculated. They are very close to values reported in the literature, obtained using optical detection of the carbonate and phosphate radicals. 相似文献
17.
The investigations were made to determine the total contents of Fe, Mn, Zn, Cu, Pb, Cd, Ni and Cr in the roadside soils and rocks of the Sierra Nevada Mountains in Spain. There were differences in both the age and lithology of the bed-rock in the study area. The surface soil layer is primarily enriched with lead in relation to the bed-rock, but zinc, manganese, and cadmium also occur.Lead, zinc and cadmium concentrations show a decrease with increasing distance from the road, whereas the levels of iron, manganese, copper, nickel and chromium do not show such a variation. The change in lead and zinc concentrations with increasing distance from the road is related to the topography of the area immediately adjacent to the road. On the descending slopes the concentrations of these metals remain unchanged or increase with the increasing distance from the road, whereas on the ascending slopes they show a clear decrease. 相似文献
18.
Catecholamines and their metabolites affect children's nervous system. Dopamine is an important neurotransmitter in the brain. In the routine analysis for diagnostics of diseases, the dopamine metabolite homovanillic acid (HVA) is determined. Mercury is a neurotoxic agent and can cause different undesirable effects on the brain. In the present work a putative correlation between HVA, the main metabolite of dopamine, and mercury in urine of healthy and autistic children was studied. The level of HVA was higher in the urine of autistic children (14.5 ± 8.3 mg L?1) compared to generally healthy children (4.4 ± 0.5 mg L?1). The level of mercury in the urine of autistic children was lower (0.36 ± 0.24 µg L?1) than in the urine of healthy children (2.1 ± 1.0 µg L?1) showing that there is no correlation between HVA and mercury. 相似文献
19.
Pollution of water bodies by trace metals is an established problem and several studies have been conducted to deal with it. South Africa is amongst those countries whose water systems are most affected as a result of intensive mining activities. This research was dedicated to the development of an insoluble chelating polymer for use as an adsorbent for abstraction of metal ions from mining and industrial wastewaters. Polyethylenimine (PEI), well known for its metal chelating potential, was cross-linked by epichlorohydrin (ECH) in order to convert it into a water-insoluble form for direct use as an adsorbent. The binding affinity of the cross-linked polyethylenimine (CPEI) to heavy metal ions was assessed as well as its ability to be regenerated for re-use. CPEI exhibited good complexation ability to metal ions with high affinity to Cr and most divalent metal ions. The observed order of complexation was: Cr?>?Zn>?Fe?>?Ni?>?Mn?>?Pb. On the other hand, it showed very poor ability to bind oxo-anions such as SeO3 2? and AsO2 ? which has been attributed to the unavailability of suitable functional groups to interact with these ions. 相似文献
20.
Węgrzyn Magdalena Rudnik Ewa Kamocka-Bronisz Renata Kukfisz Bożena 《Journal of Polymers and the Environment》2021,29(6):1808-1816
Journal of Polymers and the Environment - Biocomposites based on polyethylene from renewable resources derived from sugar cane as raw material were modified with phosphonium ionic liquids.... 相似文献