The effect of export to the deep sea on the long-range transport potential of persistent organic pollutants

Background  

Export to the deep sea has been found to be a relevant pathway for highly hydrophobic chemicals. The objective of this study is to investigate the influence of this process on the potential for long-range transport (LRT) of such chemicals.     

Die Wirkung von Sprengstoffen in Böden einer militärischen Altlast auf die Populationsentwicklung vonFolsomia candida (Willem 1902) (Collembola, Insecta)

The influence of explosive wastes in soil on the reproduction of the springtailFolsomia candida (Willem 1902) (insects of the Order Collembola) was investigated in a standard test according to ISO-Draft-Guideline 11268-2. In the test, we used soils with 3 different contamination levels from an area used for different military purposes (in Hallschlag, Germany), especially for explosive operations, since the beginning of the century. We found different and heterogenous mixtures of contaminants in the soils (primarily TNT and DNT) which resulted in a high mortality rate among the adult insects and in a dramatic reduction in the reproductive potential of the Collembola. In the mixture of contaminants with the highest contamination levels, the total extinction of exposed Collembola was observed as a result of the death of adult insects.     

Effects of acidifying reagents on microwave treatment of dairy manure

Dairy manure, acidified using organic acids (acetic, oxalic, and citric acid) were treated with microwave enhanced advanced oxidation process (MW/H₂O₂-AOP). The effect of a mixture of oxalic acid and commonly used mineral acids (sulfuric and hydrochloric acid) on MW/H₂O₂-AOP was also examined. Substantial amounts of phosphorus were released under MW/H₂O₂-AOP, regardless of organic acid or mineral acid used. All three organic acids were good acidifying reagents; however, only oxalic acid could remove free calcium ion in the solution, and improve settleability of dairy manure. The MW/H₂O₂-AOP and calcium removal process could be combined into a single-stage process, which could release phosphate, solubilize solids and remove calcium from dairy manure at the same time. A mixture of oxalic acid and mineral acid produced the maximum volume of clear supernatant and had an ideal molar ratio of calcium to magnesium for effective struvite (magnesium ammonium phosphate) crystallization process. A single-stage MW/H₂O₂-AOP would simplify the process and reduce mineral acid consumption compared to a two-stage operation. The results of a pilot scale study demonstrate that MW/H₂O₂-AOP is effective in treating manure and recovering resource from dairy farms.     

Opportunity cost based analysis of corporate eco-efficiency: A methodology and its application to the CO2-efficiency of German companies

In this paper, we propose the return-to-cost-ratio (RCR) as an alternative approach to the analysis of operational eco-efficiency of companies based on the notion of opportunity costs. RCR helps to overcome two fundamental deficits of existing approaches to eco-efficiency. (1) It translates eco-efficiency into managerial terms by applying the well-established notion of opportunity costs to eco-efficiency analysis. (2) RCR allows to identify and quantify the drivers behind changes in corporate eco-efficiency. RCR is applied to the analysis of the CO₂-efficiency of German companies in order to illustrate its usefulness for a detailed analysis of changes in corporate eco-efficiency as well as for the development of effective environmental strategies.     

Elevator availability and its impact on stair use in a workplace

Consistent success in encouraging stair climbing on public access staircases contrasts with equivocal evidence for effectiveness in worksites. This paper tests whether contextual factors may affect stair/elevator choice. The study investigated the impact of elevator availability, pedestrian traffic (number using the elevator and stairs per minute), building occupancy (total individuals in the building) and time of day on stair ascent and descent in a workplace. Stair and elevator choices were monitored by automatic counters every weekday during two phases. In a natural experiment, days with four available elevators were compared with days when three elevators were available. Stair use increased for three elevators compared to four. Increasing building occupancy was associated with increased stair use, whilst increasing pedestrian traffic and time of day was associated with reduced stair use. A follow-up study revealed complimentary effects of building occupancy and time of day on elevator waiting times, indicating that increased stair use by contextual factors reflects increased elevator waiting times. In contrast, shorter waiting times are likely when momentary pedestrian traffic is high and later in the day. Crucially, the magnitude of the effects of these contextual factors was ten times larger than previously reported effects of stair climbing interventions.     

Behaviour of Dioxins, Furans and Metals Associated with Stabilized Msw Combustor Ash in Sea Water

This report presents the results of a research programme designed to examine the engineering and environmental acceptability of stabilizing municipal solid waste (MSW) combustor ash for artificial reef construction. Municipal solid waste combustor ash was combined with Portland cement to form solid blocks using conventional construction block making technology. the resultant stabilized combustor ash (SCA) blocks were used to construct an artificial habitat in Conscience Bay, Long Island Sound, New York and compared to identical concrete blocks, fabricated using natural aggregates. Over a 4.5 year period divers periodically returned to the site to monitor the interaction of SCA blocks with the marine environment and compare the performance of these blocks with the concrete control blocks. Results show that the SCA blocks retain their strength after prolonged sea water exposure. Contaminants of environmental concern, including metals, dioxins and furans, were retained within the cementitious matrix of the SCA blocks after prolonged sea water submersion. in addition, organisms growing on the surfaces of the SCA blocks did not accumulate contaminants from the blocks.     

Urban Air Quality Assessment Model: UAQAM

The Urban Air Quality Assessment Model (UAQAM) calculates urban concentrations caused by city emissions themselves, the so-called city background concentration. Three versions of the model for describing the dispersion were studied: Box, Gifford Hanna (GH) and a combined form of these two (Box–GH model). Regional background emissions contributing to the urban background concentration were accounted for by using measurements and calculations from a dispersion model on the continental scale. The results of the three UAQAM versions for a number of European cities were compared to measurements of SO₂ and NO _X . The Box–GH model shows better results when compared to the Box model and slightly better results in comparison to the GH model. The Box–GH model has been taken as a starting point for the assessment of urban air quality with UAQAM.