金属尾矿制备生物陶粒的研究

阐述了利用江西某金属矿的尾矿、炉渣、粉煤灰制备一种多孔滤料陶粒的方法。实验结果表明：粒径5—30mm、粒子密度1．5-2．5g．／cm^3堆积密度0．65-1．3g／cm^3、比表面积7．2-13．5m^2／g、酸可溶率〈0．7％、筒压强度6．5-9．1MPa、吸水率0．1％～5％的陶粒质轻多孔,比表面积大,附着的微生物量大,孔隙率高,微生物挂膜快,老化生物膜易脱落。     

武汉月湖和莲花湖表层沉积物中持久性有机物的污染状况

采用气－质联用技术分析了武汉汉阳月湖和莲花湖的4个表层沉积物样品中的有机污染物,探讨了两湖沉积物受持久性有机物污染的程度。月湖中共检测出124种有机物,其中属环境优先控制污染物和美国EPA筛选的内分泌干扰物19种;莲花湖中共检测出186种有机物,环境优先控制污染物和美国EPA筛选的内分泌干扰物34种。主要污染物包括：酞酸酯、酯类、酚类、杂环和苯及其衍生物等。污染物浓度顺序为L1＞L2＞Y2＞Y1,莲花湖中有机物浓度明显高于月湖。两湖邻苯二甲酸酯的含量最高,占了污染物总量的96%~98%,邻苯二甲酸乙基己基酯（平均值 17 59903 ng/g 干重）和邻苯二甲酸二丁酯（平均值 2 515.76 ng/g 干重）是两湖沉积物中的主要酞酸酯类污染物。     

Effects of the adaptations to climate changes on the income of herdsmen in Qinghai Province

This study aims to implement the empirical analysis of the effects of the adaptive measures on the income of herdsmen in the context of the climate change with the positive mathematical programming(PMP)model.The survey was first implemented in three counties in the Three Headwaters Region.Finally the measures and recommendations suitable for the economic development in the ecologically fragile areas were proposed.The main conclusions are as follows:priority can be given to the measures to prevent the damage from rats and the engineering measures for pasture maintenance in Zeku County,where the geological conditions and grass quality are inferior,while the fiscal subsidy can be prioritized in Tongde County where the grassland area is relatively less.These recommendations can not only provide good reference for the protection of grassland resources,but they also lay a foundation for the implementation of more suitable measures to help the herdsmen in the ecologically fragile areas to adapt to the climate change.     

Application of Tradable Emission Permits in Europe

Abstract

The purpose of this study is merely to review the current situation in the designing and implementation of the emission trading programs in Europe. Historical data show that although there is a series of shortcomings in their current functioning, employing such instruments for GHG reduction policy making is strongly expected to be efficient and effective. The European Union Emission Trading Scheme (EU ETS), Clean Development Mechanism (CDM) and Joint Implementation (JI) are just a few examples of the ambitious EU initiative that heavily relies on such instruments. We dwell on their operations and achievements by far and all the content in this article is expected to convince the Chinese government and regional public authorities to take positive actions and attitudes in promoting these instruments.     

不同生物炭对磷的吸附特征及其影响因素

为了实现植物生物质资源化利用,选择5种生物质材料制备生物炭,通过比较5种生物炭材料的磷吸附能力,筛选出了2种磷吸附效果较佳的材料,并探明了筛选生物炭材料的理化性质及其对磷的吸附特征.结果表明,5种生物炭材料中,仅水稻秸秆和玉米秸秆生物炭对磷具有吸附能力.Langmuir等温吸附曲线表明,水稻秸秆生物炭对废水中磷的吸附能力强于玉米秸秆生物炭,理论最大吸附量为：水稻秸秆生物炭(9.78 mg·g^-1)>玉米秸秆生物炭(0.39 mg·g^-1).水稻秸秆生物炭的比表面积(148.30 m²·g^-1)和总孔体积(0.11 cm³·g^-1)远高于玉米秸秆生物炭8.26 m²·g^-1和0.03 cm³·g^-1,同时水稻秸秆生物炭有更高的Mg、 Ca、 Fe和Al元素含量.水稻秸秆生物炭和玉米秸秆生物炭对磷吸附的最佳pH为酸性;在不同的pH范围内（3.0～11.0）,水稻秸秆生...     

南水北调丹江口库区土壤中微塑料分布特征及风险评估

为探究丹江口库区土壤中微塑料赋存特征及影响因素,通过对果园、旱地、水田和湿地进行土壤样品采集,利用密度分选、显微镜观察和拉曼光谱仪测定等方法对土壤中微塑料进行鉴定.结果表明,研究区采集的64个样本均有微塑料检出,丰度范围为645~15161 n·kg^-1.空间分布上,库尾高于库中和库首,且表层土壤（0~20 cm）中微塑料的丰度明显低于下层土壤（20~40 cm）.微塑料主要类型为聚丙烯（26.4%）和聚酰胺（20.2%）,粒径主要集中在50~500 μm之间（75%）,常见形状为碎片状（66.2%）.相关性分析显示,土壤微塑料丰度与土地利用、距水面和住宅的距离、人口密度和土壤性状密切相关.从微塑料污染风险来看,72.1%区域微塑料聚合物污染指数处于Ⅲ级和Ⅳ级,丹江口库区存在一定的微塑料污染风险.研究结果可为微塑料风险评估提供支撑.     

缺氧MBBR耦合部分厌氧氨氧化强化城市生活污水深度脱氮

缺氧MBBR是强化传统城市污水处理系统脱氮的一种方法,本研究通过向城市污水后置反硝化SBR中投加填料构建了缺氧双污泥系统,实现了城市生活污水部分厌氧氨氧化深度脱氮.在250d的运行中脱氮性能逐渐提高并实现稳定,出水总氮在5 mg·L~(-1)左右. 211～250 d的平均硝氮、氨氮和总氮去除率分别为(97. 7±2. 9)%、(93. 3±2. 9)%和(94. 3±2. 7)%.长期运行中观测到氨氮和硝氮的同步去除.针对氨氮去除途径进行分析,系统同化、硝化作用微弱.缺氧MBBR中存在厌氧氨氧化活性且对脱氮有不可忽视的作用.实时定量PCR结果进一步说明缺氧MBBR中厌氧氨氧化菌富集,特别是缺氧填料生物膜中厌氧氨氧化菌丰度由初始的4. 37×10~7copies·g~(-1)增长到了2. 28×10~(10)copies·g~(-1).本研究表明缺氧填料生物膜在厌氧氨氧化的富集强化城市污水深度脱氮中或许具有可应用的潜能.     

Relationships between net primary productivity and stand age for several forest types and their influence on China's carbon balance

Affected by natural and anthropogenic disturbances such as forest fires, insect-induced mortality and harvesting, forest stand age plays an important role in determining the distribution of carbon pools and fluxes in a variety of forest ecosystems. An improved understanding of the relationship between net primary productivity (NPP) and stand age (i.e., age-related increase and decline in forest productivity) is essential for the simulation and prediction of the global carbon cycle at annual, decadal, centurial, or even longer temporal scales. In this paper, we developed functions describing the relationship between national mean NPP and stand age using stand age information derived from forest inventory data and NPP simulated by the BEPS (Boreal Ecosystem Productivity Simulator) model in 2001. Due to differences in ecobiophysical characteristics of different forest types, NPP-age equations were developed for five typical forest ecosystems in China (deciduous needleleaf forest (DNF), evergreen needleleaf forest in tropic and subtropical zones (ENF-S), deciduous broadleaf forest (DBF), evergreen broadleaf forest (EBF), and mixed broadleaf forest (MBF)). For DNF, ENF-S, EBF, and MBF, changes in NPP with age were well fitted with a common non-linear function, with R(2) values equal to 0.90, 0.75, 0.66, and 0.67, respectively. In contrast, a second order polynomial was best suitable for simulating the change of NPP for DBF, with an R(2) value of 0.79. The timing and magnitude of the maximum NPP varied with forest types. DNF, EBF, and MBF reached the peak NPP at the age of 54, 40, and 32 years, respectively, while the NPP of ENF-S maximizes at the age of 13 years. The highest NPP of DBF appeared at 122 years. NPP was generally lower in older stands with the exception of DBF, and this particular finding runs counter to the paradigm of age-related decline in forest growth. Evaluation based on measurements of NPP and stand age at the plot-level demonstrates the reliability and applicability of the fitted NPP-age relationships. These relationships were used to replace the normalized NPP-age relationship used in the original InTEC (Integrated Terrestrial Ecosystem Carbon) model, to improve the accuracy of estimated carbon balance for China's forest ecosystems. With the revised NPP-age relationship, the InTEC model simulated a larger carbon source from 1950-1980 and a larger carbon sink from 1985-2001 for China's forests than the original InTEC model did because of the modification to the age-related carbon dynamics in forests. This finding confirms the importance of considering the dynamics of NPP related to forest age in estimating regional and global terrestrial carbon budgets.     

Ligand-assisted degradation of carbon tetrachloride by microscale zero-valent iron

Degradation of carbon tetrachloride (CT) by microscale zero-valent iron (ZVI) was investigated in batch systems with or without organic ligands (ethylenediaminetetraacetic acid (EDTA), citric acid, tartaric acid, malic acid and oxalic acid) at pHs from 3.5 to 7.5. The results demonstrated that at 25°C, the dechlorination of CT by microscale ZVI is slow in the absence of organic ligands, with a pseudo-first-order rate constant of 0.0217 h(-1) at pH 3.5 and being further dropped to 0.0052 h(-1) at pH 7.5. However, addition of organic ligands significantly enhanced the rates and the extents of CT removal, as indicated by the rate constant increases of 39, 31, 32, 28 and 18 times in the presence of EDTA, citric acid, tartaric acid, malic acid and oxalic acid, respectively, at pH 3.5 and 25°C. The effect of EDTA was most significant; the dechlorination of CT at an initial concentration of 20 mg l(-1) increased from 16.3% (no ligands) to 89.1% (with EDTA) at the end of 8h reaction. The enhanced CT degradation in the presence of organic ligands was primarily attributed to the elimination of a surface passivation layer of Fe(III) (hydr)oxides on the microscale ZVI through chelating of organic ligands with Fe(III), which maintained the exposure of active sites on ZVI surface to CT.     

地铁换乘车站客流疏运模拟及风险分析（2）——单通道换乘车站

为了研究通道换乘地铁车站的客流疏运过程及风险点,文章针对某单通道换乘车站,通过对车站通道和客流分析,提出了优化的客流流线;并基于智能个体和矢量空间模拟技术,建立了地铁换乘车站的疏运模型,模拟了高峰时间段内的客流疏运过程。数值模拟结果显示了交叉客流、拥堵发生位置及原因,辨识了高风险位置,并提出了整改措施。文章提出的模拟方法和结论可为国内外类似车站制定客流组织方案及通道设计提供参考。