A Proactive Approach Can Make Site Remediation Less Expensive

Without any incentive to clean up a contaminated site, remediation is often delayed until the site owner is compelled to act by regulatory agencies. In such a context, the selected technology is typically the one that will reach the remediation goals as quickly as possible. Unfortunately, this criterion is often met by overly expensive technologies, resulting in high and sometimes unaffordable total remediation costs, leading to a remediation with a negative net benefit. This study examines the effects of time constraint and benefit value on the optimal remediation strategy for a diesel-contaminated site. This strategy is developed using the technico-economic model METEORS, which takes into account the technology’s effectiveness, the uncertainty of the level of contamination, and the possibility of reducing this uncertainty through either an additional characterization (before selecting and applying a technology) or the monitoring of the remediation technology (during its use). Results of simulations with both economic and temporal constraints support a proactive approach to site remediation.     

Dynamique des populations de Tisbe holothuriae (Crustacea: Copepoda) en élevage sur trois régimes artificiels différents

The influence of three different artificial diets (Tetramin, Bioter food and Renutryl) on the life cycle of Tisbe holothuriae Humes, 1957 has been investigated under constant experimental conditions (19°C; 38 S). Females (F2) whose life history has been followed, were obtained from a common mother (F1). They were bred in 50 ml dishes and transferred into a fresh container as soon as they produced a new egg-sac. Offspring (F3) resulting from successive egg-layings were counted as soon as they moulted into adults. Larval mortality was estimated in two ways: (1) by enumeration of adults issuing from a known number of nauplii; (2) by comparison of the average number of eggs from egg-sacs of F2 with the average number of adult offspring F3. The life-span of F2 females, including the larval stages, varies between 23.6 days (Renutryl diet) and 33.4 days (Tetramin diet). The first egg-sac appears about 12 days after hatching, whatever diet is used. The first copulation immediately follows the last moult, about 8 days after hatching. The reproductive period lasts for 6.5 (Renutryl) to 10.4 days (Bioter). The average number of successive egg-sacs laid is minimal with Renutryl (3.7) and maximal with Tetramin (5.1), but actual egg production is higher with Renutryl (86 eggs/sac) than with Bioter (67) or Tetramin (58). Nevertheless, as a result of varying larval mortality with the different diets, eventual numbers of adult F3 obtained are significantly higher with Bioter (310) than with Tetramin and Renutryl (216 and 188, respectively). The offspring F3 sex-ratio varies in successive broods and with the nature of the food offered: more females are produced with Bioter or Renutryl than with the Tetramin diet. Then net reproduction rate, R ₀, is higher with Bioter, because of the low larval mortality, high fertility, and high ratio of females resulting from this diet. The intrinsic rate of natural increase (r _m) is similar with Renutryl and Bioter diets (0.298 and 0.301, respectively), a lower value (0.260) occurs with the Tetramin diet. These different values are discussed and compared with previous data for Tisbe species fed natural diets.     

Study of the presence of fluorine in the recycled fractions during carbothermal treatment of EAF dust

Carbothermal treatment tests of electric arc furnace dusts (EAFD) using the Waelz kiln process were carried out in pilot-scale for the production of zinc oxide. The association of halides in the EAFD, and the recycled products, such as zinc oxide fumes and high-grade iron contents fractions were examined by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM) analysis. XRD reveals the presence of chlorine and fluorine in the dusts in the form of KCl, NaCl and CaF2. An ultra-pure fraction of zinc was obtained after the Double Leaching Waelz Oxide (DLWO) process was performed on the zinc oxide fumes. The halide contents were reduced to approximately 100 ppm Cl and 700 ppm F. The rest of these elements are in the form of CaF2. About 65% F is volatilised as lead and zinc fluorides, 15% is expected in the magnetic fractions and 20% in non-magnetic fractions as CaF2 and MnF2, respectively.     

Modeling flow and nitrate fate at catchment scale in Brittany (France)

In the intensive pig-farming (Sus scrofa) area of Brittany (western France), many surface and subsurface water resources are contaminated by nitrate (NO3) with concentrations that chronically exceed the European Community 50 mg L(-1) drinking standard. To ensure sustainable water supply, the fate of NO3 must be considered in both surface water and ground water. The fate of N was investigated in a Britain catchment, the Co?t-Dan watershed, with an integrated management tool: the hydrological SWAT model coupled with the ground water model MODFLOW, and its companion contaminant and solute transport model MT3DMS. The model was validated with respect to water quantity during a 6-yr period and for the NO3 concentration during a 44-mo period, at two gauging stations in the catchment. The coupled models reproduced accurately the measurements. At the basin outlet, the Nash-Sutcliffe coefficients were 0.88 for monthly flow for the entire period and 0.87 for monthly N load. Alternative scenarios were simulated and showed potential benefits of decreasing manure application from 210 to 170 kg N ha(-1) as required by the European Commission Nitrates Directive.     

Bioremediation of Chromate by Sulfate-Reducing Bacteria, Cytochromes c3 and hydrogenases

The treatment of soils and ground waters polluted by heavy metals is of economical and environmental interest. Reduction of Cr(VI) to the less toxic Cr(III) associated to its precipitation is a potentially useful process for bioremediation. In order to develop ecological processes using micro-organisms, we have compared various sulfate-reducing bacteria for enzymatic reduction of chromate. The best Cr(VI) reductase activity was obtained with Desulfomicrobium norvegicum. Despite morphological changes induced by the presence of chromate, this strain can grow in the presence of up to 500 M Cr(VI) and can decontaminate waters polluted by Cr(VI) when seeded in bioreactors. We have demonstrated the ability of several metalloenzymes (cytochromes c ₃ and hydrogenases) to reduce chromate. Biophysical investigations of the chromate/protein interaction in order to get further informations on the mechanism of metal reduction by cytochromes c ₃ are under the way.     

Sulfur Metabolism in Polluted Sphagnum Peat Bogs: A Combined 34S–35S–210Pb Study

The size and isotopic behavior of sulfur pools in²¹⁰Pb-dated peat cores were investigated to obtain aninsight into retention mechanisms of pollutant S in twomountain-top peatlands of the Northern Czech Republic, CentralEurope. The bogs were situated 40 km apart in an area whichbetween the years 1985 and 1995 received as much as 130 kg Sha^-1 yr^-1 from the atmosphere. Vertical peataccretion was faster at Pod Jelení horou (JH) than atVelký moál (VM). Organic carbon-bonded S was themost abundant sulfur pool, constituting 77 and 65 wt. % at JHand VM, respectively. At JH both the S concentration maximumand the highest annual S deposition rate were displaceddownward by more than 20 years (from 1987 to the 1960s)indicating that the buried S is vertically mobile. At VM the Sconcentration was the highest in the topmost 2-cm section eventhough atmospheric S deposition peaked in 1987. Differentmechanisms of S isotope redistribution prevailed in thetopmost peat layers at JH, where a negative ³⁴Sshift occurred, and at VM, where a positive ³⁴Sshift occurred. Bacterial sulfate reduction was responsiblefor the negative ³⁴S shift at JH. One possibleexplanation of the positive ³⁴S shift at VM isrelease of ³²S-enriched products of mineralization duringpeat diagenesis. There was a strong positive correlationbetween the abundance of total and pyrite S along the profiles.The presence of pyrite S at VM (526 ± 60 ppm) suggestedthat even at VM bacterial sulfate reduction occurred. Ananaerobic incubation of JH peat indicated sulfate reductionrate of 600 nmol g^-1 day^-1. The turnover times forinorganic S pools were shorter than for the organic S pools.Cumulative S contents in the Czech peat bogs were found to besignificantly lower than in similar sites in the NortheasternU.S., even though the atmospheric S inputs were more thanthree times higher at the Czech sites. Possible causes of suchdiscrepancy are discussed.     

Biowaste effects on soil and native plants in a semiarid ecosystem

Many soils of the Mediterranean region with a semiarid climate are subjected to progressive degradation as a result of water erosion. Biosolids and municipal solid wastes (MSW) were surface-applied once at three rates (40, 80, and 120 Mg ha(-1)) to different plots in a degraded semiarid ecosystem. The study was conducted to determine the effects of such applications on soil chemical properties and native vegetation over a three-year period. Soil N, P, and K initially increased with increasing biowaste application rates, but then decreased over time. Levels of Zn and Cu were higher in MSW than biosolid-treated plots, and increased in both years after application. Concentrations of soil Cd, Pb, Ni, and Cr did not change as a result of biowaste amendment in the study period. The growth of native plants was enhanced by the addition of biowastes. Total plant canopy and plant biomass increased significantly and remained higher in all treatments than in the control plot over the three-year period. The species richness of native plants decreased with increasing biowaste rates. Differences in the development of native plant communities between treatments were observed, and were more remarkable three years after biowaste application. Tissue N, P, K, Zn, and Cu levels increased with the biowaste application rate, but concentrations of tissue Pb, Cd, Ni, and Cr did not increase significantly. Biowastes applied at the rate of 80 Mg ha(-1) gave rise to the most favorable soil and native vegetation results while avoiding environmental risks.     

Wildfire effects on hiking and biking demand in New Mexico: a travel cost study

We use a travel cost model to test the effects of wild and prescribed fire on visitation by hikers and mountain bikers in New Mexico. Our results indicate that net benefits for mountain bikers is $150 per trip and that they take an average of 6.2 trips per year. Hikers take 2.8 trips per year with individual net benefits per trip of $130. Both hikers' and mountain bikers' demand functions react adversely to prescribed burning. Net benefits for both groups fall as areas recover from prescribed burns. Because both visitation and annual recreation benefits decrease to these two types of visitors, this gives rise to multiple use costs associated with prescribed burning. With respect to wildfire, hikers and mountain bikers both exhibit decreased visitation as areas recover from wildfires, however, only hikers indicate an increase in per trip net benefits. Bikers' demand effectively drops to zero. These results differ from previous findings in the literature and have implications for efficient implementation of the National Fire Plan and whether prescribed burning is a cost effective tool for multiple use management of National Forests. Specifically, that fire and recreation managers cannot expect recreation users to react similarly to fire across recreation activities, or different geographic regions. What is cost effective in one region may not be so in another.     

Landform Classification for Land Use Planning in Developed Areas: An Example in Segovia Province (Central Spain)

Landform-based physiographic maps, also called land systems inventories, have been widely and successfully used in undeveloped/rural areas in several locations, such as Australia, the western United States, Canada, and the British ex-colonies. This paper presents a case study of their application in a developed semi-urban/suburban area (Segovia, Spain) for land use planning purposes. The paper focuses in the information transfer process, showing how land use decision-makers, such as governments, planners, town managers, etc., can use the information developed from these maps to assist them. The paper also addresses several issues important to the development and use of this information, such as the goals of modern physiography, the types of landform-based mapping products, the problem of data management in developed areas, and the distinctions among data, interpretations, and decisions.