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371.
Árpád Ambrus Zsuzsannna Horváth Júlia Szenczi-Cseh 《Journal of environmental science and health. Part. B》2018,53(6):404-410
ABSTRACTThe effects of the spread of residue concentrations in the samples derived from the selected supervised trials and the number of trials were studied on the magnitude and uncertainty of the short-term dietary intakes calculated with the proposed new procedure (IESTIp) and that one used currently by the FAO (Food and Agriculture Organization) and WHO (World Health Organization) Joint meeting on Pesticide Residues (JMPR) (IESTIc). The residue data of 10 pesticides were obtained from supervised trials conducted on apples and pears. The methods described in Part I were used for the calculations of the uncertainty. The results indicate that the ratio of IESTIP to IESTIc (φIESTI) is directly proportional to the ratio of the estimated maximum residue level (MRL), recommended by the JMPR; to the highest residue (HR) observed in supervised trials, and it may have a wide range depending on the particular conditions. The φIESTI becomes greater with the increase of the difference between the mrl or maximum residue limit (MRL, established by the Codex Alimentarius Commission, CAC) and HR, and becomes smaller if the difference between the large portion (LP) and unit mass (U) decreases. The φIESTI ranged between 2 and 5.1 in the 16 cases examined indicating that the IESTIp calculation method leads to higher intake estimates. The ratio of CVIESTIp and CVIESTIc ranged typically between 0.62 and 1.71. It rapidly increased up to 12 trials. For a larger number of trials, the ratio remained practically constant (1.69–1.71). The processing factor (PF) equally affects the MRL and HR values, therefore, it will not practically influence the φIESTI. The uncertainty of the estimated median residues depends on the spread and number of values in the residue datasets, which affects the uncertainty of the conversion factor (CF) and subsequently the uncertainty of the estimated IESTIp. Residue values obtained from minimum nine independent trials are required for the correct calculation of the 95% confidence intervals of the calculated median residues. The uncertainty of the analytical results directly affects the median, HR values and indirectly the calculated mrl and the MRL derived from it. Therefore, it should also be considered for the calculation of the combined uncertainty of the conversion factors. For the correct interpretation of the results of dietary exposure calculations, the upper 95% confidence limit of the short-term intake should also be considered. However, it is not the current practice of regulatory agencies or JMPR. 相似文献
372.
Ildikó Kovács Gábor Veréb Szabolcs Kertész Cecilia Hodúr Zsuzsanna László 《Environmental science and pollution research international》2018,25(35):34912-34921
In the present study, TiO2-coated ultrafiltration membranes were prepared and used for oily water filtration (droplet size <?2 μm). The aim of this work was to investigate the effect of different salt contents on fouling and filtration properties of neat and TiO2-coated membranes during oil-in-water emulsion filtration. The effect of the TiO2 coating on the flux, surface free energy, and retention values was measured and compared with the neat membrane values. The cleanability of the fouled TiO2-coated membranes by UV irradiation was also investigated by measuring flux recovery and contact angles, and the chemical changes during cleaning were characterized by ATR-IR. It was found that increasing the salt content of the model wastewaters, oil-in-water emulsions, increased the zeta potential and the size of the droplets. The presence of the TiO2 coating decreases the membrane fouling during oily emulsion filtration compared to the neat membrane, due to the hydrophilicity of the coating regardless of the salt content of the emulsions. The neat and coated membrane oil retention was similar, 96?±?2%. The coated membrane can be effectively cleaned with UV irradiation without additional chemicals and a significant flux recovery can be achieved. Monitoring of the cleaning process by following the membrane surface wettability and ATR-IR measurements showed that the recovery of flux does not mean the total elimination of the oil layer from the membrane surface. 相似文献
373.
Nabee Basatnia Seyed Abbas Hossein Jesús Rodrigo-Comino Yones Khaledian Eric C. Brevik Jacqueline Aitkenhead-Peterson Usha Natesan 《Environmental monitoring and assessment》2018,190(5):314
Coastal lagoon ecosystems are vulnerable to eutrophication, which leads to the accumulation of nutrients from the surrounding watershed over the long term. However, there is a lack of information about methods that could accurate quantify this problem in rapidly developed countries. Therefore, various statistical methods such as cluster analysis (CA), principal component analysis (PCA), partial least square (PLS), principal component regression (PCR), and ordinary least squares regression (OLS) were used in this study to estimate total organic matter content in sediments (TOM) using other parameters such as temperature, dissolved oxygen (DO), pH, electrical conductivity (EC), nitrite (NO2), nitrate (NO3), biological oxygen demand (BOD), phosphate (PO4), total phosphorus (TP), salinity, and water depth along a 3-km transect in the Gomishan Lagoon (Iran). Results indicated that nutrient concentration and the dissolved oxygen gradient were the most significant parameters in the lagoon water quality heterogeneity. Additionally, anoxia at the bottom of the lagoon in sediments and re-suspension of the sediments were the main factors affecting internal nutrient loading. To validate the models, R2, RMSECV, and RPDCV were used. The PLS model was stronger than the other models. Also, classification analysis of the Gomishan Lagoon identified two hydrological zones: (i) a North Zone characterized by higher water exchange, higher dissolved oxygen and lower salinity and nutrients, and (ii) a Central and South Zone with high residence time, higher nutrient concentrations, lower dissolved oxygen, and higher salinity. A recommendation for the management of coastal lagoons, specifically the Gomishan Lagoon, to decrease or eliminate nutrient loadings is discussed and should be transferred to policy makers, the scientific community, and local inhabitants. 相似文献
374.
Priscilla Araújo Victor Sílvia Belém Gonçalves Fabricio Machado 《Journal of Polymers and the Environment》2018,26(5):1755-1774
A modified sequential mass-suspension polymerization was employed to ensure adequate dispersion of lignin into the monomeric phase. Due to its complex macromolecular structure and low compatibility with styrene, eucalyptus wood-extracted lignin, via a modified Kraft method, was esterified with methacrylic anhydride to ensure organic phase homogeneity into the reaction medium. Infrared spectroscopy showed a decrease in the hydroxyl band, a characteristic of natural lignin (3200–3400 cm?1) and an increase in the characteristic ester band (1720–1740 cm?1) whereas nuclear magnetic resonance measurements exhibited intense peaks in the range from 1.7 to 2.05 ppm (–CH3) and 5.4 to 6.2 ppm (=CH2), related to methacrylic anhydride. Comparatively, the esterified lignin also displayed an increase of its glass transition temperature for 98?°C, related to natural lignin, whose T g was determined to be equal to 91?°C. Styrene/lignin-based polymers exhibited higher average molar masses in comparison to the values observed for polystyrene synthesized with similar amounts of benzoyl peroxide, due to the ability of lignin to act as a free-radical scavenger. Composites obtained with styrene and natural or esterified lignin were successfully synthesized, presenting regular morphology and proper lignin dispersion. Based on a very simple polymerization system, it is possible to enhance the final properties of polystyrene through the incorporation of lignin, which represents an important platform for developing attractive polymeric materials from renewable resources. 相似文献
375.
Ximenes Carolina Falcão Rodrigues Samya Mere Lima Podratz Priscila Lang Merlo Eduardo de Araújo Julia Fernandez Puñal Rodrigues Lívia Carla Melo Coitinho Juliana Barbosa Vassallo Dalton Valentim Graceli Jones Bernardes Stefanon Ivanita 《Environmental science and pollution research international》2017,24(31):24509-24520
Environmental Science and Pollution Research - Organotin compounds, such as tributyltin (TBT), are environment contaminants that induce bioaccumulation and have potential toxic effects on marine... 相似文献
376.
Ponce Roberto D. Fernández Francisco Stehr Alejandra Vásquez-Lavín Felipe Godoy-Faúndez Alex 《Regional Environmental Change》2017,17(6):1811-1821
Regional Environmental Change - Agriculture is one of the most vulnerable economic sectors to the impacts of climate change, specifically those related with expected changes in water availability.... 相似文献
377.
Moreno T Querol X Alastuey A García do Santos S Fernández Patier R Artiñano B Gibbons W 《Journal of environmental monitoring : JEM》2006,8(10):1060-1068
Source apportionment study was performed, applying principal component analysis to the results of 221 chemical analyses of PM10 and PM2.5 samples collected daily from the industrial (but low traffic) Spanish town of Puertollano over a 14-month period during 2004-2005. Results reveal compositional variations attributable to different mixtures of natural and anthropogenic materials, mainly soil and rock dust (crustal), marine salt (only in PM10), petrochemical refinery emissions, and particles attributed to the combustion of local coal, which is unusually rich in Pb and Sb. During the study period there were 34 pollution episodes when PM10 exceeded 50 tg m(-3), mostly due to winter air temperature inversions, regional atmospheric stagnation, or African dust incursions (North African, NAF days: usually in summer). Whereas the crustal component during NAF episodes averaged 52% with a PM2.5/PM10 ratio of 0.54, this dropped to 29% and a PM2.5/PM10 of 0.67 during non-NAF days when anthropogenic materials predominated. Abnormally enhanced concentrations of pathfinder metallic trace elements provide additional evidence for source apportionment: thus aerosols with raised levels of Pb and Sb are associated with local coal combustion, Ni and V can be linked to petrochemical PM emissions, and Ti, Mn, Rb, and Ce are particularly characteristic of crustal dust incursions. 相似文献
378.
Distribution and partitioning of iron, zinc, and arsenic in surface sediments in the Grande River mouth to Cuitzeo Lake, Mexico 总被引:1,自引:0,他引:1
Benjamín Villalobos-Castañeda Ruth Alfaro-Cuevas Raúl Cortés-Martínez Verónica Martínez-Miranda Liliana Márquez-Benavides 《Environmental monitoring and assessment》2010,166(1-4):331-346
Cuitzeo Lake is one of the largest and most important lakes in Mexico. It receives different types of pollutants through its main tributary, the Grande River of Morelia. The aim of this work was to determine if high concentrations of iron, zinc, and arsenic are present in sediments in an area near the river mouth to the lake, as well as to estimate the partitioning of these metals using a sequential extraction procedure in order to obtain information of their potential bioavailability. Sediment samples were collected from three different sites in Cuitzeo Lake and two sites in Grande River in both dry and wet seasons. A sequential extraction procedure was carried out to determine the concentrations of these elements in different geochemical phases of the sediments. Total metal concentrations were evaluated by using the enrichment factor and the geoaccumulation index. A comparison with sediment quality guidelines and shale values has also been made. The results indicate that sediments are considered unpolluted by iron and moderately polluted by zinc and arsenic. However, fractionation studies showed that significant amounts of Zn and As could be released to the lake ecosystem depending on the environmental conditions, representing a medium risk potential of bioavailability to the biota. 相似文献
379.
de Melo JG de Amorim EL de Albuquerque UP 《Environmental monitoring and assessment》2009,156(1-4):567-580
A majority of the native medicinal plants that are commercialized in Brazil are harvested from natural populations. In addition to this essentially unrestrained collecting, these plants have been heavily impacted by the cutting and the fragmentation of forest formations throughout the country. Considering the limited availability of natural resources, threats to species diversity, and the necessity of conservation efforts in light of the rapid exhaustion of natural ecosystems, it is becoming exceedingly important to establish conservation priorities. The present work sought to identify the native medicinal plants harvested for industrial purposes and to establish conservation priorities for the species of highest commercial value. To that end, a survey of Brazilian industrial products that use medicinal plants was undertaken in 54 shops in the city of Recife (Pernambuco, NE Brazil). The survey noted information concerning the commercial name of the product, its plant composition and pharmaceutical presentation, therapeutic indications, as well as the laboratory that produced it. Only native species were considered. A total of 74 different native species used to produce more than 300 types of products were encountered in the present survey. Twelve species demonstrated significant versatility (Species which had the highest numbers of different therapeutic indications and body systems), and 58.33% of these plants were trees. Destructive collecting predominates (58.11%), greatly affecting taxa collected exclusively from wild populations (86.49%). The intensive use of exclusively wild species and the destructive harvesting techniques employed in gathering them create serious problems that will threaten the availability of these resources to future generations. 相似文献
380.
Application of water quality indices and analysis of the surface water quality monitoring network in semiarid North-Central Chile 总被引:4,自引:0,他引:4
Espejo L Kretschmer N Oyarzún J Meza F Núñez J Maturana H Soto G Oyarzo P Garrido M Suckel F Amezaga J Oyarzún R 《Environmental monitoring and assessment》2012,184(9):5571-5588
Surface water quality has increasing importance worldwide and is particularly relevant in the semiarid North-Central Chile, where agriculture and mining activities are imposing heavy pressure on limited water resources. The current study presents the application of a water quality index in four watersheds of the 29°-33°S realm for the period 1999-2008, based on the Canadian Council of Ministers for the Environment approach and the Chilean regulation for irrigation water quality. In addition, two modifications to the index are tested and a comprehensive characterization of the existing monitoring network is performed through cluster analysis. The basins studied show fairly good water quality in the overall, specially the Limarí basin. On the other hand, the lower index values were obtained for the headwaters of Elqui, associated with the El Indio mining district. The first modification of the indicator (i.e., to consider parameters differentially according to their effect on human health or the environment) did not produce major differences with respect to the original index, given the generally good water quality. The second modification (i.e., to consider as threshold values the more restrictive figures derived from a set of regulations) yielded important differences in the indicator values. Finally, an adequate characterization of the monitoring network was obtained. The results presented spatial coherence and the information can be used as a basis for the optimization of the monitoring network if required. 相似文献