全文获取类型
收费全文 | 343篇 |
免费 | 3篇 |
国内免费 | 1篇 |
专业分类
安全科学 | 1篇 |
废物处理 | 11篇 |
环保管理 | 11篇 |
综合类 | 121篇 |
基础理论 | 81篇 |
污染及防治 | 71篇 |
评价与监测 | 24篇 |
社会与环境 | 24篇 |
灾害及防治 | 3篇 |
出版年
2022年 | 9篇 |
2021年 | 13篇 |
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 9篇 |
2017年 | 15篇 |
2016年 | 14篇 |
2015年 | 19篇 |
2014年 | 10篇 |
2013年 | 16篇 |
2012年 | 19篇 |
2011年 | 16篇 |
2010年 | 8篇 |
2009年 | 10篇 |
2008年 | 21篇 |
2007年 | 19篇 |
2006年 | 12篇 |
2005年 | 7篇 |
2004年 | 13篇 |
2003年 | 8篇 |
2002年 | 10篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1997年 | 3篇 |
1995年 | 2篇 |
1994年 | 2篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1971年 | 2篇 |
1964年 | 3篇 |
1959年 | 4篇 |
1957年 | 4篇 |
1940年 | 2篇 |
1931年 | 1篇 |
1930年 | 2篇 |
1929年 | 3篇 |
1928年 | 2篇 |
1926年 | 3篇 |
1925年 | 2篇 |
1924年 | 3篇 |
1923年 | 5篇 |
1922年 | 1篇 |
1921年 | 4篇 |
1920年 | 2篇 |
1919年 | 1篇 |
1918年 | 1篇 |
1916年 | 2篇 |
1915年 | 1篇 |
1913年 | 2篇 |
排序方式: 共有347条查询结果,搜索用时 15 毫秒
11.
The significance of colloidal fractions regarding the transport of artificial radionuclides in natural water systems is underlined by using sequential ultrafiltration both in the Rh?ne freshwater and the marine area under and outside the influence of the river outflow. Indeed, the Rhodanian aquatic system represents an interesting test site as various artificial radionuclides are released into the Rh?ne river by several nuclear installations. We focused our study on (137)Cs, (106)Ru, (60)Co, (238)Pu and (239+240)Pu. Our results show that Fe, Al and Organic carbon (OC) are the main components of colloidal matter. Colloids represent about 15% of dissolved (<450 nm) OC and 25% of dissolved Fe and Al exported towards the sea. Within the dissolved (< 450 nm) phase, these colloidal compounds are shown to account for the transport of 40% for both Co and Ru, 60% for (238)Pu and (239+240)Pu and have no significance on (137)Cs flux. 相似文献
12.
Understanding the fate and transport of petroleum hydrocarbons from coal tar within gasholders 总被引:1,自引:0,他引:1
Coal tars have been identified as posing a threat to human health due to their toxic, mutagenic and carcinogenic characteristics. Workers involved in former gasholders decommissioning are potentially exposed to relevant concentrations of volatile and semi-volatile hydrocarbons upon opening up derelict tanks and during tar excavation/removal. While information on contaminated sites air-quality and its implications on medium-long term exposure is available, acute exposure issues associated with the execution of critical tasks are less understood. Calculations indicated that the concentration of a given contaminant in the gasholder vapour phase only depends on the coal tar composition, being only barely affected by the presence of water in the gasholder and the tar volume/void space ratio. Fugacity modelling suggested that risk-critical compounds such as benzene, naphthalene and other monocyclic and polycyclic aromatic hydrocarbons may gather in the gasholder air phase at significant concentrations. Gasholder emissions were measured on-site and compared with the workplace exposure limits (WELs) currently in use in UK. While levels for most of the toxic compounds were far lower than WELs, benzene air-concentrations where found to be above the accepted threshold. In addition due to the long exposure periods involved in gasholder decommissioning and the significant contribution given by naphthalene to the total coal tar vapour concentration, the adoption of a WEL for naphthalene may need to be considered to support operators in preventing human health risk at the workplace. The Level I fugacity approach used in this study demonstrated its suitability for applications to sealed environments such as gasholders and its further refining could provide a useful tool for land remediation risk assessors. 相似文献
13.
Andersson FA Karlsson A Svensson BH Ejlertsson J 《Journal of the Air & Waste Management Association (1995)》2004,54(7):855-861
Volatile sulfur compounds (VSCs) in biogas originating from a biogas production plant and from a municipal sewage water treatment plant were identified. Samples were taken at various stages of the biogas-producing process, including upgrading the gas to vehicle-fuel quality. Solid-phase microextraction was used for preconcentration of the VSCs, which were subsequently analyzed using gas chromatography in combination with mass spectrometry. Other volatile organic compounds present also were identified. The most commonly occurring VSCs in the biogas were hydrogen sulfide, carbonyl sulfide, methanethiol, dimethyl sulfide, and dimethyl disulfide, and hydrogen sulfide was not always the most abundant sulfur (S) compound. Besides VSCs, oxygenated organic compounds were commonly present (e.g., ketones, alcohols, and esters). The effect of adding iron chloride to the biogas reactor on the occurrence of VSCs also was investigated. It was found that additions of 500-g/m3 substrate gave an optimal removal of VSCs. Also, the use of a prefermentation step could reduce the amount of VSCs formed in the biogas process. Moreover, in the carbon dioxide scrubber used for upgrading the gas, VSCs were removed efficiently, leaving traces (ppbv levels). The scrubber also removed other organic compounds. 相似文献
14.
Lambert O Veyrand B Durand S Marchand P Le Bizec B Piroux M Puyo S Thorin C Delbac F Pouliquen H 《Chemosphere》2012,86(1):98-104
Three beehive matrices, sampled in six different apiaries from West France, were analyzed for the presence of four polycyclic aromatic hydrocarbons (PAH4: benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene and chrysene). Samples were collected during four different periods in both 2008 and 2009. Honey samples showed the lowest levels of PAH4 contamination (min = 0.03 μg kg−1; max = 5.80 μg kg−1; mean = 0.82 μg kg−1; Sd = 1.17). Bee samples exhibited higher levels of PAH4 contamination (min = 0.32 μg kg−1; max = 73.83 μg kg−1; mean = 7.03 μg kg−1; Sd = 17.83) with a great dispersion of the concentrations due to four main events of high concentrations. Pollen samples showed only one major episode with the highest PAH4 concentration found (min = 0.33 μg kg−1; max = 129.41 μg kg−1; mean = 7.10 μg kg−1; Sd = 22.28). The PAH4 concentrations found were significantly influenced by the landscape context for all beehive samples. 相似文献
15.
Propiconazole inhibits the sterol 14α-demethylase in Glomus irregulare like in phytopathogenic fungi
Calonne M Sahraoui AL Campagnac E Debiane D Laruelle F Grandmougin-Ferjani A Fontaine J 《Chemosphere》2012,87(4):376-383
The increasing concentrations impact (0.02, 0.2 and 2 mg L−1) of a Sterol Biosynthesis Inhibitor (SBI) fungicide, propiconazole, was evaluated on development and sterol metabolism of two non-target organisms: mycorrhizal or non-mycorrhizal transformed chicory roots and the arbuscular mycorrhizal fungus (AMF) Glomus irregulare using monoxenic cultures. In this work, we provide the first evidence of a direct impact of propiconazole on the AMF by disturbing its sterol metabolism. A significant decrease in end-products sterols contents (24-methylcholesterol and in 24-ethylcholesterol) was observed concomitantly to a 24-methylenedihydrolanosterol accumulation indicating the inhibition of a key enzyme in sterol biosynthesis pathway, the sterol 14α-demethylase like in phytopathogenic fungi. A decrease in end-product sterol contents in propiconazole-treated roots was also observed suggesting a slowing down of the sterol metabolism in plant. Taken together, our findings suggest that the inhibition of the both AM symbiotic partners development by propiconazole results from their sterol metabolism alterations. 相似文献
16.
Four series of dicephalic cationic surfactants, considered as new antielectrostatic agents have been investigated in order to establish their toxicity and biodegradability. Among them N,N-bis[3,3′-(dimethylamine)propyl]alkylamides, N,N-bis[3,3′-(dimethylamine)propyl]alkylamide dihydrochlorides, N,N-bis[3,3′-(trimethylammonio)propyl]alkylamide dibromides and N,N-bis[3,3′-(trimethylammonio)propyl]alkylamide dimethylsulphates with different hydrophobic chain length (n-C9H19 to n-C15H31) and type of counterion (chloride, bromide and methylsulfate) have been studied. The inhibitory effect against microorganisms has been examined using model gram-positive and gram-negative bacteria, and yeasts. None of the tested surfactants have shown antimicrobial activity against gram-negative bacteria (Escherichia coli, Pseudomonas putida) and yeasts (Saccharomyces cerevisiae, Rhodotorula glutinis) at a concentration below 1000 μg mL−1, however some of them were moderately active against gram-positive bacteria (Staphylococcus aureus, Bacillus subtilis). The Microtox® test was successfully applied to measure EC50 values of the studied dicephalic cationic surfactants. Their toxicity to Vibrio fischeri depended upon the alkanoyl chain length with the EC50 values in a range of 2.6-980 mg L−1. N,N-bis[3,3′-(dimethylamine)propyl]alkylamide dihydrochlorides 2a-b and N,N-bis[3,3′-(trimethylammonio)propyl]alkylamide dibromides 3a-b comprising n-decanoyl and n-dodecanoyl hydrophobic tails appeared to be the least toxic. Furthermore, the biodegradability under aerobic conditions of 2a-b, 3a-b was evaluated using OECD Method 301F. According to the obtained results 2a, 3a-3b can be considered as almost readily biodegradable and they are not expected to be persistent in the environment. Additionally, partial biodegradation was observed for 2b, indicating its possible biodegradation in wastewater treatment systems. 相似文献
17.
Katarzyna?Wojczulanis-JakubasEmail authorView authors OrcID profile Ma?gorzata?E.?Chrostek Frédéric?Jiguet Carlos?Zumalacárregui?Martínez David?Miguélez Júlio?M.?Neto 《Die Naturwissenschaften》2017,104(11-12):101
Differential migration has been extensively reported in spring, but less so in autumn, particularly in relation to sex in monomorphic bird species. Here, we analysed the autumn passage of a monomorphic, globally threatened passerine, the Aquatic Warbler Acrocephalus paludicola throughout Western Europe, with regard to age and sex. We showed that, overall, adults migrated earlier than first-year birds, and males migrated earlier than females during the autumn migration. This may be caused by an overall social dominance of adults over immatures, and differentiated migration strategy of males and females. In addition, we found male-skewed sex proportions, with a tendency to an equalised ratio in more southern stopover sites. This may indicate a male bias in the global population or different migration strategies of the sexes. Differential migration may cause the age and sex classes to be exposed differently to various threats affecting demographic structure of the species. 相似文献
18.
Estelle Lefrançois Laure Apothéloz-Perret-Gentil Philippe Blancher Samuel Botreau Cécile Chardon Laura Crepin Tristan Cordier Arielle Cordonier Isabelle Domaizon Benoit J. D. Ferrari Julie Guéguen Jean-Christophe Hustache Louis Jacas Stephan Jacquet Sonia Lacroix Anne-Laurence Mazenq Alina Pawlowska Pascal Perney Jan Pawlowski Frédéric Rimet Jean-François Rubin Dominique Trevisan Régis Vivien Agnès Bouchez 《Environmental science and pollution research international》2018,25(34):33858-33866
The effectiveness of environmental protection measures is based on the early identification and diagnosis of anthropogenic pressures. Similarly, restoration actions require precise monitoring of changes in the ecological quality of ecosystems, in order to highlight their effectiveness. Monitoring the ecological quality relies on bioindicators, which are organisms revealing the pressures exerted on the environment through the composition of their communities. Their implementation, based on the morphological identification of species, is expensive because it requires time and experts in taxonomy. Recent genomic tools should provide access to reliable and high-throughput environmental monitoring by directly inferring the composition of bioindicators’ communities from their DNA (metabarcoding). The French-Swiss program SYNAQUA (INTERREG France-Switzerland 2017–2019) proposes to use and validate the tools of environmental genomic for biomonitoring and aims ultimately at their implementation in the regulatory bio-surveillance. SYNAQUA will test the metabarcoding approach focusing on two bioindicators, diatoms, and aquatic oligochaetes, which are used in freshwater biomonitoring in France and Switzerland. To go towards the renewal of current biomonitoring practices, SYNAQUA will (1) bring together different actors: scientists, environmental managers, consulting firms, and biotechnological companies, (2) apply this approach on a large scale to demonstrate its relevance, (3) propose robust and reliable tools, and (4) raise public awareness and train the various actors likely to use these new tools. Biomonitoring approaches based on such environmental genomic tools should address the European need for reliable, higher-throughput monitoring to improve the protection of aquatic environments under multiple pressures, guide their restoration, and follow their evolution. 相似文献
19.
Mathieu Sicard Frédéric Chevalier Mickaël De Vlechouver Didier Bouchon Pierre Grève Christine Braquart-Varnier 《Die Naturwissenschaften》2010,97(9):819-826
Ecological factors modulate animal immunocompetence and potentially shape the evolution of their immune systems. Not only
environmental parameters impact on immunocompetence: Aging is one major cause of variability of immunocompetence between individuals,
and sex-specific levels of immunocompetence have also been frequently described. Moreover, a growing core of data put in light
that vertically transmitted symbionts can dramatically modulate the immunocompetence of their hosts. In this study, we addressed
the influence of gender, age and the feminising endosymbiont Wolbachia (wVulC) on variations in haemocyte density, total PO activity and bacterial load in the haemolymph of the terrestrial isopod
Armadillidium vulgare. This host–symbiont system is of particular interest to address this question since: (1) wVulC was previously shown as immunosuppressive in middle-aged females and (2) wVulC influences sex determination. We show that age, gender and Wolbachia modulate together immune parameters in A. vulgare. However, wVulC, which interacts with aging, appears to be the prominent factor interfering with both PO activity and haemocyte density.
This interference with immune parameters is not the only aspect of wVulC virulence on its host, as reproduction and survival are also altered. 相似文献
20.
Wax perception in honeybees: contact is not necessary 总被引:1,自引:0,他引:1
In social insects, much progress has been made in identifying variations in the cuticular signatures of sexes, castes, kin and reproductive status. In contrast to this, we still do not know how the receivers perceive these recognition cues. This study was designed to investigate whether honeybees use contact-chemosensory or olfactory sensilla to perceive wax components. To answer this question in a behavioral assay, we combined classical conditioning of the proboscis extension reaction and a recently established method using zinc sulfate to selectively block antennal contact-chemosensory sensilla. Comparison of the responses to sucrose, wax and geraniol before and after antennal zinc sulfate treatment revealed that the sucrose response is lost after treatment but the responses to wax and geraniol are maintained. As sucrose is perceived by the contact-chemosensory sensilla, the retention of the wax response indicates that contact-chemosensory sensilla are not necessary for wax perception. 相似文献