全文获取类型
收费全文 | 983篇 |
免费 | 12篇 |
国内免费 | 6篇 |
专业分类
安全科学 | 24篇 |
废物处理 | 59篇 |
环保管理 | 70篇 |
综合类 | 186篇 |
基础理论 | 178篇 |
污染及防治 | 317篇 |
评价与监测 | 101篇 |
社会与环境 | 58篇 |
灾害及防治 | 8篇 |
出版年
2023年 | 11篇 |
2022年 | 29篇 |
2021年 | 37篇 |
2020年 | 16篇 |
2019年 | 18篇 |
2018年 | 50篇 |
2017年 | 29篇 |
2016年 | 57篇 |
2015年 | 47篇 |
2014年 | 54篇 |
2013年 | 77篇 |
2012年 | 47篇 |
2011年 | 68篇 |
2010年 | 53篇 |
2009年 | 45篇 |
2008年 | 65篇 |
2007年 | 54篇 |
2006年 | 44篇 |
2005年 | 29篇 |
2004年 | 30篇 |
2003年 | 33篇 |
2002年 | 22篇 |
2001年 | 19篇 |
2000年 | 14篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 8篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1990年 | 3篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1964年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有1001条查询结果,搜索用时 15 毫秒
771.
Giovanni Eustáquio Alves Silva Flávia Toledo Ramos Ana Paula de Faria Marcel Giovanni Costa França 《Environmental science and pollution research international》2014,21(19):11572-11579
We determined the length, volume, dry biomass, and density in seeds of five castor bean cultivars and verified notable physicochemical trait differences. Seeds were then subjected to different toxic aluminum (Al) concentrations to evaluate germination, relative root elongation, and the role of root apices’ rhizosphere mucilage layer. Seeds’ physicochemical traits were associated with Al toxicity responses, and the absence of Al in cotyledons near to the embryo was revealed by Al-hematoxylin staining, indicating that Al did not induce significant germination reduction rates between cultivars. However, in the more sensitive cultivar, Al was found around the embryo, contributing to subsequent growth inhibition. After this, to investigate the role of mucilage in Al tolerance, an assay was conducted using NH4Cl to remove root mucilage before or after exposure to different Al concentrations. Sequentially, the roots were stained with hematoxylin and a quantitative analysis of staining intensity was obtained. These results revealed the significant contribution of the mucilage layer to Al toxicity responses in castor bean seedlings. Root growth elongation under Al toxicity confirmed the role of the mucilage layer, which jointly indicated the differential Al tolerance between cultivars and an efficient Al-exclusion mechanism in the tolerant cultivar. 相似文献
772.
773.
Fernando M. Lanças Igor R. B. Olivares Priscila M. Alves 《Journal of environmental science and health. Part. B》2013,48(5):491-498
In this work the development, validation and application of method using Solid Phase Microexctration (SPME) for the analyses of five pollutants (phenol, 2-nitrophenol, 2,4-dimethylphenol, 2,4-dichlorophenol and 4-chloro, 3-methyl phenol) in supplying water, using gas chromatography (GC) with flame ionization detector (FID) is described. The optimal conditions obtained for SPME were: fiber type: Poliacrylate (PA); extraction time: 40 minutes; extraction temperature: 70°C; amount of salt added to sample (NaCl): 15%; desorption temperature: 8 minutes. The parameters studied in the method validation were: limit of detection (0.3 and 3.5 μ g.L? 1); precision, measured by the variation coefficient (between 2.1 and 8.8%); calibration curve and linearity, by using the external standardization method (between 1 and 50 50 μ g.L? 1). After the methodology development, samples of water collected in Atibaia River (São Paulo - Brazil) were analyzed, using the optimized methodology. Three water samples collected in the rain season showed a peak with retention time close to 4-chloro, 3 methyl phenol further analyzed by Gas Chromatography-Mass Spectrometry for the identity confirmation. In spite of the fact that none target compounds were found in the river water samples analyzed, the presence of two phenols different from those investigated (p-terc butyl phenol; butylated hydroxytoluene) were detected. These results together with the results of the limit of detection (that showed to be lower than the maximum concentration of phenols demanded by different environment control agencies), and the results of the validation, indicate the applicability of this method for the analysis of selected phenols in river water samples. 相似文献
774.
Gerson Freitas Silva Valente Regina Célia Santos Mendonça José Antonio Marques Pereira Leonardo Bonato Felix 《Journal of environmental science and health. Part. B》2013,48(4):355-361
Iron electrodes were used for electrocoagulation (EC) treatment of wastewater from a dairy plant. Electrolysis time, pH, current density and distance between electrodes were considered to assess the removal efficiency of chemical oxygen demand (COD), total solids (TS) and their fractions and turbidity. Samples were collected from the effluent of a dairy plant using a sampling methodology proportional to the flow. The treatments were applied according to design factorial of half fraction with two levels of treatments and three repetitions at the central point. The optimization of parameters for treating dairy industry effluent by electrocoagulation using iron electrodes showed that electric current application for 15 minutes, an initial sample pH close to neutral (pH 7.0) and a current density of 50 A . m?2 resulted in a significant reduction in COD by 58 %; removal of turbidity, suspended solids and volatile suspended solids by 95 %; and a final treated effluent pH of approximately 9.5. Negative consequences of the type of electrode used were the emergence of an undesirable color and an increase in the proportion of dissolved solids in the treated effluent. 相似文献
775.
Mehmet Mahramanlioğlu İrfan Kizilcikli İ. Özlem Biçer Melda Tunçay 《Journal of environmental science and health. Part. B》2013,48(2):187-200
Abstract The removal of 2, 4‐D (2, 4‐ dichlorophenoxyacetic acid) from aqueous solutions by activated spent bleaching earths (SBE) was studied at 20 °C. Experiments were performed as a function of time, initial concentration, dose and particle size of the adsorbent. The Langmuir and Freundlich adsorption equations were fitted by the adsorption data obtained. The values of Langmuir and Freundlich constants were determined. The adsorption kinetic was found to follow Lagergren equation. Both the boundary layer and intraparticle diffusion played important roles in the adsorption rate of 2, 4‐D. As the size of the adsorbent increased, the time to reach equilibrium increased but adsorption capacity decreased. 相似文献
776.
Thomas Plocoste Jean-François Dorville Stéphanie Monjoly Sandra Jacoby-Koaly Maïna André 《Journal of the Air & Waste Management Association (1995)》2013,63(12):1278-1300
ABSTRACTThis paper presents a study on ground-level ozone (O3), nitrogen oxides (NOx = NO + NO2) concentrations, and their variabilities in the ambient air of three sites of a tropical archipelago that is moderately urbanized. Statistical analysis was performed on a quite complete (>80%) set of 5 years of measurements (2008–2012). There are few studies on those pollutants and their seasonal behavior in the Caribbean area, where pollution level and cities configuration are different from megacities. Analyses are focused on pollutant variations at the scale of the day, the week, and the seasons, using hourly data. The observations show that NOx concentrations are more elevated during the wet season, whereas O3 concentrations are higher in the dry season. Amplitudes of ozone cycles are strongly influenced by meteorological conditions (temperature, global radiation, and wind speed) and prevailing levels of NOx. An ozone weekend effect is detected with the highest amplitude in the city, where anthropogenic activity is the lowest during the weekend. Due to the nature and the origin of pollutants, NOx shows higher variability than O3 in the time series. Our results evince the need for continuous measurements of volatile organic compounds (VOCs) in order to better quantify their contribution in O3 formation in an insular context where numerous natural sources have been identified.Implications: Statistical analyses of observed NOx and O3 concentrations for 5 years for a typical low industrialized site of the Caribbean area have been done. Air quality for those components is correct based on the standards of the World Health Orgaization, pollutant source spatial distributions, and level of industrialization. Observations show the same patterns as in megacities but also a strong impact of weather conditions and road traffic. Behaviors of O3 cannot be fully explained without VOCs monitoring. Localization and type of AQS should be reconsidered to improve the accuracy of concentrations of the pollutant and better understand their behaviors. 相似文献
777.
Christian Seigneur Betty Pun Prasad Pai Jean-François Louis Paul Solomon Chris Emery 《Journal of the Air & Waste Management Association (1995)》2013,63(4):588-599
ABSTRACT Guidance for the performance evaluation of three-dimensional air quality modeling systems for particulate matter and visibility is presented. Four levels are considered: operational, diagnostic, mechanistic, and probabilistic evaluations. First, a comprehensive model evaluation should be conducted in at least two distinct geographical locations and for several meteorological episodes. Next, streamlined evaluations can be conducted for other similar applications if the comprehensive evaluation is deemed satisfactory. In all cases, the operational evaluation alone is insufficient, and some diagnostic evaluation must always be carried out. Recommendations are provided for designing field measurement programs that can provide the data needed for such model performance evaluations. 相似文献
778.
Pedogenesis and nickel biogeochemistry in a typical Albanian ultramafic toposequence 总被引:1,自引:0,他引:1
Aida Bani Guillaume Echevarria Emmanuelle Montargès-Pelletier Fran Gjoka Sulejman Sulçe Jean Louis Morel 《Environmental monitoring and assessment》2014,186(7):4431-4442
This study aimed at relating the variability of Ni biogeochemistry along the ultramafic toposequence to pedogenesis and soil mineralogy. Hypereutric Cambisols dominate upslope; Cambic Vertisols and Fluvic Cambisols occur downslope. The soil mineralogy showed abundance of primary serpentine all over the sequence. It is predominant upslope but secondary smectites dominate in the Vertisols. Free Fe-oxides are abundant in all soils but slightly more abundant in the upslope soils. Whereas serpentines hold Ni in a similar and restricted range in every soil (approx. 0.3 %), Ni contents in smectites may vary a lot and Mg-rich and Al-poor smectites in the Vertisol could hold up to 4.9 % Ni. Ni was probably adsorbed onto amorphous Fe-oxides and was also exchangeable in secondary smectites. High availability of Ni in soils was confirmed by DTPA extractions. However, it varied significantly along the toposequence, being higher in upslope soils, where Ni-bearing amorphous Fe-oxides were abundant and total organic carbon higher and sensibly lower downslope on the Vertisols: NiDTPA varied from 285 mg kg?1 in the surface of soil I (upslope) to 95.9 mg kg?1 in the surface of Fluvic Cambisols. Concentration of Ni in Alyssum murale shoots varied from 0.7 % (Hypereutric Cambisols) to 1.4 % (Hypereutric Vertisol). Amazingly, Ni uptake by A. murale was not correlated to NiDTPA, suggesting the existence of specific edaphic conditions that affect the ecophysiology of A. murale upslope. 相似文献
779.
Murat Kavurmacı Semih Ekercin Levent Altaş Yakup Kurmaç 《Environmental science and pollution research international》2013,20(8):5416-5424
This paper focuses on the evaluation of water quality variations in Hirfanl? Water Reservoir, which is one of the most important water resources in Turkey, through EO-1 (Earth Observing-1) Advanced Land Imager (ALI) multispectral data and real-time field sampling. The study was materialized in 20 different sampling points during the overpass of the EO-1 ALI sensor over the study area. A multi-linear regression technique was used to explore the relationships between radiometrically corrected EO-1 ALI image data and water quality parameters: chlorophyll a, turbidity, and suspended solids. The retrieved and verified results show that the measured and estimated values of water quality parameters are in good agreement (R 2?>?0.93). The resulting thematic maps derived from EO-1 multispectral data for chlorophyll a, turbidity, and suspended solids show the spatial distribution of the water quality parameters. The results indicate that the reservoir has average nutrient values. Furthermore, chlorophyll a, turbidity, and suspended solids values increased at the upstream reservoir and shallow coast of the Hirfanl? Water Reservoir. 相似文献
780.
Carolinne Borges Khayat Emília Oliveira Alves Costa Macks Wendhell Gonçalves Damiana Mirian da Cruz e Cunha Alex Silva da Cruz Caroline Oliveira de Araújo Melo Rogério Pereira Bastos Aparecido Divino da Cruz Daniela de Melo e Silva 《Environmental science and pollution research international》2013,20(10):7334-7340
We evaluated 41 rural workers occupationally exposed to pesticides and 32 subjects as a control group, using the micronucleus (MN) and the comet assay. For the comet assay, we evaluated the peripheral blood, and for the MN, we sampled cells from the oral epithelium. Damage to DNA was measured by tail length, % DNA in tail (% tail), olive tail moment (OTM), and tail moment (TM). The exposed group presented an 8× increase in MN frequency, when compared to the control group (p <0.05). When we contrasted the MN frequencies between the individuals that use and do not use personal protective equipment, we found a mean of 7.5 MN (57 % variance) and 12.1 MN (130 % variance), respectively. The binucleated cells were 0.04 and 0.005, in the exposed and control groups, respectively, indicating 8× increase in the number of binucleated cells, when comparing the groups (p <0.05). In the comet assay, we demonstrated statistically significant differences in three parameters (% DNA, OTM, and TM) indicating that the rural workers presented high levels of genomic damages. Our results indicate that occupational exposure to pesticides could cause genome damage in somatic cells, representing a potential health risk to Brazilian rural workers that deal constantly with agrochemicals without adequate personal protection equipment. 相似文献