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81.
Morselli L Luzi J De Robertis C Vassura I Carrillo V Passarini F 《Waste management (New York, N.Y.)》2007,27(8):S85-S91
In Emilia-Romagna region (Northern Italy) the integrated waste treatment system consists of material collection and recycling, incineration with energy recovery and landfill as final disposal. In particular, at least one incineration plant is working in almost every province of the region. In this work, a screening life cycle assessment approach is applied to seven different incinerators, to compare the different plant technologies and identify the most relevant environmental impacts and processes. The characterization method used in the life cycle impact assessment step is Eco-indicator 99. The functional unit is 1 ton of waste input. As a first result, it can be noted that while the combustion systems are rather similar, the main variables are ascribable to gas cleaning options and efficiency in energy recovery, which result in quite different environmental performances. Among heavy metals, particular attention must be paid to Cd and As, due to their high toxicity, despite their low quantities. The impact due to dioxin emission is orders of magnitude lower than other contaminants (e.g., heavy metals). Furthermore, a catalytic system could be useful for a complete removal of organic contaminants and for a more effective abatement of nitrogen oxides. Finally, the environmental impact assessment sorts the various plants according to their age, i.e., the most recent plants provide the best environmental performances for the same quantity of combusted waste. 相似文献
82.
Municipal solid waste incinerator (MSWI) bottom ash may be used as a road construction material; it potentially contains however a sizable quantity of heavy metals, which under the effect of rainfall infiltration through the road structure can be leached out from the material and infiltrate into the underlying soil. An eco-compatibility assessment of MSWI bottom ash reuse in road construction applications necessitates examining the solubility and retention of heavy metals in road soils. This study is dedicated to Pb transfer, sorption and desorption (NEN 7341 standard test) within various soils. These experiments yield results relative to the interaction between road soils and an MSWI bottom ash leachate representative of a "fresh" product, with a high leaching potential. For the soils investigated, the sorption of lead varies between 90% and 99%. For an extraction at pH 7, Pb release is very low (<2%) for all soils, while at pH 4 leaching varies between 4% and 47%. This work shows that Pb may be fixed by some types of road soil in mostly stable forms. 相似文献
83.
Absorption, disposition and excretion of polybrominated diphenyl ethers (PBDEs) in chicken 总被引:1,自引:0,他引:1
Except for fish, no toxicokinetic data on polybrominated diphenyl ethers (PBDEs) is available on relevant animals for the human food chain. In the present work, absorption, elimination through eggs and disposition of PBDEs in laying chickens were studied and compared to dioxin behaviour. Hens were fed with diet containing 3.4 mg/kg feed of PBDEs and 0.95 ng TEQ/kg feed of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs). PBDEs have been demonstrated to show drastically different behaviours from PCDD/Fs and dioxin-like compounds. Excretion of PBDEs increased for two weeks and then decreased to nearly 0%. Sixty-two percent of ingested 2,2',4,4'-tetraBDE (BDE-47) were found in excreta after two weeks, suggesting a reductive debromination of PBDEs in the digestive tract. PBDE level in eggs increased during five weeks and reached 24 microg/g fat. After then, levels decreased to 3 microg/g fat at the end of the trial. PBDE bioconcentration factors estimated for abdominal fat varied from 0.7 for BDE-47 to 2 for BDE-183. 相似文献
84.
Laboratory-scale studies were aimed at elucidating the physico-chemical aspects on the removal process of crystal violet (CV) from waters and solid substrates. The laponite clay (RD) and sand were chosen for the double aim at investigating them as CV adsorbents for water treatment and as substrates which mime the soil components. Sand is very effective in removing CV from waters. The cyclodextrins (CDs) were exploited as solubility-enhancement agents to remove CV from the solid substrates. They are powerful solvent media because they extract the CV from sand forming water-soluble CV/CD inclusion complexes and do not show affinity for sand. Optimum performance was shown by the modified CDs (i.e. hydroxypropyl-β-cyclodextrin and methyl-β-cyclodextrin). A linear correlation between the logarithm of the equilibrium constant for the CV/CD inclusion complexes formation (Kcpx) and the maximum amount of CV extracted from sand in the columns experiments at a flow rate of 1.5 ml min−1 was drawn. This relationship predicts that CDs with Kcpx < 180 M−1 are not suitable for CV removal from sand. CDs failed to displace CV from RD because they generate the formation of RD clusters where CV remains entrapped. 相似文献
85.
The pathway for the flow of salt-marsh grass production into marsh food-webs is still not well defined. We compared the abilities
of three marsh macroinvertebrates [salt marsh periwinkles, Littoraria irrorata (Say) (=Littorina irrorata), salt-marsh coffee-bean snails, Melampus bidentatus (Say); and a talitrid amphipod, Uhlorchestia spartinophila Bounsfield and Heard] to access standing-dead leaves of smooth cordgrass (Spartina alterniflora Loisel). The invertebrates were incubated with naturally-decaying leaves, and the rates of removal of organic matter and
living fungal biomass (ergosterol) were measured. The impact of invertebrate activity upon fungal growth rates was measured
as rates of fungal-membrane synthesis (incorporation of radioacetate into ergosterol). The removal rates of organic leaf biomass
per mg individual biomass were highest for amphipods (700 μg mg−1 d−1) and lowest for periwinkles (90 μg mg−1 d−1), but the relatively large biomass of the snails made their removal rates per individual greater than those of amphipods.
Net removal of ergosterol by all three invertebrates was >50% for yellow-brown (early-decay) leaf blades. For fully-brown
(advanced-decay) blades, >50% removal of ergosterol was found only for periwinkles; exposure to coffee-bean snails and amphipods
resulted in a net ergosterol reduction of ≤20%. The lower net reduction of living fungal biomass by coffee-bean snails and
amphipods may have been due to fungal-growth stimulation (2.3-fold stimulation in coffee-bean snails and 1.5-fold stimulation
in amphipods). Grazing by periwinkles did not stimulate fungal growth, possibly because of its high intensity. Grazing by
these three salt-marsh shredders may affect marsh-grass shoot-decay in different ways. Periwinkles may abbreviate the period
of fungal production, and incorporate the decaying material relatively quickly into snail biomass and fecal-pellet rain to
the sediments. Coffee-bean snails and amphipods may enhance and prolong fungal production, along with the formation of fecal-pellet
rain. All three invertebrates fed preferentially on leaf blades rather than leaf sheaths, and feeding rates of gastropods
were higher during the night than during the day.
Received: 25 November 1998 / Accepted: 4 November 1999 相似文献
86.
Experimental evidence of a testosterone-induced shift from paternal to mating behaviour in a facultatively polygynous songbird 总被引:5,自引:2,他引:3
Previous studies have suggested that testosterone (T) profiles of male birds reflect a trade-off between mate attraction behaviours
(requiring high T levels) and parental care activities (requiring low T levels). In this study, we experimentally elevated
T levels of monogamous males in the facultatively polygynous European starling (Sturnus vulgaris), and compared mate attraction and paternal behaviour of T-treated males with those of controls (C-males). T-males significantly
reduced their participation in incubation and fed nestlings significantly less often than C-males. Females paired to T-treated
males did not compensate for their mate’s lower paternal effort. The observed reduction in a male’s investment in incubating
the eggs was accompanied by an increased investment in typical female-attracting behaviours: T-males spent a significantly
higher proportion of their time singing to attract additional females. They also occupied more additional nestboxes than C-males,
although the differences just failed to be significant, and carried significantly more green nesting materials into an additional
nestbox (a behaviour previously shown to serve a courtship function). T-males also behaved significantly more aggressively
than C-males. During the nestling period, the frequency of mate-attracting behaviours by T-treated and control males no longer
differed significantly. Despite the reduced paternal effort by T-males and the lack of compensation behaviour by females,
hatching and breeding success did not differ significantly between T- and C-pairs.
Received: 7 February 2000 / Revised: 10 August 2000 / Accepted: 3 September 2000 相似文献
87.
The planning and management of coastal sites in Catalonia has been mainly concerned with rendering beaches functional for
mass frequentation. This has caused serious problems for the beaches, including the alteration of dune formation processes
and the destruction of beach vegetation and habitats. Municipal capacity to plan and manage beaches is theoretically very
limited and relegated to the design of plans related to the maintenance of facilities for beach users. Nonetheless, a singular
experience, led by a local council in the metropolitan area of Barcelona demonstrates the crucial role that a local administration
can play in achieving a balance between habitat preservation and social use based on sustainable coastal management objectives,
in spite of a restrictive legislation. 相似文献
88.
Lea Nicita Giovanni Signorello Maria De Salvo 《Journal of Environmental Planning and Management》2016,59(7):1225-1237
This paper applies the Kuhn–Tucker model to estimate recreation demand of parks in Sicily. We estimate a fixed coefficient specification and a random coefficient specification to take into account heterogeneity across visitors. Estimates suggest a diversity of preferences across the population and that parks with higher level of quality attributes are more likely to be visited. We also simulate two sets of hypothetical policy scenarios to evaluate and compare the recreational value of each park and the welfare impacts of changes in a quality attribute. 相似文献
89.
90.
Burçak Ebin Martina Petranikova Christian Ekberg 《Journal of Material Cycles and Waste Management》2018,20(4):2018-2027
Nickel–metal hydride (NiMH) batteries contain high amount of industrial metals, especially iron, nickel, cobalt and rare earth elements. Although the battery waste is a considerable secondary source for metal and chemical industries, a recycling process requires a suitable pretreatment method before proceeding with recovery step to reclaim all valuable elements. In this study, AA- and AAA-type spent NiMH batteries were ground and then sieved for size measurement and classification. Chemical composition of the ground battery black mass and sorted six different size fractions were determined by an analytical technique. Crystal structures of the samples were analyzed by X-ray diffraction. Results show that after mechanical treatment, almost 87 wt% of the spent NiMH batteries are suitable for further recycling steps. Size classification by sieving enriched the iron content of the samples in the coarse fraction which is bigger than 0.25 mm. On the other hand, the amounts of nickel and rare earth elements increased by decreasing sample size, and concentrated in the finer fractions. Anode and cathode active materials that are hydrogen storage alloy and nickel hydroxide were mainly collected in finer size fraction of the battery black mass. 相似文献