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排序方式: 共有334条查询结果,搜索用时 15 毫秒
191.
Stea Francesco Faita Francesco Borghini Andrea Faita Francesca Bianchi Fabrizio Bustaffa Elisa Minichilli Fabrizio Andreassi Maria Grazia Sicari Rosa 《Environmental science and pollution research international》2016,23(20):20307-20314
Environmental Science and Pollution Research - Exposure to arsenic (As) increases cardiovascular risk. The purpose of this study was to evaluate the relationship between As and intima-media... 相似文献
192.
Magdalena E. Bergés-Tiznado Federico Páez-Osuna Alessandra Notti Francesco Regoli 《Environmental monitoring and assessment》2013,185(9):7459-7468
In this study, we examined the bioavailability of arsenic through the mangrove oyster Crassostrea corteziensis sampled from seven coastal lagoons in SE Gulf of California during the rainy and dry seasons. As concentrations in soft tissue of oysters C. corteziensis fluctuated between 5.2 and 11.6 μg/g on dry weight; organisms from the control site presented the lowest As concentrations in the two sampling seasons. As speciation was evaluated in selected samples and indicated that arsenobetaine was the major arseno-compound accounting for 53.5–74.7 % of total As. Lower percentage contributions were obtained for nonextractable As (9.7–25.5 %) and other molecules such as arsenocholine and methyl-arsonate (<5 %). Inorganic As was detectable in only two samples, at concentrations lower than 0.1 μg/g. These As data are the first generated in NW Mexico and indicate that C. corteziensis is safe for human consumption in terms of arseno-compounds. It is evident that As bioavailability in these lagoons is low. 相似文献
193.
Gorbi Stefania Benedetti Maura Virno Lamberti Claudia Pisanelli Barbara Moltedo Ginevra Regoli Francesco 《Environmental pollution (Barking, Essex : 1987)》2009,157(11):3166-3173
Diethylene glycol (DEG) is largely used during oil and gas exploitation by offshore platforms. The aim of this work was to investigate if this compound induces direct molecular/cellular effects in marine organisms, or indirectly modulate those of produced waters (PWs). Sea bass (Dicentrarchus labrax) were exposed to DEG dosed alone or in combination with PWs from an Adriatic platform. A wide array of analysed biomarkers included cytochrome P450-dependent enzymatic activity, bile metabolites, glutathione S-transferases, acetylcholinesterase, peroxisomal proliferation, antioxidant defences (catalase, glutathione reductase, glutathione peroxidases, glutathione), total oxyradical scavenging capacity, malondialdehyde and DNA integrity (single strand breaks and frequency of micronuclei). Results did not reveal marked effects of DEG, while PWs influenced the biotransformation system, the oxidative status and the onset of genotoxic damages. Co-exposures caused only limited differences of biomarker responses at some experimental conditions, overall suggesting a limited biological impact of DEG at levels normally deriving from offshore activities. 相似文献
194.
Biosorption of heavy metals is an innovative and alternative technology to remove these pollutants from aqueous solutions using inactive and dead biomasses such as agricultural and industrial wastes, algae and bacteria. In this study olive mill solid residue was used as heavy metal adsorbent material for its wide availability as agricultural waste and also for its cellulosic matrix, rich of potential metal binding active sites. Preliminary studies concerned with the removal of different heavy metals (Hg, Pb, Cu, Zn and Cd), the effect of pre-treatments by water and n-hexane and the regeneration possibility. Olive mill solid residue resulted able to remove heavy metals from aqueous solutions with an affinity series reflecting the hydrolytic properties of the metallic ions, but also a particular affinity for copper. It can be supposed that biosorption phenomenon occur by a general ion exchange mechanism combined with a specific complexation reaction for copper ions. Water pre-treatment is sufficient to reduce COD release in the effluent according to the law limit, while n-hexane pre-treatment strongly reduces also the adsorption properties of this material. Experimental isotherms obtained under different operating conditions were fitted using a non linear regression method for the estimation of the Langmuir parameters. Moreover a simple Scatchard plot analysis was performed for a preliminary investigation of the active sites, showing the presence of two different site affinities depending on the metal concentration, according to the previous hypothesis of two kinds of uptake mechanisms for copper biosorption. Regeneration tests gave good results in terms of yield of regeneration and also concentration ratios. 相似文献
195.
Marwan A. Hassan Michael Church Thomas E. Lisle Francesco Brardinoni Lee Benda Gordon E. Grant 《Journal of the American Water Resources Association》2005,41(4):853-876
This paper reviews sediment transport and channel morphology in small, forested streams in the Pacific Northwest region of North America to assess current knowledge of channel stability and morphology relevant to riparian management practices around small streams. Small channels are defined as ones in which morphology and hydraulics may be significantly influenced by individual clasts or wood materials in the channel. Such channels are headwater channels in close proximity to sediment sources, so they reflect a mix of hillslope and channel processes. Sediment inputs are derived directly from adjacent hillslopes and from the channel banks. Morphologically significant sediments move mainly as bed load, mainly at low intensity, and there is no standard method for measurement. The larger clastic and woody elements in the channel form persistent structures that trap significant volumes of sediment, reducing sediment transport in the short term and substantially increasing channel stability. The presence of such structures makes modeling of sediment flux in these channels — a potential substitute for measurement — difficult. Channel morphology is discussed, with some emphasis on wood related features. The problem of classifying small channels is reviewed, and it is recognized that useful classifications are purpose oriented. Reach scale and channel unit scale morphologies are categorized. A “disturbance cascade” is introduced to focus attention on sediment transfers through the slope channel system and to identify management practices that affect sediment dynamics and consequent channel morphology. Gaps in knowledge, errors, and uncertainties have been identified for future research. 相似文献
196.
Fermo Paola Comite Valeria La Russa Mauro Francesco 《Environmental science and pollution research international》2022,29(20):29382-29384
Environmental Science and Pollution Research - 相似文献
197.
Zuccato E Castiglioni S Fanelli R Reitano G Bagnati R Chiabrando C Pomati F Rossetti C Calamari D 《Environmental science and pollution research international》2006,13(1):15-21
- DOI: http://dx.doi.org/10.1065/espr2006.01.004
Background, Aim and Scope Environmental contamination by pharmaceuticals is an emerging issue. Until recently, information on medicinal substances
released into the environment was scant, but several studies have now been published. Data are, however, usually scattered
and a systematic approach to this subject is generally lacking. Moreover, because of differences in the prevalence of diseases,
treatment habits and options, or simply for market reasons, the pollution profile can differ significantly in different countries.
The aim of this work is to review the papers dealing with environmental contamination by pharmaceuticals in Italy, with the
aim of providing a comprehensive view on a national scale.
Methods Papers related to environmental contamination by pharmaceuticals in Italy were reviewed, in order to offer a comprehensive
view of this subject. Topics included analysis, occurrence, monitoring, modelling, treatment, control of the emissions, and
ecotoxicological effects of pharmaceuticals in the environment.
Results and Conclusion The literature suggests that pharmaceuticals are widespread contaminants, entering the environment from a myriad of scattered
points. Patients, in case of drugs for human use, or animals for veterinary drugs, are the main sources of contamination.
Pharmaceuticals can be ranked according to environmental loads, predicted by multiplying sales figures by the rate of metabolism
in man or animals. Priority pharmaceuticals, i.e. the molecules of concern for the environment, can be measured in waste and
surface water by liquid chromatography-tandem mass spectrometry, and the loads detected are generally comparable to the predicted
ones. Pharmaceuticals are designed to stimulate a response in humans and animals at low doses, with a very specific target,
so the implications for human health and the environment need to be assessed. In vitro and in vivo studies suggest that pharmaceutical
principles, taken singularly or in combinations, and concentrations close to those detected in the environment, may have ecotoxicological
effects. The sewage system is an important point in the control of contamination, but sewage treatment plants are not able
efficiently to abate a substantial part of water-borne pharmaceuticals. Several variables play a role, however, in the processes
of waste water treatment, and could be specifically adjusted to improve the efficiency of drug abatement, mitigating the potential
environmental hazards.
Recommendation and Perspective Pharmaceuticals in the environment are becoming a subject of global concern, with potential environmental consequences. Further
knowledge of the causes, occurrence and effects of drugs as environmental pollutants is necessary for a better understanding
of this ecological issue, as well as to improve abatement strategies, and to mitigate subtle environmental consequences. 相似文献
198.
Kerstin Ronneberger Maria Berrittella Francesco Bosello Richard S. J. Tol 《Environmental Modeling and Assessment》2009,14(2):149-168
In this paper, the global agricultural land use model Kleines Land Use Model is coupled to an extended version of the computable general equilibrium model (CGE) Global Trade Analysis
Project in order to consistently assess the integrated impacts of climate change on global cropland allocation and its implication
for economic development. The methodology is innovative as it introduces dynamic economic land-use decisions based also on
the biophysical aspects of land into a state-of-the-art CGE; it further allows the projection of resulting changes in cropland
patterns on a spatially more explicit level. A convergence test and illustrative future simulations underpin the robustness
and potentials of the coupled system. Reference simulations with the uncoupled models emphasise the impact and relevance of
the coupling; the results of coupled and uncoupled simulations can differ by several hundred percent.
相似文献
Francesco BoselloEmail: Email: |
199.
The Ti02-mediated photomineralization of 8–1000 ppm of methanoic acid, of 6–100 ppm of ethanoic acid, of 6–180 ppm of propanoic acid, and of 6–90 ppm of n-decanoic acid in aqueous solutions was studied at 296± 2 K or 308 ± 2 K, with low and high pressure mercury arc lamps (radiant power in the absorption range 8 and 145 W respectively), using PHOTOPERM® CPP/313 membranes containing immobilized 30±3 wt.% Ti02, and, in parallel runs, 7 wt.% of a synergic mixture of tri(t-butyl)- and tri-(i-propyl) vanadate(V) as photocatalytic promoter. Stoichiometric H202 was used or, in some of the runs, 03, at saturation, as oxygen suppliers. Disappearance of total organic carbon (TOC) was followed as a function of time. To fit kinetic curves up to complete photomineralization, a kinetic model was employed, already used successfully in previous studies, which considers appearance and disappearance of all intermediates, as if they were represented by a hypothetical single molecule, mediating all of them. The photocatalytic activity of trialkyl vanadates was evaluated from quantum yields at “infinite” concentration, with respect to the maximum allowable efficiencies. When using O3, a dark catalysis effect clearly appeared towards intermediate species produced during the photocatalysed degradation. 相似文献
200.
Francesco Ferretti Andrea Sforzi Sandro Lovari 《Behavioral ecology and sociobiology》2011,65(5):875-887
Interference is expected to occur at feeding areas between species with a similar diet, but few studies have tested this idea
for wild ungulates. We analysed interactions between fallow deer, European roe deer and wild boar, in three sites, in a Mediterranean
area. We expected that interference should be greater between deer than between them and wild boar. We documented the negative
effects of behavioural interference by fallow on foraging behaviour of roe deer, under field conditions. Deer species built
up 90% interference interactions, with fallow always dominant on roe, also through direct aggression. Although roe deer decreased
feeding and increased vigilance levels in proximity (<50 m) of either fallow deer or wild boar, they were displaced significantly
more often by the former than by the latter. Fallow deer were neither displaced nor alarmed by roe and rarely by wild boar.
No deer species displaced wild boar. Interference was significantly greater on solitary roe deer, especially females, in spring
and roe left the feeding ground most often in the smallest site (13 ha). Roe deer avoided areas where the local density of
fallow deer was the highest. During our 4-year-study, roe deer density decreased whereas fallow deer numbers increased. Behavioural
interference may explain how fallow deer outcompete roe deer through spatial exclusion from feeding sites and avoidance of
areas with high densities of the former. Fallow deer evolved in semi-arid, relatively poor habitats of Asia Minor: interspecific
defence of crucial resources could have developed as a beneficial tactic for its survival. 相似文献