Field-scale effective matrix diffusion coefficient for fractured rock: results from literature survey

Matrix diffusion is an important mechanism for solute transport in fractured rock. We recently conducted a literature survey on the effective matrix diffusion coefficient, D_m^e, a key parameter for describing matrix diffusion processes at the field scale. Forty field tracer tests at 15 fractured geologic sites were surveyed and selected for the study, based on data availability and quality. Field-scale D_m^e values were calculated, either directly using data reported in the literature, or by reanalyzing the corresponding field tracer tests. The reanalysis was conducted for the selected tracer tests using analytic or semi-analytic solutions for tracer transport in linear, radial, or interwell flow fields. Surveyed data show that the scale factor of the effective matrix diffusion coefficient (defined as the ratio of D_m^e to the lab-scale matrix diffusion coefficient, D_m, of the same tracer) is generally larger than one, indicating that the effective matrix diffusion coefficient in the field is comparatively larger than the matrix diffusion coefficient at the rock-core scale. This larger value can be attributed to the many mass-transfer processes at different scales in naturally heterogeneous, fractured rock systems.Furthermore, we observed a moderate, on average trend toward systematic increase in the scale factor with observation scale. This trend suggests that the effective matrix diffusion coefficient is likely to be statistically scale-dependent. The scale-factor value ranges from 0.5 to 884 for observation scales from 5 to 2000 m. At a given scale, the scale factor varies by two orders of magnitude, reflecting the influence of differing degrees of fractured rock heterogeneity at different geologic sites. In addition, the surveyed data indicate that field-scale longitudinal dispersivity generally increases with observation scale, which is consistent with previous studies. The scale-dependent field-scale matrix diffusion coefficient (and dispersivity) may have significant implications for assessing long-term, large-scale radionuclide and contaminant transport events in fractured rock, both for nuclear waste disposal and contaminant remediation.     

Diffusive wave models for operational forecasting of channel routing at continental scale

Operational forecast models require robust, computationally efficient, and reliable algorithms. We desire accurate forecasts within the limits of the uncertainties in channel geometry and roughness because the output from these algorithms leads to flood warnings and a variety of water management decisions. The current operational Water Model uses the Muskingum-Cunge method, which does not account for key hydraulic conditions such as flow hysteresis and backwater effects, limiting its ability in situations with pronounced backwater effects. This situation most commonly occurs in low-gradient rivers, near confluences and channel constrictions, coastal regions where the combined actions of tides, storm surges, and wind can cause adverse flow. These situations necessitate a more rigorous flow routing approach such as dynamic or diffusive wave approximation to simulate flow hydraulics accurately. Avoiding the dynamic wave routing due to its extreme computational cost, this work presents two diffusive wave approaches to simulate flow routing in a complex river network. This study reports a comparison of two different diffusive wave models that both use a finite difference solution solved using an implicit Crank–Nicolson (CN) scheme with second-order accuracy in both time and space. The first model applies the CN scheme over three spatial nodes and is referred to as Crank–Nicolson over Space (CNS). The second model uses the CN scheme over three temporal nodes and is referred to as Crank–Nicolson over Time (CNT). Both models can properly account for complex cross-section geometry and variable computational points spacing along the channel length. The models were tested in different watersheds representing a mixture of steep and flat topographies. Comparing model outputs against observations of discharges and water levels indicated that the models accurately predict the peak discharge, peak water level, and flooding duration. Both models are accurate and computationally stable over a broad range of hydraulic regimes. The CNS model is dependent on the Courant criteria, making it less computational efficient where short channel segments are present. The CNT model does not suffer from that constraint and is, thus, highly computationally efficient and could be more useful for operational forecast models.     

Thriving at work: Impact of psychological capital and supervisor support

Thriving at work is a positive psychological state characterized jointly by learning and vitality. Conventional wisdom and some initial research indicate that such thriving benefits both employees themselves and their organizations. This study specifically tests thriving at work by linking it to a theoretically important personal outcome variable (self‐development), refining its relationship with agentic work behaviors (task focus and heedful relating), and proposing and testing two new antecedent variables (psychological capital and supervisor support climate). Using structural equation modeling on a sample of 198 dyads (employees and their supervisors), strong support was found for the theory‐driven hypothesized relationships. The results contribute to a better understanding of positive organizational scholarship and behavior in general and specifically to the recently emerging positive construct of employees' thriving at work. Copyright © 2013 John Wiley & Sons, Ltd.     

Host preference,site fidelity,and homing behavior of the symbiotically luminous cardinalfish,Siphamia tubifer (Perciformes: Apogonidae)

The sea urchin cardinalfish, Siphamia tubifer (Perciformes: Apogonidae), is unusual among coral reef fishes for its use of bioluminescence, produced by symbiotic bacteria, while foraging at night. As a foundation for understanding the relationship between the symbiosis and the ecology of the fish, this study examined the diel behavior, host urchin preference, site fidelity, and homing of S. tubifer in June and July of 2012 and 2013 at reefs near Sesoko Island, Okinawa, Japan (26°38′N, 127°52′E). After foraging, S. tubifer aggregated in groups among the spines of the longspine sea urchin, Diadema setosum, and the banded sea urchin, Echinothrix calamaris. A preference for D. setosum was evident (P < 0.001), especially by larger individuals (>25 mm standard length, P < 0.01), and choice experiments demonstrated the ability of S. tubifer to recognize and orient to a host urchin and to conspecifics. Tagging studies revealed that S. tubifer exhibits daily fidelity to a host urchin; 43–50 and 26–37 % of tagged individuals were associated with the same urchin after 3 and 7 days. Tagged fish also returned to their site of origin after displacement; by day two, 23–43 and 27–33 % of tagged individuals returned from displacement distances of 1 and 2 km. These results suggest that S. tubifer uses various environmental cues for homing and site fidelity; similar behaviors and cues might be used by larvae for recruitment to settlement sites and for the acquisition of luminous symbiotic bacteria.     

The Estuarine Component of the Us E.P.A.'S Environmental Monitoring and Assessment Program

The US Environmental Protection Agency's Office of Research and Development has initiated the Environmental Monitoring and Assessment Program (EMAP) to monitor status and trends in the condition of the nation's near coastal waters, forests, wetlands, agro-ecosystems, surface waters, deserts and rangelands. the programme is also intended to evaluate the effectiveness of Agency policies at protecting ecological resources occurring in these systems. Monitoring data collected for all ecosystems will be integrated for regional and national status and trends assessments. the near coastal component of EMAP consists of estuaries, coastal waters, and the Great Lakes. Near coastal ecosystems have been regionalized and classified, and an integrated sampling strategy has been developed. EPA and NOAA have agreed to coordinate and, to the extent possible, integrate the near coastal component of EMAP with the NOAA National Status and Trends Program. A demonstration project was conducted in estuaries of the mid-Atlantic region (Chesapeake Bay to Cape Cod) in the summer of 1990. in 1991, monitoring continued in mid-Atlantic estuaries and was initiated in estuaries of a portion of the Gulf of Mexico. Preliminary results indicate: there are no insurmountable logistical problems with sampling on a regional scale; several of the selected indicators are practical and sensitive on the regional scale; and an efficient effort in future years will provide valuable information on condition of estuarine resources at regional scales.     

Inspired to perform: A multilevel investigation of antecedents and consequences of thriving at work

Emerging research evidence across multiple industries suggests that thriving at work is critically important for creating sustainable organizational performance. However, we possess little understanding of how factors across different organizational levels stimulate thriving at work. To address this gap, the current study proposes a multilevel model that simultaneously examines contextual and individual factors that facilitate thriving at work and how thriving relates to positive health and overall unit performance. Analysis of data collected from 275 employees, at multiple time periods, and their immediate supervisors, representing 94 work units, revealed that servant leadership and core self‐evaluations are 2 important contextual and individual factors that significantly relate to thriving at work. The results further indicated that thriving positively relates to positive health at the individual level, with this relationship partially mediated by affective commitment. Our results also showed that collective thriving at work positively relates to collective affective commitment, which in turn, positively relates to overall unit performance. Taken together, these findings suggest that work context and individual characteristics play significant roles in facilitating thriving at work and that thriving is an important means by which managers and their organizations can improve employees' positive health and unit performance.     

Polycyclic aromatic hydrocarbon concentrations,mutagenicity, and Microtox® acute toxicity testing of Peruvian crude oil and oil-contaminated water and sediment

The oil industry is a major source of contamination in Peru, and wastewater and sediments containing oil include harmful substances that may have acute and chronic effects. This study determined polycyclic aromatic hydrocarbon (PAH) concentrations by GC/MS, mutagenicity using TA98 and TA100 bacterial strains with and without metabolic activation in the Muta-ChromoPlate? test, and Microtox® 5-min EC₅₀ values of Peruvian crude oil, and water and sediment pore water from the vicinity of San José de Saramuro on the Marañón River and Villa Trompeteros on the Corrientes River in Loreto, Peru. The highest total PAH concentration in both areas was found in water (Saramuro?=?210.15 μg/ml, Trompeteros?=?204.66 μg/ml). Total PAH concentrations in water from San José de Saramuro ranged from 9.90 to 210.15 μg/ml (mean?=?66.48 μg/ml), while sediment pore water concentrations ranged from 2.19 to 70.41 μg/ml (mean?=?24.33 μg/ml). All water samples tested from Saramuro and Trompeteros sites, and one out of four sediment pore water samples from Trompeteros, were found to be mutagenic (P?<?0.001). One sediment pore water sample in Saramuro was determined to have a measurable toxicity (Microtox EC₅₀?=?335.1 mg/l), and in Trompeteros, the EC₅₀ in water and sediment pore water ranged from 25.67 to 133.86 mg/l. Peruvian crude oil was mutagenic using the TA98 strain with metabolic activation, and the EC₅₀ was 17.18 mg/l. The two areas sampled had very high PAH concentrations that were most likely associated with oil activities, but did not lead to acute toxic effects. However, since most of the samples were mutagenic, it is thought that there is a greater potential for chronic effects.     

Simulating Unstressed Crop Development and Growth Using the Unified Plant Growth Model (UPGM)

Since initial development of the EPIC model in 1989, the EPIC plant growth component has been incorporated into other erosion and crop management models (e.g., WEPS, WEPP, SWAT, ALMANAC, and GPFARM) and subsequently modified to meet research objectives of the model developers. This has resulted in different versions of the same base plant growth component. The objectives of this study are the following: (1) describe the standalone Unified Plant Growth Model (UPGM), initially derived from the WEPS plant growth model, to be used for merging enhancements from other EPIC-based plant growth models; and (2) describe and evaluate new phenology, seedling emergence, and canopy height sub-models derived from the Phenology Modular Modeling System (PhenologyMMS V1.2) and incorporated into UPGM. A 6-year (2005–2010) irrigated maize (Zea mays L.) study from northeast Colorado was used to calibrate and evaluate UPGM running both the original (i.e., based on WEPS) and new phenology, seedling emergence, and canopy height sub-models. Model statistics indicated the new sub-models usually resulted in better simulation results than the original sub-models. For example when comparing original and new sub-models, respectively, for predicting canopy height, the root mean square error (RMSE) was 53.7 and 40.7 cm, index of agreement (d) was 0.84 and 0.92, relative error (RE) was 26.0 and ?1.26 %, and normalized objective function (NOF) was 0.47 and 0.33. The new sub-models predict leaf number (old sub-models do not), with mean values for 4 years of 2.43 leaves (RMSE), 0.78 (d), 18.38 % (RE), and 0.27 (NOF). Simulating grain yield, final above ground biomass, and harvest index showed little difference when running the original or new sub-models. Both the new phenology and seedling emergence sub-models respond to varying water deficits, increasing the robustness of UPGM for more diverse environmental conditions. Future research will continue working to incorporate existing enhancements from other EPIC-based plant growth models to unify them into one model such as multispecies competition and N cycling.     

A call for longitudinal research in positive organizational behavior

After defining and providing the current status of psychological capital (PsyCap), we address the need to better understand its stability (i.e., state vs. trait). Specifically, we issue a call for longitudinal research. The balance of this “incubator” article examines the relevance, potential obstacles, and advantages of this design in meeting PsyCap's future research needs. Copyright © 2008 John Wiley & Sons, Ltd.