LEHR superfund stormwater runoff and putah creek mercury issues

Stormwater runoff from the University of California, Davis/U.S. Department of Energy Laboratory for Energy‐Related Health Research (UCD/US DOE LEHR) Superfund site located on the University of California campus in Davis, California, has been found to contain over 500 ng/L of total recoverable mercury, which is about ten times the California Toxics Rule criterion. This stormwater runoff is discharged to Putah Creek, which is Clean Water Act Section 303(d) listed as impaired for excessive mercury bioaccumulation in edible fish. A discussion is presented on the potential impact of the mercury in stormwater runoff from LEHR leading to excessive bioaccumulation of mercury in Putah Creek fish. The mercury in the stormwater runoff is derived from former flooding of the soils near the creek, which contains mercury derived from abandoned upstream mercury mines located in the Coast Range Vaca Hills to the west of LEHR. The implications of this situation for implementing a Total Maximum Daily Load (TMDL) to control mercury in stormwater runoff to Putah Creek are presented. © 2009 Wiley Periodicals, Inc.     

The Effect of Masterbatch Addition on the Mechanical, Thermal, Optical and Surface Properties of Poly(lactic acid)

There has been considerable interest in the use of the biodegradable polymer poly(lactic acid) (PLA) as a replacement for petroleum derived polymers due to ease of processability and its high mechanical strength. Other material properties have however limited its wider application. These include its brittle properties, low impact strength and yellow tint. In an attempt to overcome these drawbacks, PLA was blended with four commercially available additives, commonly known as masterbatches. The effect of the addition of 1.5 wt% of the four masterbatches on the mechanical, thermal, optical and surface properties of the polymer was evaluated. All four masterbatches had a slight negative effect on the tensile strength of PLA (3–5% reduction). There was a four fold increase in impact resistance however with the addition of one of the masterbatches. Differential scanning calorimetry demonstrated that this increase corresponded to a decrease in the polymer crystallinity. However there was an associated increase in polymer haze with the addition of this masterbatch. The clarity of PLA was improved through the addition of an optical brightener masterbatch, but the impact resistance remained low. The glass transition and melting temperatures of PLA were not affected by the addition of the masterbatches, and no change was observed in surface energy. Some delay in PLA degradation, in a PBS degradation medium at 50 °C, was observed due to blending with these masterbatches.     

The contemporary cement cycle of the United States

A country-level stock and flow model for cement, an important construction material, was developed based on a material flow analysis framework. Using this model, the contemporary cement cycle of the United States was constructed by analyzing production, import, and export data for different stages of the cement cycle. The United States currently supplies approximately 80% of its cement consumption through domestic production and the rest is imported. The average annual net addition of in-use new cement stock over the period 2000–2004 was approximately 83 million metric tons and amounts to 2.3 tons per capita of concrete. Nonfuel carbon dioxide emissions (42 million metric tons per year) from the calcination phase of cement manufacture account for 62% of the total 68 million tons per year of cement production residues. The end-of-life cement discards are estimated to be 33 million metric tons per year, of which between 30% and 80% is recycled. A significant portion of the infrastructure in the United States is reaching the end of its useful life and will need to be replaced or rehabilitated; this could require far more cement than might be expected from economic forecasts of demand for cement.     

Factors influencing farmers’ decisions on nitrogen fertilizer application in the Liangzihu Lake basin,Central China

Overuse of nitrogen (N) fertilizers in agriculture activities has caused severe water pollution in China. The lack of data at producer level hampers decision makers in the development and implementation of efficient policies to curb excessive N-fertilizer use. In a survey of 300 farm households in the Liangzihu Lake basin, we identified factors associated with farmers’ decisions on N-fertilizer use and application rate. Household survey and multiple linear regression models indicate that the average application rate in the study region is 229 kg N ha^?1, which exceeds the recommended rate for maximum profit for cereal crops (maize, wheat, and rice) in China of 150–180 kg N ha^?1. High N-application rates are associated with low farmland productivity (coefficient = ?15.66, p = 0.02), a high share of off-farm income (coefficient = 27.14, p = 0.003), and a low education level of the household head (coefficient = ?10.83, p = 0.039). Neither physical infrastructure nor access to input markets appears to be related to N-application rates. It may be concluded that excessive use of N in agriculture of Central China is mainly a problem of insufficient awareness and high share of off-farm income.     

Effect of temperature and precipitation on linear increment of <Emphasis Type="Italic">Sphagnum fuscum</Emphasis> and <Emphasis Type="Italic">S. magellanicum</Emphasis> in Western Siberia

The linear increment of Sphagnum fuscum and S. magellanicum in ombrotrophic mires of Western Siberia has been measured during two years over a transect about 2500 km long extending from forest–steppe to forest–tundra. Along the latitudinal gradient, the increment of both species has proved to be correlated with annual average air temperature and, in S. magellanicum, also with annual precipitation. The determinants of their growth differ between the southern, central, and northern parts of the study region. At the regional level, the annual and summer precipitation plays a more important role than the average air temperature. The increment of S. fuscum in the southern part is positively correlated with the amount of precipitation and negatively correlated with summer temperature, whereas the situation in the central part is inverse. In S. magellanicum, the linear increment is directly dependent on the annual average temperature and annual and summer precipitation in the south and on the annual and summer precipitation in the north of Western Siberia. The dynamics of linear growth of both species in bog pine forests during the growing season are similar: its rate is the highest in June, when the linear increment of S. fuscum and S. magellanicum amounts to 60 and 85% of the annual total, respectively.     

Influence of experimental conditions on manifestation of the group effect in the gypsy moth, <Emphasis Type="Italic">Lymantria dispar</Emphasis> L.

The effect of rearing conditions for gypsy moth larvae on parameters of their development (its duration and mortality) was studied in experiments with early instar larvae reared singly or in groups. The manifestation of the group effect was analyzed depending on the choice of experimental unit (the larva or the rearing container) and the amount of volume per larva. The observed effects were evaluated quantitatively.     

Siberian musk deer in the diets of tiger and bears in the Sikhote-Alin

The role of the Siberian musk deer in the diets of the Amur tiger, brown bear, and Asian black bear has been studied in the Sikhote-Alin State Biosphere Reserve in 1992 to 2016. Information has been collected from 763 tiger feeding sites, and the contents of tiger feces have been analyzed. Radiotelemetry has been used to evaluate tiger–musk deer relationships. The musk deer accounted for 0.26% of all animal species found to be eaten by the tiger. Musk deer remains in feces of the tiger, brown bear, and Asian black bear occurred with frequencies of 1.3, 0.2, and 0.3%, respectively. A case of musk deer avoiding the presence of brown bear is described.     

Carbon fluxes from coarse woody debris in southern taiga forests of the Valdai Upland

Studies in three typical forest biotopes of the Valdai Upland were performed to evaluate the stocks and surface area of coarse woody debris from spruce and birch (in linear transects), its colonization by xylotrophic fungi (during reconnaissance surveys), and CO₂ emission (by a chamber method). The stock and surface area were minimum in a paludal birch forest (46.4 m³/ha and 960 m²/ha) and maximum in a decay area of spruce forest (256.1 m³/ha and 3761 m²/ha, respectively). The assemblages of wood-decay fungi had a composition typically found in southern taiga forests. The total CO₂ flux varied from 145 kg C-CO₂/ha per year in the paludal birch forest to 462 kg C-CO₂/ha per year in small herb–green moss spruce forest. It is concluded that air temperature is an informative predictor of seasonal C-CO₂ flux rate from coarse woody debris.     

Research priorities for managing the impacts and dependencies of business upon food,energy, water and the environment

Delivering access to sufficient food, energy and water resources to ensure human wellbeing is a major concern for governments worldwide. However, it is crucial to account for the ‘nexus’ of interactions between these natural resources and the consequent implications for human wellbeing. The private sector has a critical role in driving positive change towards more sustainable nexus management and could reap considerable benefits from collaboration with researchers to devise solutions to some of the foremost sustainability challenges of today. Yet opportunities are missed because the private sector is rarely involved in the formulation of deliverable research priorities. We convened senior research scientists and influential business leaders to collaboratively identify the top forty questions that, if answered, would best help companies understand and manage their food-energy-water-environment nexus dependencies and impacts. Codification of the top order nexus themes highlighted research priorities around development of pragmatic yet credible tools that allow businesses to incorporate nexus interactions into their decision-making; demonstration of the business case for more sustainable nexus management; identification of the most effective levers for behaviour change; and understanding incentives or circumstances that allow individuals and businesses to take a leadership stance. Greater investment in the complex but productive relations between the private sector and research community will create deeper and more meaningful collaboration and cooperation.     

When experts disagree: the need to rethink indicator selection for assessing sustainability of agriculture

Sustainability indicators are well recognized for their potential to assess and monitor sustainable development of agricultural systems. A large number of indicators are proposed in various sustainability assessment frameworks, which raises concerns regarding the validity of approaches, usefulness and trust in such frameworks. Selecting indicators requires transparent and well-defined procedures to ensure the relevance and validity of sustainability assessments. The objective of this study, therefore, was to determine whether experts agree on which criteria are most important in the selection of indicators and indicator sets for robust sustainability assessments. Two groups of experts (Temperate Agriculture Research Network and New Zealand Sustainability Dashboard) were asked to rank the relative importance of eleven criteria for selecting individual indicators and of nine criteria for balancing a collective set of indicators. Both ranking surveys reveal a startling lack of consensus amongst experts about how best to measure agricultural sustainability and call for a radical rethink about how complementary approaches to sustainability assessments are used alongside each other to ensure a plurality of views and maximum collaboration and trust amongst stakeholders. To improve the transparency, relevance and robustness of sustainable assessments, the context of the sustainability assessment, including prioritizations of selection criteria for indicator selection, must be accounted for. A collaborative design process will enhance the acceptance of diverse values and prioritizations embedded in sustainability assessments. The process by which indicators and sustainability frameworks are established may be a much more important determinant of their success than the final shape of the assessment tools. Such an emphasis on process would make assessments more transparent, transformative and enduring.