Mapping the contaminant plume of an abandoned hydrocarbon disposal site with geophysical and geochemical methods,Jiangsu, China

Environmental Science and Pollution Research - The management and remediation of abandoned hydrocarbon-contaminated sites require detailed information on the distribution of contaminant plumes. In...     

不同磁性金属丝对丙烷爆炸反应抑制机理研究

为探究不同材质金属丝自身磁性差异对抑制气体爆炸的影响,在密闭圆形管道中进行丙烷-空气爆炸实验,采取爆炸瞬态压力测试、产物组成色谱检测和数值模拟机理分析相结合的方法进行探究。结果表明:与填装非磁性铝丝组相比,铁磁性铁丝组爆炸压力峰值更低;产物中一氧化碳和二氧化碳含量减少,残余丙烷和生成烃类物质种类和含量均增多;模拟分析得到温度敏感性基元反应R96,R1,R334,R276,R396,R254促进温度升高,R104,R409,R19,R358抑制温度升高;铁磁性的铁丝可能由于自身的感应磁场效应使其抑制自由基反应较铝丝更为有效。研究方法将产物分析与数值模拟相结合,对分析爆炸特性和抑爆机理具有参考意义。     

Mesoporous silica synthesized from natural local kaolin as an effective adsorbent for removing of Acid Red 337 and its application in the treatment of real industrial textile effluent

Environmental Science and Pollution Research - This paper presents a synthesis of mesoporous silica (MS) from natural clay as a silica source using Pluronic L35 (EO11PO16EO11) as a...     

障碍物在分岔附近对瓦斯爆炸压力影响的实验研究*

为研究置障条件下不同分岔角度管道中瓦斯爆炸压力变化规律,采用长15 m、截面为160 mm×100 mm的矩形和直径160 mm的半圆形组成的拱形模拟巷道,通过改变分岔角附近障碍物的形状与阻塞比,研究瓦斯爆炸在30~45°与30~60°双分岔管道分岔角附近的压力变化规律。结果表明:瓦斯爆炸在30~45°和30~60°双分岔管道中,分岔角后2支管压力均有所增大,且45°和60°支管中压力变化较30°支管更加明显;障碍物位于30°分岔角后,当阻塞比为0.4时,障碍物形状对2~4测点爆炸压力的影响均表现为矩形最大,拱形次之,圆形最小;管道中矩形障碍物对2,3测点爆炸压力的影响随阻塞比增加而增大,对测点4爆炸压力的影响则随阻塞比的增加而减小;设置矩形障碍物时,30~45°双分岔管道中2,3测点的压力增幅大于30~60°双分岔管道,且压力增幅随阻塞比增加而增大,而测点4的表现则相反,30~60°双分岔管道大于30~45°双分岔管道,且压力增幅随阻塞比增加而减小。     

An implicit wetting–drying algorithm for the discontinuous Galerkin method: application to the Tonle Sap,Mekong River Basin

Environmental Fluid Mechanics - The accurate simulation of wetting–drying processes in floodplains and coastal zones is a challenge for hydrodynamic modelling, especially for long time...     

生活垃圾填埋气中甲烷短期产生时空变化规律探究

采用自制垃圾填埋甲烷测量装置对衡阳某垃圾处理站临时堆放的处于发酵期的垃圾开展浓度测定试验,探究垃圾填埋气中甲烷在短期内产生的时空规律。结果表明：填埋场中甲烷浓度存在明显的气体分层现象,其浓度主要与纵向填埋深度呈正相关,与距填埋场边界的水平距离呈负相关;填埋初期,距离地表越近,同一水平方向甲烷浓度在不同区域变化较大,随着填埋时间的增长其浓度变化趋于稳定;填埋场内部温度与垃圾埋深和外界温度成线性相关,并且与垃圾埋深成反比,与外界温度成正比。     

Simultaneous determination of iprodione,procymidone, and chlorflurenol in lake water and wastewater matrices by GC-MS after multivariate optimization of binary dispersive liquid-liquid microextraction

This study reports the optimization of a binary dispersive liquid-liquid microextraction method for the determination of iprodione, procymidone, and chlorflurenol by gas chromatography mass spectrometry. The study was aimed at using two extraction solvents to increase the extraction efficiency of all analytes. The binary solvents recorded results higher than the mono-solvents. After examining the effects of main experimental parameters and their interactions by analysis of variance, 200 μL of binary mixture (dichloromethane and 1,2-dichloroethane), 2.5 mL of ethanol, and 15 s vortex were obtained as optimum parameters. The detection and quantification limits calculated for the analytes were found to be between 0.30–1.6 and 1.0–5.3 ng/mL, respectively. Enhancement in detection power calculated as a ratio of the binary extraction detection limit to the detection limit of direct GC-MS analysis was 105-, 214-, and 233-fold for chlorflurenol, iprodione, and procymidone, respectively. In order to check the accuracy of the developed method, recovery study was performed. Water sampled from a lake and two wastewater samples from treatment facilities were spiked at two concentrations, and the percent recovery calculated for the samples ranged between 87 and 116%. These results confirmed the suitability of the method to real samples for accurate determination of the analytes at trace levels.     

基于等级-网络分析框架的泛长江三角洲中心城市评价研究

城市中心性既体现在城市的等级位序,亦表现为城市在网络体系中的节点连通性以及节点之间的“流”强度。将区域城市等级体系和关系网络研究相结合,是城市体系理论与实践研究可探索的方向。以泛长江三角洲52个城市为研究对象,通过中心城市指数表征城市的等级中心性,企业网络联系测度城市的网络中心性,结合城市的等级中心性和网络中心性特征进行中心城市评价。将泛长江三角洲地区中心城市划分为了5个等级和7种类型,分别是：1个全球城市:上海;3个国家中心城市:杭州、南京、苏州;温州等6个区域等级中心城市;宁波等8个区域网络枢纽城市;盐城等8个地区等级中心城市;淮北等6个地区网络枢纽城市以及19个地方一般城市。基于对中心城市的类型划分,可进一步研究提出针对不同类型城市的分类引导政策。通过提升基础设施连通度、延伸产业链等措施来提升等级中心性较高城市的系统开放性;通过强化要素资源集聚,提高城市服务水平等促进关系网络枢纽城市的等级水平。 关键词： 中心城市;等级体系;关系网络;泛长江三角洲     

Co-Creating Green Transition: How Municipality Employees Negotiate their Professional Identities as Agents of Citizen Involvement in a Cross-Local Setting

Citizen involvement plays an important role in many governmental and municipal attempts towards green transition, reflecting a departure from a deficit model of public communication towards participatory ambitions of engaging citizens. Recently, the notion of co-creation or co-production has gained importance as a way of conceptualizing and organizing citizen involvement. The current study examines how four municipality partners in Sweden and Denmark embark on a common project on citizen involvement and co-creation as an avenue to green transition, addressing private decisions of individual citizens or families where the municipality has no legislative competence. By analysing how several local authorities with different but similar challenges negotiate and jointly identify themselves as agents of citizen involvement, the study offers an upscaling to what may be termed the plura-local level. Analytically, the study takes a discourse approach, combining close readings of texts and talk with an interdiscursive and diachronic analysis.     

Moderation effect of planning on housing development along the French Atlantic coast: findings from an event history hazard model

Laws and bylaws are regularly challenged for their effectiveness in containing urbanisation sprawl and, conversely, for the constraints they put on development projects. From a French case study, we used survival analysis to disentangle a complex mix of influences on the distribution of residential construction over a 42-year observation period at plot scale when almost everything changes simultaneously. We found that integrated laws and bylaws can slow down coastal urbanisation but do not stop it. Although land planning is becoming more effective, it still provides ample opportunity for residential development because other factors, like distance to existing infrastructure, exert a far stronger influence than the protection of coastal areas. Therefore, this article contributes to filling a knowledge gap about the founding role of public policies on land use dynamics.