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Gabriela Scheibel Cassol Chii Shang Juan Li Li Ling Xin Yang Ran Yin 《环境科学学报(英文版)》2022,34(7):119-128
Drinking water utilities are interested in upgrading their treatment facilities to enhance micropollutant removal and byproduct control. Pre-oxidation by chlorine dioxide (ClO2) followed by coagulation-flocculation-sedimentation and advanced oxidation processes (AOPs) is one of the promising solutions. However, the chlorite (ClO2–) formed from the ClO2 pre-oxidation stage cannot be removed by the conventional coagulation process using aluminum sulfate. ClO2– negatively affects the post-UV/chlorine process due to its strong radical scavenging effect, and it also enhances the formation of chlorate (ClO3–). In this study, dosing micromolar-level ferrous iron (Fe(II)) into aluminum-based coagulants was proposed to eliminate the ClO2– generated from ClO2 pre-oxidation and benefit the post-UV/chlorine process in radical production and ClO3– reduction. Results showed that the addition of 52.1-µmol/L FeSO4 effectively eliminated the ClO2– generated from the pre-oxidation using 1.0 mg/L (14.8 µmol/L) of ClO2. Reduction of ClO2– increased the degradation rate constant of a model micropollutant (carbamazepine) by 55.0% in the post-UV/chlorine process. The enhanced degradation was verified to be attributed to the increased steady-state concentrations of HO· and ClO· by Fe(II) addition. Moreover, Fe(II) addition also decreased the ClO3– formation by 53.8% in the UV/chlorine process and its impact on the formation of chloro-organic byproducts was rather minor. The findings demonstrated a promising strategy to improve the drinking water quality and safety by adding low-level Fe(II) in coagulation in an advanced drinking water treatment train. 相似文献
24.
Adriana Melo Jousilene de Sales Tavares Marianny de Assis Costa Renato Santana de Aguiar Gustavo Malinger Fabiana de Oliveira Melo Mariana Balbino da-Silva Bruno Luiz Fonseca Schamber-Reis Gabriela Gama Amilcar Tanuri Leila Chimelli Patricia Oliveira-Szejnfeld Melania M. Ramos de Amorim 《黑龙江环境通报》2020,40(13):1732-1740
25.
Astrid Wetzel Gabriela Klante D. Werner 《Umweltwissenschaften und Schadstoff-Forschung》1991,3(5):266-271
Im Zusammenhang mit der Umweltchemikalienprüfung und der Untersuchung und Kontrolle kontaminierter B?den besteht gro?er Bedarf
an Testverfahren mit h?heren Pflanzen, die schnell, einfach und preisgünstig durchzuführen sind und bereits bestehende Testverfahren
nach OECD- und BBA-Richtlinien sinnvoll erg?nzen k?nnen. Dieser Beitrag stellt einen Biotoxizit?tstest vor, der die Nodulation
in der Leguminosen-Kn?llchen-Symbiose als sensiblen Wirkungsparameter für die Belastung mit polyzyklischen aromatischen Kohlenwasserstoffen
(PAK) benutzt. Fremdstoff, Pflanze und Mikroorganismus werden dabei auf einer festen Matrix in Kontakt miteinander gebracht;
das axenische System erlaubt die Untersuchung der Fremdstoffwirkung sowohl auf den Gesamtorganismus Pflanze, als auch auf
die Interaktion von Pflanze und Mikroorganismus (Kn?llchenbildung). In Dose-Response-Versuchen zeigte sich der Wirkungsparameter
Nodulation, gemessen als Anzahl Wurzelkn?llchen pro Pflanze, sensibler als andere pflanzliche Wachstumsparameter.
There is great need for toxicity tests with higher plants for the investigation and monitoring of chemicals in the environment
— especially for tests which are quick, easy, and inexpensive. Such tests should add to and improve current guidelines, e.g.,
OECD- and BBA-Guidelines. This article describes the nodulation of leguminous plants withRhizobium bacteria used in a bioassay with polycyclic aromatic hydrocarbons (PAH). Plants growing on a solid medium were exposed simultaneously
to bacteria and PAH. This axenic culture system allows to observe the impact of PAH on plant growth and the interaction between
plant and bacteria (nodulation). Dose-response-experiments indicated that nodulation measured as number of nodules per plant,
was more sensitive to the inhibition by PAH than other plant growth parameters. 相似文献
26.
Baselines for land-use change in the tropics: application to avoided deforestation projects 总被引:2,自引:0,他引:2
Sandra Brown Myrna Hall Ken Andrasko Fernando Ruiz Walter Marzoli Gabriela Guerrero Omar Masera Aaron Dushku Ben DeJong Joseph Cornell 《Mitigation and Adaptation Strategies for Global Change》2007,12(6):1001-1026
Although forest conservation activities, particularly in the tropics, offer significant potential for mitigating carbon (C)
emissions, these types of activities have faced obstacles in the policy arena caused by the difficulty in determining key
elements of the project cycle, particularly the baseline. A baseline for forest conservation has two main components: the
projected land-use change and the corresponding carbon stocks in applicable pools in vegetation and soil, with land-use change
being the most difficult to address analytically. In this paper we focus on developing and comparing three models, ranging
from relatively simple extrapolations of past trends in land use based on simple drivers such as population growth to more
complex extrapolations of past trends using spatially explicit models of land-use change driven by biophysical and socioeconomic
factors. The three models used for making baseline projections of tropical deforestation at the regional scale are: the Forest
Area Change (FAC) model, the Land Use and Carbon Sequestration (LUCS) model, and the Geographical Modeling (GEOMOD) model.
The models were used to project deforestation in six tropical regions that featured different ecological and socioeconomic
conditions, population dynamics, and uses of the land: (1) northern Belize; (2) Santa Cruz State, Bolivia; (3) Paraná State,
Brazil; (4) Campeche, Mexico; (5) Chiapas, Mexico; and (6) Michoacán, Mexico.
A comparison of all model outputs across all six regions shows that each model produced quite different deforestation baselines.
In general, the simplest FAC model, applied at the national administrative-unit scale, projected the highest amount of forest
loss (four out of six regions) and the LUCS model the least amount of loss (four out of five regions). Based on simulations
of GEOMOD, we found that readily observable physical and biological factors as well as distance to areas of past disturbance
were each about twice as important as either sociological/demographic or economic/infrastructure factors (less observable)
in explaining empirical land-use patterns.
We propose from the lessons learned, a methodology comprised of three main steps and six tasks can be used to begin developing
credible baselines. We also propose that the baselines be projected over a 10-year period because, although projections beyond
10 years are feasible, they are likely to be unrealistic for policy purposes. In the first step, an historic land-use change
and deforestation estimate is made by determining the analytic domain (size of the region relative to the size of proposed
project), obtaining historic data, analyzing candidate baseline drivers, and identifying three to four major drivers. In the
second step, a baseline of where deforestation is likely to occur–a potential land-use change (PLUC) map—is produced using
a spatial model such as GEOMOD that uses the key drivers from step one. Then rates of deforestation are projected over a 10-year
baseline period based on one of the three models. Using the PLUC maps, projected rates of deforestation, and carbon stock
estimates, baseline projections are developed that can be used for project GHG accounting and crediting purposes: The final
step proposes that, at agreed interval (e.g., about 10 years), the baseline assumptions about baseline drivers be re-assessed.
This step reviews the viability of the 10-year baseline in light of changes in one or more key baseline drivers (e.g., new
roads, new communities, new protected area, etc.). The potential land-use change map and estimates of rates of deforestation
could be re-done at the agreed interval, allowing the deforestation rates and changes in spatial drivers to be incorporated
into a defense of the existing baseline, or the derivation of a new baseline projection. 相似文献
27.
Flower fluorescence has been previously proposed as a potential visual signal to attract pollinators. In this work, this point was addressed by quantitatively measuring the fluorescence quantum yield (Φ f) for flowers of Bellis perennis (white, yellow, pink, and purple), Ornithogalum thyrsoides (petals and ovaries), Limonium sinuatum (white and yellow), Lampranthus productus (yellow), Petunia nyctaginiflora (white), Bougainvillea spectabilis (white and yellow), Antirrhinum majus (white and yellow), Eustoma grandiflorum (white and blue), Citrus aurantium (petals and stigma), and Portulaca grandiflora (yellow). The highest values were obtained for the ovaries of O. thyrsoides (Φ f?=?0.030) and for Citrus aurantium petals (Φ f?=?0.014) and stigma (Φ f?=?0.013). Emitted photons as fluorescence were compared with reflected photons. It was concluded that the fluorescence emission is negligible compared to the reflected light, even for the most fluorescent samples, and it may not be considered as an optical signal in biocommunication. The work was complemented with the calculation of quantum catches for each studied flower species to describe the visual sensitization of eye photoreceptors. 相似文献
28.
Teresa Pamatz-Bolaños Denis A. Cabrera-Munguia Horacio González Rosa E. Del Río José L. Rico Gabriela Rodríguez-García 《International Journal of Green Energy》2018,15(8):465-472
Caesalpinea eriostachys seed oil, as a source of triglycerides with potential application for biodiesel production in Mexico is introduced. Its lipid profile obtained by Gas Chromatography-Mass Spectrometry (GC-MS) revealed saturated and unsaturated glycerol esters as the constituents. Therefore, heterogeneous and homogeneous catalyzed transesterification reactions were assayed employing ZnAl hydrotalcites and KOH, as the catalysts, respectively. The transesterification reactions yielded 59% for Zn/Al(2), 79% for Zn/Al(4), and 90% for KOH, depicting typical behavior, as in biodiesel production data from literature, where Zn-Al hydrotalcites or KOH were assayed. The caloric, density, viscosity values, and fatty acid methyl esters profile from reaction products were concordant to EN 14214, suggesting C. eriostachys as a promising feedstock for biodiesel production. 相似文献
29.
Rafael C. Lajmanovich Juan Carlos Sánchez-Hernández Paola M. Peltzer Andrés M. Attademo Gabriela S. Fiorenza Mariana C. Cabagna 《毒物与环境化学》2013,95(6):1145-1161
We determined the normal levels of butyrylcholinesterase (BChE), carboxylesterase (CbE), and glutathione S-transferases (GST) activities in three South American toad species in order to establish reference values for field pesticide monitoring purposes. Interspecies variations in B-esterase and GST activities were examined according to body mass. In addition, comparative inhibition of BChE and CbE activities using malaoxon, and chemical reactivation of malaoxon-inhibited BChE activity using pyridine-2-aldoxime methochloride (2-PAM) were investigated. Bufo fernandezae had average activity values for BChE: 17.31 mmol min?1 ml?1; CbE: 621.49 nmol min?1 ml?1 and GST: 1.94 mmol min?1 ml?1 while B. arenarum enzymatic average activities were BChE: 9.51 mmol min?1 ml?1; CbE: 270.07 nmol min?1 ml?1, and GST: 1.59 mmol min?1 ml?1; finally Bufo schneideri had enzymatic mean values of BChE: 2.08 mmol min?1 ml?1; CbE: 301.95 nmol min?1 ml?1, and GST: 1.60 mmol min?1 ml?1. Moreover, we found an allometric relationship between plasma BChE and CbE activities and body size for the three toad species. We suggest that B. fernandezae would be the species with a higher tolerance capacity to organophosphorous insecticides compared to the other toad species, while B. schneideri may be the most vulnerable toad species to field pesticide exposure, although some other factors (e.g., brain AChE sensitivity or pesticide metabolism by phosphotriesterases) should be also taken into account. The malaoxon-inhibited BChE activity of the three toad species was reactivated in the presence of 2-PAM, and it is recommended as a specific and sensitive methodology in the assessment of field exposure to OP insecticides together to compare BChE activity levels between OP-exposed and nonexposed individuals. 相似文献
30.
Fumian Tulio Machado Ferreira Fernando César de Andrade Juliana da Silva Ribeiro Canal Natália Silva Gomes Gabriela Teixeira Lilian Borges Miagostovich Marize Pereira 《Food and environmental virology》2021,13(4):553-559
Food and Environmental Virology - Norovirus is a major cause of foodborne-associated acute gastroenteritis (AGE) outbreaks worldwide. Usually, food products are contaminated either during... 相似文献