BaO/γ-Al2O3同时吸附脱除一氧化氮和二氧化硫

利用固定床连续流动反应器研究了BaO／γ—Al2O，同时吸附模拟烟气中NO和SO2的工艺条件和再生循环使用性能，对BaO／γ—Al2O3进行了比表面积和程序升温表面反应（TPSR）等表征分析。结果表明，BaO／γ—Al2O3的适宜工艺条件是SO2与NO体积比为2．9～8．4、原料气中O2体积分数大于4．5％、吸附温度448～523K。BaO／γ—Al2O3在循环使用过程中吸附能力下降。与NOXSO吸附催化剂Na2CO3／γ—Al2O3相比，BaO／γ-Al2O3同时吸附SO2和NO的能力大、再生循环使用性能好、适宜的SO2与NO体积比范围宽、热稳定性好。将BaO／γ—Al2O3应用于NOXSO工艺可望提高该工艺的脱硫、脱氮效率。     

Effectiveness of resistivity monitoring for interpreting temporal changes in landfill properties

It is always possible for impermeable layers to exist in landfills. When they do, the properties of the solution at the exit of the leachate-collection system might not accurately reflect the overall properties of the landfill. This study examines whether resistivity monitoring is effective for determining the influence of impermeable layers on the leachate. The test cell used in this study was filled with waste made up mainly of incinerator ash and shredded incombustible material. Three lines of resistivity sensors were laid in the uppermost layer of the fill. A resistivity profile was recorded periodically from each of these lines. The water-table level and leachate properties were measured concurrently. Leachate conductivity was mainly controlled by concentrations of the main ions, and it correlated inversely to variations in resistivity. Temporal changes in the resistivity of the fills are an excellent means of assessing the leaching in fills. Monitoring the properties of leachate, combined with resistivity profiling, is extremely useful for interpreting the temporal changes of properties in landfills containing impermeable layers.     

自然生态小区建设指导原则及其建设内容探讨--以筠连县大雪山自然生态小区为例

自然生态小区是构建优美生态环境区域的生态“细胞工程”。它根据当地的自然状况和社会经济状况,以较小的经济和社会代价实现一定区域生态环境优美、生态文明有序、生态系统良性循环的社会经济生态综合体。由于自然生态小区的建设是新兴事物,其建设途径还有很多问题值得探讨。在自然生态小区建设投资方面,应当明确生态环境建设投资和生产赢利建设投资,对于前者应当以政府和政策性投资为主,而后者应当是在政策法规规范下的企业投资为主;在发展模式方面,应当促进环境友好的规模化高效益产业,包括有机绿色产业、地方特色产业、民族文化产业等;在效益分配方面,必须要充分考虑整个社区居民资源共享和利益合理分配,实现整个社区生态文明建设和经济发展目标的一致。     

对排污权交易的现实思考

排污权交易作为一种制度,在我国尚未完全建立.在准市场机制调整之下的排污权交易市场具有比现行排污收费制度更合理之处.排污权交易制度的目的在于逐步减少污染排放,而非刺激排污.其具有的激励和资源配置功能,不仅能较好地控制排污总量,还能提供更丰富的控制污染的方法和途径.公众甚至可以直接参与对环境的管理.本文作者试图从经济学和竞争法的角度对排污权交易的现实问题作一浅显分析.     

用微波消解-光度法测定废钻井液中的总铬

采用微波消解-光度法处理钻井液废水中的总铬。该方法克服了常规消解方法的缺点,测定步骤简单、快速,准确性高。通过实验探讨了微波功率、加热时间、样品体积对样品消解的影响。与常压的硫酸-硝酸消解法进行比较的结果表明,用微波消解-光度法处理泥浆废水可将消解时间由原来的6h缩短为20min,加标回收率由60%提高到92%,降低了工作强度,改善了工作环境。     

沉水植物对富营养化水体的净化效果研究

通过建立小型围隔区,研究了沉水植物对富营养化水体中氮、磷等污染物的净化效果,以及对底泥中磷含量的影响.结果表明:(1)在放养沉水植物的围隔水体中各种营养盐浓度明显低于对照围隔;(2)沉水植物对磷的吸收能够有效地保持底泥中磷的含量,而在对照围隔中的底泥中磷元素含量却不断增加;(3)经50天后,水体中TN、NH4 -N、TP、PO43--P和CODMn平均去除率分别为36.3%、70.5%、54.6%、65.4%和43.1%.     

化学法处理电镀废水的自动化控制应用

采用化学法自动控制处理含铬和含镍电镀废水,选择合适的化学药剂和pH、ORP控制参数,连续式处理电镀废水.运行结果表明:该工艺简单、处理效果良好、运行稳定、可操作性好、运行成本适中、能很好的适应水质的波动,处理后的水质完全符合排放标准.     

Use of Microbial Community to Evaluate Performance of a Wetland System in Treating Pb/Zn Mine Drainage

The performance of a wetland system in treating lead (Pb)/zinc (Zn) mine drainage was evaluated by using the polyurethane foam unit (PFU) microbial community (method), which has been adopted by China as a standardized procedure for monitoring water quality. The wetland system consisted of four cells with three dominant plants: Typha latifolia, Phragmites australis and Paspalum distichum. Physicochemical characteristics [pH, EC, content of total suspended solid (TSS) and metals (Pb, Zn, Cd, and Cu)] and PFU microbial community in water samples had been investigated from seven sampling sites. The results indicated that the concentrations of Pb, Zn, Cd, Cu, and TSS in the mine drainage were gradually reduced from the inlet to the outlet of the wetland system and 99%, 98%, 75%, 83%, and 68% of these metals and TSS respectively, had been reduced in concentration after the drainage passed through the wetland system. A total of 105 protozoan species were identified, the number of protozoa species and the diversity index (DI) gradually increased, while the heterotrophic index (HI) gradually decreased from the inlet to the outlet of the wetland system. The results indicated that DI, HI, and total number species of protozoa could be used as biological indicators indicating the improvement of water quality.     

Removal of selenate from water by zerovalent iron

Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. In this study, ZVI was used to remove selenate [Se(VI)] at a level of 1000 microg L(-1) in the presence of varying concentrations of Cl-, SO(2-)4, NO(-)3, HCO(-)3, and PO(3-)4. Results showed that Se(VI) was rapidly removed during the corrosion of ZVI to iron oxyhydroxides (Fe(OH)). During the 16 h of the experiments, 100 and 56% of the added Se(VI) was removed in 10 mM Cl- and SO(2-)4 solutions under a closed contained system, respectively. Under an open condition, 100 and 93% of the added Se(VI) were removed in the Cl- and SO(2-)4 solutions, respectively. Analysis of Se species in ZVI-Fe(OH) revealed that selenite [Se(IV)] and nonextractable Se increased during the first 2 to 4 h of reaction, with a decrease of Se(VI) in the Cl- experiment and no detection of Se(VI) in the SO(2-)4 experiment. Two mechanisms can be attributed to the rapid removal of Se(VI) from the solutions. One is the reduction of Se(VI) to Se(IV), followed by rapid adsorption of Se(IV) to Fe(OH). The other is the adsorption of Se(VI) directly to Fe(OH), followed by its reduction to Se(IV). The results also show that there was little effect on Se(VI) removal in the presence of Cl- (5, 50, and 100 mM), NO(-)3 (1, 5, and 10 mM), SO(2-)4 (5 mM), HCO(-)3 (1 and 5 mM), or PO(3-)4 (1 mM) and only a slight effect in the presence of SO(2-)4 (50 and 100 mM), HCO(-)3 (10 mM), and PO(3-)4 (5 mM) during a 2-d experiment, whereas 10 mM PO(3-)4 significantly inhibited Se(VI) removal. This work suggests that ZVI may be an effective agent to remove Se from Se-contaminated agricultural drainage water.     

Quantification of intrinsic water use efficiency along a moisture gradient in Northeastern China

Water use efficiency (WUE) is an important ecophysiological characteristic of plants, especially in semiarid and arid regions. At the scale of community or ecosystem, WUE is difficult to quantify because the amount of water used per unit dry mass production is a function of microclimatic variables and species composition. In this study, we analyzed corrected intrinsic water use efficiency (IWUE(s)) of grass and shrub species along the western segment of the Northeast China Transect (NECT) and the relationship between IWUE(s) and mean annual rainfall, habitat degradation status, vegetation type, and plant functional type (C3 versus C4) at 22 survey sites. Site intrinsic water use efficiency (IWUE(v)) and its relationship with the aforementioned site variables were analyzed based on species frequencies at each site. First, it was concluded that photosynthetic pathway played a very important role in determining species IWUE(s). Mean IWUE(s) for C4 species was approximately double that of C3 species. Second, mean annual rainfall, vegetation type, and site degradation status significantly affected IWUE(s) (p < 0.01). Mean IWUE(s) at degraded sites was twice as high as that at nondegraded sites. The mean IWUE(s) for meadows was significantly higher than those for other vegetation types (p < 0.05). Third, the frequency of occurrence of C4 plants explained 36% of the variance in IWUE(v) across the survey sites. The mean frequency of C4 occurrence at degraded sites was more than double that at nondegraded sites. Consequently, mean IWUE(v) at degraded sites was more than double that at nondegraded sites. Dominant C4 species in saline-alkaline areas tended to have higher intrinsic WUE than dominant C4 species in sandy shrub communities.