Influence of H2S and NH3 on biogas dry reforming using Ni catalyst: a study on single and synergetic effect

● NH₃ in biogas had a slight inhibitory effect on dry reforming. ● Coexistence of H₂S and NH₃ led to faster decline of biogas conversion. ● Regeneration was effective for catalysts deactivated under synergetic effect. Biogas is a renewable biomass energy source mainly composed of CH₄ and CO₂. Dry reforming is a promising technology for the high-value utilization of biogas. Some impurity gases in biogas can not be completely removed after pretreatment, which may affect the performance of dry reforming. In this study, the influence of typical impurities H₂S and NH₃ on dry reforming was studied using Ni/MgO catalyst. The results showed that low concentration of H₂S in biogas could cause serious deactivation of catalyst. Characterization results including EDS, XPS and TOF-SIMS confirmed the adsorption of sulfur on the catalyst surface, which was the cause of catalyst poisoning. We used air calcination method to regenerate the sulfur-poisoned catalysts and found that the regeneration temperature higher than 500 °C could help catalyst recover the original activity. NH₃ in the concentration range of 50–10000 ppm showed a slight inhibitory effect on biogas dry reforming. The decline rate of biogas conversion efficiency increased with the increase of NH₃ concentration. This was related to the reduction of oxygen activity on catalyst surface caused by NH₃. The synergetic effect of H₂S and NH₃ in biogas was investigated. The results showed that biogas conversion decreased faster under the coexistence of H₂S and NH₃ than under the effect of H₂S alone, so as the surface oxygen activity of catalyst. Air calcination regeneration could also recover the activity of the deactivated catalyst under the synergetic effect of H₂S and NH₃.     

塔里木油田库尔勒生活基地生活垃圾处理现状与对策探讨

对塔里木油田库尔勒生活基地生活垃圾的处理现状和主要构成进行调查后,结合所在城市生活垃圾的处理方式,提出库尔勒生活基地生活垃圾"分类收集与回收利用"的途径,分析了实施中可能存在的问题,探讨了具体的对策,强调要从加强环保宣传、明确管理部门责任、完善回收设施、采用半市场化处理的对策思路。     

滑坡灾害风险区划与预测研究综述

对前人关于滑坡灾害风险区划与预测研究的成果进行了分析概括,同时,也指出了存在5个方面的问题。根据我国国土在地形地貌上存在"南北分区,东西分带,交叉成网",及今后随着社会经济不断向地质环境条件恶劣的山区与海岸带发展、滑坡灾害的威胁和可能受到滑坡灾害威胁的地区将进一步增加的特点,指出面对严峻的滑坡灾害,传统的以单个滑坡机理研究和整治为目的的方法和手段在减轻滑坡灾害方面已显得力不从心,区域性的、超前性的预测研究已迫在眉睫。     

城镇社区地震应急工作模式的建立

社区地震应急工作是我国地震应急管理工作的重要内容之一,是减轻地震灾害的有效途径。如何依托社区开展地震应急工作是近年来,特别是汶川地震后全社会关注的问题。从地震应急组织管理、应急预案、志愿者队伍建设、宣传培训、应急演练、物资储备、避难场地和疏散通道设置以及地震应急处置等几个方面讨论了社区地震应急工作模式。     

地震人员伤亡快速评估模型研究

每年地震都会给社会造成巨大人员伤亡,如果震后能迅速预知地震人员伤亡数量,这对挽救生命损失是十分有意义的。统计了近10年来中国大陆数10次强震、中强震灾害损失,根据影响伤亡的主要因素,用线性回归分析法,建立地震人员伤亡快速评估模型,并对模型进行验证,使之可用于地震预警。     

植筋搭接混凝土柱偏心受压性能试验研究

对钢筋混凝土植筋搭接柱在静载作用下的偏心受压破坏进行了探索性的研究。通过试验,得到了试验柱的承载力与锚固长度、跨中弯矩与挠度、荷载与位于搭接段跨中截面受压区混凝土应变等关系曲线。试验结果认为,钢筋混凝土搭接柱在混凝土未被压坏的前提下,发生的钢筋锚固失效主要是锚固强度失效,并确认了植筋试件的薄弱面。另外,试件破坏时的粘结应力随锚固长度的增加逐渐减小。而对FISV360S植筋胶来说,锚固长度的增加能明显地提高试验梁的极限承载力。最后分别提出了临界锚固长度计算公式和试验柱极限承载力计算公式。     

Emission control for precursors causing acid rain (V): Improvement of acid soil with the bio-briquette combustion ash

The bio-briquette technique which mixes coal, biomass and sulfur fixation agent and bio-briquettes under 3-5 t/cm^2 line pressure has aroused people‘s attention in view of controlling the air pollution and the acid rain. In this paper, the physicochemical properties of bio-briquette and its ash were investigated. And the acid soil was improved by the bio-briquette combustion ash, which contained nutritive substances such as P, N, K and had the acid-neutralizing capacity(ANC). The pH, EC, effective nutrient elements(Ca, Mg, K, P and N), heavy metal elements(AI, Cu, Cd, Cr, Zn and Mn) and acid-neutralizing capacity change of ash-added soils within the range of 0-10%, were also studied. Specially, when 5% bio-briquette combustion ash was added to the tested soil, the content of the effective elements such as Ca, Mg and K rose by 100 times, ? times and twice, respectively. The total nitrogen also increased by about twice. The results showed the oxyanions such as that of AI, Cu, Cd, Cr, Zn and Mn were not potentially dangerous, because they were about the same as the averages of them in Chinese soil. It is shown that the ANC became stronger, though the ANC hardly increases in the ash-added soil. On the basis of the evaluation indices, it is concluded that the best mixture ratio is to add 2.5%--8% of the bio-briquette combustion ash to the tested soil.     

Biological removal of methanol from process condensate for the purpose of reclamation

The biological removal of methanol from condensate of ammonia manufacturing processes for the purpose of reclamation using contact type reactor was studied. Methanol of 60 mg/L was removed completely under an HRT of 1.12 h. Optimal inorganic nutrient dose was determined on evaluating methanol removal performance and dehydrogenase activities (DHA) under different nutrition doses. The optimal inorganic nutrient dose only gave an increase of conductivity of ca. 10μs/cm^2 in the effluent on treating synthetic condensate containing methanol of 30mg/L. The results demonstrated that biological removal of methanol was effective for the purpose of recovering the methanol-bearing condensate.     

原料转运站除尘系统设计及应用

针对原料转运站除尘系统常见问题,结合工程实例,从管网系统设计、除尘器选型、系统控制及日常维护等方面阐述解决方法。     

便携式GC-MS在石油污染土壤应急监测中的应用

针对石油污染土壤中VOCs含量的应急监测,便携式气相色谱-质谱联用仪适用于土壤中甲苯、乙苯、二甲苯、三氯苯等13种苯系物的快速定量检测,通过对某废弃炼油厂土壤样品测定,该方法在快速定性的同时,定量测定5~20411μg/kg土壤样品具有很高的可靠性。