Determination of selected semi-volatile organic compounds in water using automated online solid-phase extraction with large-volume injection/gas chromatography/mass spectrometry

A rapid, sensitive, and cost-effective analytical method was developed for the analysis of selected semi-volatile organic compounds in water. The method used an automated online solid-phase extraction technique coupled with programmed-temperature vaporization large-volume injection gas chromatography/mass spectrometry. The water samples were extracted by using a fully automated mobile rack system based on x-y-z robotic techniques using syringes and disposable 96-well extraction plates. The method was validated for the analysis of 30 semivolatile analytes in drinking water, groundwater, and surface water. For a sample volume of 10 mL, the linear calibrations ranged from 0.01 or 0.05 to 2.5 μg·L⁻¹, and the method detection limits were less than 0.1 μg·L⁻¹. For the reagent water samples fortified at 1.0 μg·L⁻¹ and 2.0 μg·L⁻¹, the obtained mean absolute recoveries were 70%–130% with relative standard deviations of less than 20% for most analytes. For the drinking water, groundwater, and surface water samples fortified at 1.0 μg·L⁻¹, the obtained mean absolute recoveries were 50%–130% with relative standard deviations of less than 20% for most analytes. The new method demonstrated three advantages: 1) no manipulation except the fortification of surrogate standards prior to extraction; 2) significant cost reduction associated with sample collection, shipping, storage, and preparation; and 3) reduced exposure to hazardous solvents and other chemicals. As a result, this new automated method can be used as an effective approach for screening and/or compliance monitoring of selected semi-volatile organic compounds in water.     

Accident risk of foreign drivers in various road environments

INTRODUCTION: This paper reports on the accident risk of foreign and native drivers in various road environments in Greece. In particular, the analysis aims to determine the combined effect of driver nationality, area type (inside/outside urban area), junction (yes/no), and lighting conditions (day/night) on accident fault risk. METHODS: Data from the national accident database of Greece are used in a hierarchical log-linear analysis. The induced exposure technique is applied due to the lack of exposure data. Estimated and observed odds ratios are then examined for the quantification of the various effects in terms of relative risk. RESULTS: The initial examination of a saturated model leads to the rejection of all three- and higher-order effects within variables, without providing an adequate fit to the data. On the contrary, a non-saturated second-order model presents a very satisfactory overall fit. The examination of single and combined effects indicates that the most significant effect on accident risk rises from the presence of foreign drivers at junctions. CONCLUSIONS: Results confirm that foreign drivers in Greece are at increased risk. However, immigrant permanent residents appear to have a lower risk compared to tourists, regardless of the road environment.     

A data-oriented strategy to support water resource managers and researchers

Given the wide diversity of data services provided to national water management agencies, the Group on Earth Observations (GEO) in collaboration with the Committee on Earth Observation Satellites (CEOS) developed the approach described in the report, Implementing the GEOSS Water Strategy—From Observations to Decisions to develop more coherent and equitable data services for water management through the use of Earth observations. Among other water resource issues, it recognized the need to enhance data-enriched water management services to support decision making related to drought monitoring, flood warning, tracking and improving sustainable development and monitoring and ameliorating the impacts of climate change. Needs associated with the Strategy's four themes: improved data acquisition for essential water variables, research and product development, interoperability and coordination, and capacity development and decision support, are reviewed. Responses to the recommendations have been undertaken by GEO, led by its Global Water Sustainability (GEOGloWS) initiative which includes NASA contributions, CEOS, and the Global Terrestrial Network for Hydrology (GTN-H). Progress on the themes is reviewed and benefits of these developments for international and US water management are identified. The commentary concludes with a summary of what has been achieved, what remains to be done, and the priority focus areas for implementation in the final year of the Strategy.     

Removal of chromium (VI) from water streams: a thermodynamic study

The chemical speciation of water solutions containing chromium oxyanions in various ratios is calculated (with the aid of available computer code Mineql Plus, Geochemist Workbench and Visual Minteq) and discussed. The effect of solution pH, total concentration of each species studied, and the presence of other species in solution are calculated and presented in the form of thermodynamic speciation diagrams. Electrochemical diagram (correlating pH to Eh) has been calculated as well. The conditions of Cr(VI) reduction to Cr(III) and the subsequent solid phase precipitation are given as a function of redox potential and pH. Surface reactions that might occur between the chromate ions in the solution and redox couples as Fe²⁺/Fe³⁺ on the surface of sorbents are also discussed. Moreover, experimental sorption data of hexavalent chromium onto synthetic magnetite are presented and discussed with the aid of the calculated diagrams. A mechanism is elucidated for the efficient removal of Cr(VI) from water streams at low pH values, and zeta potential data of synthetic magnetite with and without Cr(VI) are presented, which agree well with the mechanism proposed.     

Cause-specific temporal and spatial trends in green sea turtle strandings in the Hawaiian Archipelago (1982–2003)

We investigated cause-specific temporal and spatial trends in sea turtle strandings in the Hawaiian Archipelago. Five species of sea turtle were recorded in 3,861 strandings over a 22-year period (1982–2003). Green turtles comprised 97% of these strandings with size and gender composition reflecting the demographic structure of the resident green turtle population and relative green turtle abundance in Hawaiian waters. The cause of strandings was determined by necropsy based on a complete gross external and internal examination. Totally 75% of the 3,732 green turtle strandings were from Oahu where strandings occur year-round. The most common known cause of the green turtle strandings was the tumour-forming disease, fibropapillomatosis (28%) followed by hook-and-line fishing gear-induced trauma (7%), gillnet fishing gear-induced trauma (5%), boat strike (2.5%), and shark attack (2.7%). Miscellaneous causes comprised 5.4% of strandings whereas 49% of green turtle strandings could not be attributed to any known cause. Green turtle strandings attributable to boat strike were more likely from Kauai and Oahu while fibropapilloma strandings were more likely from Oahu and Maui. Hook-and-line gear strandings were more likely from Oahu due to higher per capita inshore fishing effort. The specific mortality rate (conditional probability) for fibropapillomatosis was 88%, 69% for gillnet gear and 52% for hook-and-line gear. The probability of a dead green turtle stranding increased from 1982 but levelled off by the mid-1990s. The declining mortality risk was because the prevalence and severity of fibropapillomatosis has decreased recently and so has the mortality risk attributable to gillnet gear. Despite exposure to disease and inshore fishing gears, the Hawaiian green turtle stock continues to recover following protection since the late 1970s. Nevertheless, measures to reduce incidental capture of sea turtles in coastal Hawaiian fisheries would be prudent, especially since strandings attributable to hook-and-line fishing gear have increased steadily since 1982.     

Spatial hyperdynamism in a post-disturbance simulated forest

Competition–colonization models can address the population dynamics of remnants following habitat destruction. Spatially explicit versions have produced qualifications of the extinction debt issue and limited hyperdynamism in populations following habitat destruction. Although spatially explicit, these efforts examined few indicators of the spatial structure of the landscape. An existing model is modified here to represent a difference in niche adaptations as well as the competition–colonization tradeoff. Several landscape metrics are calculated at each iteration. Although the addition of niche differentiation did not change the qualitative outcome of the model, the spatial metrics show that some aspects of landscape structure, i.e., average patch area and proximity, become hyperdynamic and remain so. Small fluctuations in species populations are magnified in their spatial expression because the landscape is simplified.