Evaluation of the pollution of the surface waters of Greece from the priority compounds of list II, 76/464/EEC directive, and other toxic compounds

The pollution of the surface waters of Greece from the priority compounds of 76/464/EEC Directive was evaluated. The occurrence of 92 toxic compounds, 64 of which belong to priority compounds of List II, candidates for List I, of 76/464/EEC Directive, was studied in surface waters and wastewater through the developed network of 62 sampling stations, which covers the whole Greek territory. The analytical determination was performed by Purge and Trap-Gas chromatography-Mass spectrometry for volatile and semivolatile organic compounds (VOCs), Gas Chromatography-Electron Capture Detection for organochlorine insecticides, Gas Chromatography-Nitrogen Phosphorous Detection for organophosphorous insecticides, High Performance Liquid Chromatography-Photodiode Array Detection for herbicides, and Electrothermal Atomic Absorption Spectrophotometry and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) for metals and the toluene extractable organotin compounds. The concentrations of VOCs and insecticides detected in the surface waters of Greece were very low, whereas the concentrations of herbicides and metals ranged generally at moderate levels. VOCs were detected almost exclusively in the rivers and very rarely in the lakes, while the frequency of occurrence of insecticides, herbicides and metals was similar for rivers and lakes. Water quality objectives (WQO) and emission limit values (ELV) have been laid down in national legal framework for a number of compounds detected in the samples, in order to safeguard the quality of surface waters from any future deterioration.     

Food,feed, and fuelwood resources of Nepal: A GIS evaluation

A GIS-based land evaluation model was developed to determine the food, feed, and fuelwood sufficiency of all districts in Nepal. Resource surpluses or deficits were calculated for each district for 1981, the year for which the national land resource data were available. Of the three resources, feed supplies were found to be the most critical. Feed deficits occurred in 57% of all districts in 1981, while food and fuelwood deficits occurred in less than 10% of all districts. Different scenarios were carried out for the year 2000 to estimate the magnitude of future resource deficits, assuming resource use and yields in Nepal remain constant in the face of growing population and livestock numbers. Linking resource data with spreadsheet and GIS systems provides a new way to understand and evaluate resources at the district and national levels. To more fully capture the usefulness of this approach, information on rates of change in productivity and land use is needed.     

Estimating maquiladora hazardous waste generation on the U.S./Mexico border

Maquiladoras, manufacturing plants that primarily assemble foreign components for reexport, are located in concentrations along the northern frontier of the US/Mexico border. These plants process a wide variety of materials using modern industrial technologies within the context of developing world institutions and infrastructure. Hazardous waste generation by maquiladoras represents a critical environmental management issue because of the spatial concentration of these plants in border municipalities where the infrastructure for waste management is nonexistent or poor. These border municipalities contain rapidly increasing populations, which further stress their waste handling infrastructure capacities while exposing their populations to greater contaminant risks. Limited empirical knowledge exists concerning hazardous waste types and generation rates from maquiladorsas. There is no standard reporting method for waste generation or methodology for estimating generation rates at this time. This paper presents a method that can be used for the rapid assessment of hazardous waste generation. A first approximation of hazardous waste generation is produced for maquiladoras in the three municipalities of Nogales, Sonora, Mexicali, Baja California, and Cd. Juarez, Chihuahua, using the INVENT model developed by the World Bank. In addition, our intent is to evaluate the potential of the INVENT model for adaptation to the US/Mexico border industrial situation. The press of border industrial development, especially with the recent adoption of the NAFTA, make such assessments necessary as a basis for the environmental policy formulation and management needed in the immediate future.     

MANAGEMENT MODEL FOR CONTROLLING NITRATE CONTAMINATION IN THE NEW JERSEY PINE BARRENS AQUIFER1

ABSTRACT: Land use planning in rapidly developing areas can serve as an effective tool for minimizing water quality impacts on ground water supplies. A land use management model applied to Jackson Township of the New Jersey Pine Barrens was developed. The management model consisted of a simulation model for the transport of nitrates from septic tank systems through the aquifer and a multiobjective, goal programming optimization model to determine population density restrictions using 208 areawide planning population projections. Results showed that growth may have to be curtailed in several areas of Jackson Township and that current population projections over the next 30 years may result in unacceptably high nitrate concentrations downgradient of Jackson Township. The management framework provides a flexible approach to land use planning.     

Temporal - and dose-related characteristics of biochemical and morphological alterations in the hamster induced by 2,3,7,8-tetrachlorodibenzo- -dioxin

The temporal - and dose-related characteristics of hepatic enzymes induced and toxic responses elicited in the hamster by 2,3,7,8-tetrachlorodibenzo- -dioxin were examined. The results demonstrate a dissociation of the induction of these hepatic enzymes from TCDD-elicited lethality, but not necessarily hepatic damage, in this species. Furthermore, the hyperthyroidism observed is suggestive of a role of these hormones in the relatively insensitive nature of this species to TCDD treatment.     

The endocrine and reproductive function of the female Yucheng adolescents prenatally exposed to PCBs/PCDFs

BACKGROUND: Polychlorinated biphenyls (PCBs) and related compounds such as polychlorinated dibenzofurans (PCDFs) and polychlorinated dibenzo-dioxins (PCDDs) alter sexual maturation and endocrine function in animals. In 1978-1979, a mass poisoning occurred in central Taiwan from cooking oil contaminated by heat-degraded PCBs and oxidated compounds PCDFs. We tested the hypothesis that in utero exposed to PCBs/PCDFs alter sexual maturation, endocrine, and reproductive function in the human pubescent females. METHODS: In 1997-1999, girls aged 13-19 years, born to mothers exposed to PCBs/PCDFs, was invited to participate in the study. Menstruation characteristic was recorded daily for 84 days and serum levels of estradiol, LH, FSH, and testosterone were measured on the 3rd day of menstruation. RESULTS: A total of 17 exposed girls and controls participated, the exposed girls reported shorter mean duration of bleeding per cycle than 16 unexposed (5.5 vs 6.5 days, P=0.0055). There was a higher rate of irregular menstrual cycle in the exposed girls (40% vs 0%, P=0.018). Serum levels of estradiol (P=0.016) and FSH (P=0.061) were higher in exposed girls as compared to controls. CONCLUSIONS: We conclude that prenatal exposure to PCBs/PCDFs resulted in abnormal menstruation and higher estradiol and FSH levels in follicular phase of menstrual cycle in adolescent girls.     

Impact of Effluent Recirculation on Stabilization Pond Performance

This paper presents a test case for the effects of recirculation on stabilization pond performance. The BOD₅, COD, SS and Total Coliform removal at the intermediate treatment stages and the outlet of a stabilization pond treatment line, over a 2-year operational period (January 2000-December 2001), is described in detail and the effluent at different stages of treatment is compared to that of a conventional stabilization pond treatment line operating under similar conditions. The system consisted of four ponds in line—an anaerobic pond, followed by three individual ponds (Pond 1, Pond 2 and Pond 3). The effluent of the last pond (Pond 3) was recirculated back to the inlet of the first pond (Pond 1) at a discharge ratio 2:1 (recirculation:inflow). The overall BOD₅, COD, SS and Total Coliforms total reduction was 89%, 81%, 85% and 99.7%, respectively. The anaerobic pond proved to be the most efficient in removing COD and SS (57% and 68%, respectively) whereas Pond 1 achieved the most significant reduction in BOD₅ and Total Coliforms (69% and 86%, respectively). Although BOD₅ and COD were adequately reduced by the recirculating pond line, the SS concentration was high due to algae presence in the final effluent. Moreover, the Total Coliforms were insufficiently removed due to the reduced hydraulic retention time involved in this type of recirculation.