Soil and plant selenium at a reclaimed uranium mine

Selenium (Se) associated with reclaimed uranium (U) mine lands may result in increased food chain transfer and water contamination. To assess post-reclamation bioavailability of Se at a U mine site in southeastern Wyoming, we studied soil Se distribution, dissolution, speciation, and sorption characteristics and plant Se accumulation. Phosphate-extractable soil Se exceeded the critical limit of 0.5 mg/kg in all the samples, whereas total soil Se ranged from a low (0.6 mg/kg) to an extremely high (26 mg/kg) value. Selenite was the dominant species in phosphate and ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA) extracts, whereas selenate was the major Se species in hot water extracts. Extractable soil Se concentrations were in the order of KH2PO4 > AB-DTPA > hot water > saturated paste. The soils were undersaturated with respect to various Se solid phases, albeit with high levels of extractable Se surpassing the critical limit. Calcium and Mg minerals were the potential primary solids controlling Se dissolution, with dissolved organic carbon in the equilibrium solutions resulting in enhanced Se availability. Adsorption was a significant (r2 = 0.76-0.99 at P < 0.05) mechanism governing Se availability and was best described by the initial mass isotherm model, which predicted a maximum reserve Se pool corresponding to 87% of the phosphate-extractable Se concentrations. Grasses, forbs, and shrubs accumulated 11 to 1800 mg Se/kg dry weight. While elevated levels of bioavailable Se may be potentially toxic, the plants accumulating high Se may be used for phytoremediation, or the palatable forage species may be used as animal feed supplements in Se-deficient areas.     

DISTRIBUTED RUNOFF FORMULATION DESIGNED FOR A PRECISION AGRICULTURAL LANDSCAPE MODELING SYSTEM1

A precision scale landscape model designed for agricultural applications is described in this paper. The Precision Agricultural Landscape Modeling System (PALMS) is a combination of two process‐based models: a diffusive wave runoff model with ponding (described in detail) and a biosphere model with a crops module (briefly reviewed). Several innovations, including numerical formulations for the hydrologic properties of the soil surface with crusting, slope/tillage angle interactions, and change of roughness and detention storage with cumulative precipitation have been included. The model is compared to observations on one 1.8 ha field planted with maize and soybeans during four growing seasons, and one 24 ha field planted with maize during one growing season. Daily average soil moisture is simulated well (within 5 percent volumetric), except in extended runoff/ponding episodes. Physical processes not simulated in the model suggest possible explanations for model errors. Planned improvements for PALMS are also presented.     

Survival,reproduction, and recruitment of woody plants after 14 years on a reforested landfill

With the advent of modern sanitary landfill closure techniques, the opportunity exists for transforming municipal landfills into urban woodlands. While costs of fullscale reforestation are generally prohibitive, a modest planting of clusters of trees and shrubs could initiate or accelerate population expansions and natural plant succession from open field to diverse forest. However, among woody species that have been screened for use on landfills, these ecological potentials have not yet been investigated. We examined a 14-yr-old landfill plantation in New Jersey, USA, established to test tolerance of 19 species of trees and shrubs to landfill environments. We measured survivorship, reproduction, and recruitment within and around the experimental installation. Half of the original 190 plants were present, although survival and growth rates varied widely among species. An additional 752 trees and shrubs had colonized the plantation and its perimeter, as well as 2955 stems of vines. However, the great majority (>95%) of woody plants that had colonized were not progeny of the planted cohort, but instead belonged to 18 invading species, mostly native, bird-dispersed, and associated with intermediate stages of secondary plant succession. Based on this evidence, we recommend that several ecological criteria be applied to choices of woody species for the restoration of municipal landfills and similar degraded sites, in order to maximize rapid and economical establishment of diverse, productive woodlands.     

CONTROLLING NONPOINT EXTERNALITIES WITH INPUT RESTRICTIONS IN AN IRRIGATED RIVER BASIN1

ABSTRACT: Irrigated agriculture is a major nonpoint source of surface water quality degradation. Nonpoint source discharges can be controlled by either output taxes or restrictions, or input taxes or restrictions. The economic theory of externality control with taxes or restrictions on input use is developed. The effectiveness of alternative input control policies in improving surface water quality is demonstrated with a mathematical model of the agriculture and water quality in Washington State's Yakima River Basin. Water quality parameters considered were river nitrogen concentration, water temperature, and cropland soil losses. Producer and social abatement costs were the most important measures of policy effectiveness.     

ENVIRONMENTAL THRESHOLD FUNCTIONS FOR USER ORIENTED RESOURCE PLANNING AND MANAGEMENT1

ABSTRACT: Managers of water related outdoor recreation resources want to provide facilities and recreational opportunities of high quality that are attractive to recreationists. The reported research develops a relevant site quality assessment and measurement procedure called environmental threshold modeling. This modeling procedure is based upon the idea that individuals (i.e., recreationists) have specific, identifiable evaluative criteria which can be expressed as a mathematical function of various site characteristics. The function of interest is called a threshold function because it separates acceptable recreational settings from unacceptable settings. Individual specific threshold functions can be easily aggregated to form a population specific threshold function that estimates the proportion of a population that would find the recreational setting acceptable for some specific activity. Presented in this paper are illustrative calibration results based upon survey data collected from recreational canoeists using the Pine River in Michigan's Manistee National Forest.     

FLUSHING CHARACTERISTICS OF A MISSISSIPPI DEAD-END CANAL SYSTEM1

ABSTRACT: A study of residential canal system on the Mississippi Gulf Coast and adjacent natural water bodies was conducted to determine the relationship in flushing characteristics between man-made and natural systems. The comparison was based on measurements of temperature, salinity, conductivity, coliform, pH, transparency, biological oxidation demand, dissolved oxygen, bathymetry, tides, water velocity, and Rhodamine dye concentrations. The results indicate that coliform bacteria increase with increasing distance of stations from St. Louis Bay and dissolved oxygen decreases in a similar manner. Biological oxidation demand was low at all stations; showing no differences between natural and man-made systems. The canal system Studied was shallower than adjacent water bodies and water velocities in the canal system are a function of tidal amplitude while velocities in the river are affected by both tides and runoff. The other parameters measured show little or no differences between natural and man-made systems, but reflect overall seasonal changes. Flushing rates between the residential canal systems and an adjacent natural system are equivalent on the basis of decline in dye concentrations measured over a five-day period.     

COMPUTATION OF RUNOFF REDUCTION CAUSED BY FARM PONDS1

ABSTRACT: A two-parameter farm pond storage index, FPSI, was Used to adjust computed surface. runoff using the partial area runoff contribution resulting from runoff captured by farm ponds. The validity of the index method was tested by fitting a continuous accounting version of the Soil Conservation Service curve number procedure to surface runoff data from each of three watersheds, first with and then without the FPSI routine. Evapotranspiration computed with the Jensen-Haise method and rainfall were input to the model. A linear relationship was assumed between the storage index and the portion of the controlled drainage area that was contributing to runoff. Adjusting the computed runoff with the FPSI reduced the coefficient of variation of monthly measured versus computed surface runoff for each of the three watersheds. The correlation coefficients for the same comparisons were increased. The annual predicted surface runoff Was improved for 12 of the 17 station years of data tested. The farm pond storage index could be used with any surface runoff model to improve the prediction of runoff from watersheds with drainage areas greater than 1 square mile and with about 20 percent or more of the drainage area controlled by farm ponds.     

COMPREHENSIVE FLOOD PLAIN MANAGEMENT1

Flooding and the susceptibility to flood damage inherent in all land uses constitute the flood hazard. Resolution of the hazard while properly recognizing flood plain environmental attributes within the context of overall community or area needs is the essence of comprehensive flood plain management. The traditional approach–flood control–has effected modification of only the flooding component of the hazard whether it be coastal or inland. Until recently Federal programs have overlooked the possibilities of modifying the susceptibility component, for which the major responsibility lies with non-Federal interests. Beginning with actions in the TVA area, the latter is now being strongly encouraged through Federal programs and actions notably the Flood Plain Management Services and Survey Programs of the Corps of Engineers, those stemming from Executive Order 11296, and those required for eligibility under the National Flood Insurance Act of 1968. Flood plain management objectives must be stated in planning, e.g., economic efficiency, reduction in threat to life and health, environmental improvement, and regional development, to permit proper evaluation of the optional means and approaches for achieving them.     

AN OPTIMIZATION TECHNIQUE ADAPTED TO USDAHL-74 REVISED MODEL OF WATERSHED HYDROLOGY1

ABSTRACT. A direct search optimization routine has been added to USDAHL-74 Revised Model of Watershed Hydrology. It provides an objective method to determine values of selected parameters to give the optimum match between observed and computed hydrologic data. Examination of intermediate results also gives information on the sensitivity of the model to changes in the parameter being optimized.     

DISINFECTION WITH QUATERNARY AMMONIUM COMPOUNDS1

ABSTRACT: The most common disinfection method is chlorination, however, it has been known that the practice of chlorination for water treatment in the Mississippi River area has caused a significant increase in mortality. The objective of this research was to search for effective disinfectants to replace chlorine. Three cationic surfactants have been tested for their bactericidal properties under various conditions. It has been found that 1 mg of cetyldimethyl-benzylammonium chloride can destroy about 4500 coliforms in one liter water within 10 minutes, under neutral pH conditions and room temperature. Cationic quaternary ammonium compound, therefore, can be a potential candidate disinfectant for replacing chlorine when necessary.