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721.
Poulain AJ Orihel DM Amyot M Paterson MJ Hintelmann H Southworth GR 《Chemosphere》2006,65(11):2199-2207
The purpose of our study was to test the hypothesis that dissolved gaseous mercury (DGM) production and evasion is directly proportional to the loading rate of inorganic mercury [Hg(II)] to aquatic ecosystems. We simulated different rates of atmospheric mercury deposition in 10-m diameter mesocosms in a boreal lake by adding multiple additions of Hg(II) enriched with a stable mercury isotope (202Hg). We measured DGM concentrations in surface waters and estimated evasion rates using the thin-film gas exchange model and mass transfer coefficients derived from sulfur hexafluoride (SF6) additions. The additions of Hg(II) stimulated DGM production, indicating that newly added Hg(II) was highly reactive. Concentrations of DGM derived from the experimental Hg(II) additions (“spike DGM”) were directly proportional to the rate of Hg(II) loading to the mesocosms. Spike DGM concentrations averaged 0.15, 0.48 and 0.94 ng l−1 in mesocosms loaded at 7.1, 14.2, and 35.5 μg Hg m−2 yr−1, respectively. The evasion rates of spike DGM from these mesocosms averaged 4.2, 17.2, and 22.3 ng m−2 h−1, respectively. The percentage of Hg(II) added to the mesocosms that was lost to the atmosphere was substantial (33–59% over 8 weeks) and was unrelated to the rate of Hg(II) loading. We conclude that changes in atmospheric mercury deposition to aquatic ecosystems will not change the relative proportion of mercury recycled to the atmosphere. 相似文献
722.
Low-permeability, non-reactive barrier walls are often used to contain contaminants in an aquifer. Rates of solute transport through such barriers are typically many orders of magnitude slower than rates through the aquifer. Nevertheless, the success of remedial actions may be sensitive to these low rates of transport. Two numerical simulation methods for representing low-permeability barriers in a finite-difference groundwater-flow and transport model were tested. In the first method, the hydraulic properties of the barrier were represented directly on grid cells and in the second method, the intercell hydraulic-conductance values were adjusted to approximate the reduction in horizontal flow, allowing use of a coarser and computationally efficient grid. The alternative methods were tested and evaluated on the basis of hypothetical test problems and a field case involving tetrachloroethylene (PCE) contamination at a Superfund site in New Hampshire. For all cases, advective transport across the barrier was negligible, but preexisting numerical approaches to calculate dispersion yielded dispersive fluxes that were greater than expected. A transport model (MODFLOW-GWT) was modified to (1) allow different dispersive and diffusive properties to be assigned to the barrier than the adjacent aquifer and (2) more accurately calculate dispersion from concentration gradients and solute fluxes near barriers. The new approach yields reasonable and accurate concentrations for the test cases. 相似文献
723.
Ninety Capsicum accessions selected from the USDA Capsicum germplasm collection were screened for their capsaicinoids content using gas hromatography with nitrogen phosphorus detection (GC/NPD). Fresh fruits of Capsicum chinense, C. frutescens, C. baccatum, C. annuum, and C. pubescens were extracted with methanol and analyzed for capsaicin, dihydrocapsaicin, and nordihydrocapsaicin. Mass spectrometry of the fruit crude extracts indicated that the molecular ions at m/z 305, 307, and 293, which correspond to capsaicin, dihydrocapsaicin, and nordihydrocapsaicin, respectively, have a common benzyl cation fragment at m/z 137 that can be used for monitoring capsaicinoids in pepper fruit extracts. Capsaicin and dihydrocapsaicin were the dominant capsaicinoids detected. Capsaicin concentrations were typically greater than dihydrocapsaicin. Concentrations of total capsaicinoids varied from not detectable to 11.2 mg fruit(-1). Statistical analysis revealed that accession PI-441624 (C. chinense) had the highest capsaicin content (2.9 mg g(-1) fresh fruit) and accession PI-497984 (C. frutescens) had the highest dihydrocapsaicin content (2.3 mg g(-1) fresh fruit). Genebank accessions PI-439522 (C. frutescens) and PI-497984 contained the highest concentrations of total capsaicinoids. 相似文献
724.
Cousillas H George I Mathelier M Richard JP Henry L Hausberger M 《Die Naturwissenschaften》2006,93(12):588-596
Vocal communication develops under social influences that can enhance attention, an important factor in memory formation and perceptual tuning. In songbirds, social conditions can delay sensitive periods of development, overcome learning inhibitions and enable exceptional learning or induce selective learning. However, we do not know how social conditions influence auditory processing in the brain. In the present study, we raised young naive starlings under different social conditions but with the same auditory experience of adult songs, and we compared the effects of these different conditions on the development of the auditory cortex analogue. Several features appeared to be influenced by the social experience, among which the proportion of auditory neuronal sites and the neuronal selectivity. Both physical and social isolation from adult models altered the development of the auditory area in parallel to alterations in vocal development. To our knowledge, this is the first evidence that social deprivation has as much influence on neuronal responsiveness as sensory deprivation. 相似文献
725.
726.
Air emission inventories in North America: a critical assessment 总被引:1,自引:0,他引:1
Miller CA Hidy G Hales J Kolb CE Werner AS Haneke B Parrish D Frey HC Rojas-Bracho L Deslauriers M Pennell B Mobley JD 《Journal of the Air & Waste Management Association (1995)》2006,56(8):1115-1129
Although emission inventories are the foundation of air quality management and have supported substantial improvements in North American air quality, they have a number of shortcomings that can potentially lead to ineffective air quality management strategies. Major reductions in the largest emissions sources have made accurate inventories of previously minor sources much more important to the understanding and improvement of local air quality. Changes in manufacturing processes, industry types, vehicle technologies, and metropolitan infrastructure are occurring at an increasingly rapid pace, emphasizing the importance of inventories that reflect current conditions. New technologies for measuring source emissions and ambient pollutant concentrations, both at the point of emissions and from remote platforms, are providing novel approaches to collecting data for inventory developers. Advances in information technologies are allowing data to be shared more quickly, more easily, and processed and compared in novel ways that can speed the development of emission inventories. Approaches to improving quantitative measures of inventory uncertainty allow air quality management decisions to take into account the uncertainties associated with emissions estimates, providing more accurate projections of how well alternative strategies may work. This paper discusses applications of these technologies and techniques to improve the accuracy, timeliness, and completeness of emission inventories across North America and outlines a series of eight recommendations aimed at inventory developers and air quality management decision-makers to improve emission inventories and enable them to support effective air quality management decisions for the foreseeable future. 相似文献
727.
Hámori K Tóth E Pál L Köteles G Losonci A Minda M 《Journal of environmental radioactivity》2006,88(2):189-198
The RAD Laboratory measured annual means of radon activity concentrations in 15 277 first-floor rooms of dwellings and in 325 rooms on upper floors in Hungary (1994-2004). The original purpose of the survey was to find radon-prone area in Hungary. The maximum measured value was 5800 Bq m(-3), while the minimum was 10 Bq m(-3). Due to geological diversity and different structures of buildings, the data set of first-floor rooms did not follow the lognormal distribution. Therefore, strata were chosen so that the measured data fitted the lognormal distribution. The numbers of dwellings above a given radon level were determined in each stratum. The national distribution was then taken as the sum of the individual distributions of all strata. This distribution was not lognormal. The parameters of the best fitting lognormal distribution were GM = 58 Bq m(-3), GSD = 2.2. The weighted averages of strata values GM = 62 Bq m(-3), GSD=2.1 were obtained corresponding to 92% of Hungarian dwellings. 相似文献
728.
Kjelland ME Kreuter UP Clendenin GA Wilkins RN Wu XB Afanador EG Grant WE 《Environmental management》2007,40(2):231-244
Fragmentation of family-owned farms and ranches has been identified as the greatest single threat to wildlife habitat, water
supply, and the long-term viability of agriculture in Texas. However, an integrative framework for insights into the pathways
of land use change has been lacking. The specific objectives of the study are to test the hypotheses that the nonagricultural
value (NAV) of rural land is a reliable indicator of trends in land fragmentation and that NAV in Texas is spatially correlated
with population density, and to explore the idea that recent changes in property size patterns are better represented by a
categorical model than by one that reflects incremental changes. We propose that the State-and-Transition model, developed
to describe the dynamics of semi-arid ecosystems, provides an appropriate conceptual framework for characterizing categorical
shifts in rural property patterns. Results suggest that changes in population density are spatially correlated with NAV and
farm size, and that rural property size is spatially correlated with changes in NAV. With increasing NAV, the proportion of
large properties tends to decrease while the area represented by small properties tends to increase. Although a correlation
exists between NAV and population density, it is the trend in NAV that appears to be a stronger predictor of land fragmentation.
The empirical relationships established herein, viewed within the conceptual framework of the State-and-Transition model,
can provide a useful tool for evaluating land use policies for maintaining critical ecosystem services delivered from privately
owned land in private land states, such as Texas. 相似文献
729.
Agyin-Birikorang S O'Connor GA Jacobs LW Makris KC Brinton SR 《Journal of environmental quality》2007,36(1):316-323
Excessive soluble P in runoff is a common cause of eutrophication in fresh waters. Evidence indicates that drinking water treatment residuals (WTRs) can reduce soluble P concentrations in P-impacted soils in the short term (days to weeks). The long-term (years) stability of WTR-immobilized P has been inferred, but validating field data are scarce. This research was undertaken at two Michigan field sites with a history of heavy manure applications to study the longevity of alum-based WTR (Al-WTR) effects on P solubility over time (7.5 yr). At both sites, amendment with Al-WTR reduced water-soluble P (WSP) concentration by >or=60% as compared to the control plots, and the Al-WTR-immobilized P (WTR-P) remained stable 7.5 yr after Al-WTR application. Rainfall simulation techniques were utilized to investigate P losses in runoff and leachate from surface soils of the field sites at 7.5 yr after Al-WTR application. At both sites, amendment with Al-WTR reduced dissolved P and bioavailable P (BAP) by >50% as compared to the control plots, showing that WTR-immobilized P remained nonlabile even 7.5 yr after Al-WTR amendment. Thus, WTR-immobilized P would not be expected to dissolve into runoff and leachate to contaminate surface waters or groundwater. Even if WTR-P is lost via erosion to surface waters, the bioavailability of the immobilized P should be minimal and should have negligible effects on water quality. However, if the WTR particles are destroyed by extreme conditions, P loss to water could pose a eutrophication risk. 相似文献
730.
Objectives: This research aims to identify and analyze the factors affecting accident severity through a macroscopic analysis, with a focus on the comparison between inside and outside urban areas. Disaggregate road accident data for Greece for the year 2008 were used. Methods: Two models were developed, one for inside and one for outside urban areas. Because the dependent variable had 2 categories, killed/severely injured (KSI) and slightly injured (SI), the binary logistic regression analysis was selected. Furthermore, this research aims to estimate the probability of fatality/severe injury versus slight injury as well as to calculate the odds ratios (relative probabilities) for various road accident configurations. The Hosmer and Lemeshow statistic and other diagnostic tests were conducted in order to assess the goodness-of-fit of the model. Results: From the application of the models, it appears that inside urban areas 3 types of collisions (sideswipe, rear-end, with fixed object/parked car), as well as involvement of motorcycles, bicycles, buses, 2 age groups (18-30 and older than 60?years old), time of accident, and location of the accident, seem to affect accident severity. Outside urban areas, 4 types of collisions (head-on, rear-end, side, sideswipe), weather conditions, time of accident, one age group (older than 60?years old), and involvement of motorcycles and buses were found to be significant. Conclusions: Factors affecting road accident severity only inside urban areas include young driver age, bicycles, intersections, and collision with fixed objects, whereas factors affecting severity only outside urban areas are weather conditions and head-on and side collisions, demonstrating the particular road users and traffic situations that should be focused on for road safety interventions for the 2 different types of networks (inside and outside urban areas). The methodology and the results of this research may provide a promising tool to prioritize programs and measures to improve road safety in Greece and worldwide. 相似文献