Land degradation,economic growth and structural change: evidences from Italy

The present study investigates the relationship between land degradation and the evolution of the productive structure in Italy during the last 50 years (1960–2010). The objectives of the study are twofold: (i) to present and discuss an original analysis of the income–environment relationship in an economic-convergent and environmental–divergent country and (ii) to evaluate the impact of the (changing) productive structure and selected socio-demographic characteristics on the level of land vulnerability. The econometric analysis indicates that the relationship between GDP and land degradation across Italian provinces is completely reverted once we move from a cross-sectional analysis to panel estimates. While economic and environmental disparities between provinces go in the same direction, with richer provinces having lower levels of LD, over time the growth process increases LD with the economic structure acting as a significant variable.     

Description and preliminary validation of the PMSS fast response parallel atmospheric flow and dispersion solver in complex built-up areas

Noxious atmospheric releases may originate from both accidents and malicious activities. They are a major concern for public authorities or first responders who may wish to have the most accurate situational awareness. Nonetheless, it is difficult to reliably and accurately model the flow, transport, and dispersion processes in large complex built-up environments in a limited amount of time and resources compatible with operational needs. The parallel version of Micro-SWIFT-SPRAY (PMSS) is an attempt to propose a physically sound and fast response modelling system applicable to complicated industrial or urban sites in case of a hazardous release. This paper presents and justifies the choice of the diagnostic flow and Lagrangian dispersion models in PMSS. Then, it documents in detail the development of the parallel algorithms used to reduce the computational time of the models. Finally, the paper emphasizes the preliminary model validation and parallel performances of PMSS based on data from both wind tunnel (Evaluation of Model Uncertainty) and in-field reduced-scale (Mock Urban Setting Test) and real-scale (Oklahoma City) experimental campaigns.     

The Food Allergy Risk Management in the EU Labelling Legislation

Food allergy represents an increasing public health issue, and a large number of food control authorities have provided regulations aimed to minimize the risk of allergic reaction for sensitized consumers. The Food and Agriculture Organization of the United Nations together with the World Health Organization established the Codex Alimentarius Commission whose main goal is to protect the consumers’ health. To purse this task the Commission listed the foods and ingredients causing the most severe allergic reactions that should be labelled. It has been reported that some cases of specific foods hypersensitivity display a different prevalence among different Countries. Thus, the European Union drew up a list of mandatory allergens (that must be labelled) longer than that provided by Codex Alimentarius. As a consequence of the complexity of the legal phraseology of the European Union (EU) and/or European Community (EC) the Regulations and/or Directives were differently translated in all EC/EU official languages determining possible misinterpretations of the legislation. Moreover, food labelling regulations were also established with the goal to promote the consumers’ conscious choice about what they eat. Starting from the case of the fermented beverages, we analysed the European legislative scenario concerning the allergen labelling of the last fifteen years, highlighting that mistranslations, misinterpretations and lack of information in the EU Regulations might lead to health and ethical issues.     

Regional-scale application of the decision support system MOIRA-PLUS: an example of assessment of the radiological impact of the Chernobyl accident on the fresh water ecosystem in Italy

The present work illustrates the customisation and application of the decision support system MOIRA-PLUS (a MOdel-based computerised system for management support to Identify optimal remedial strategies for Restoring radionuclide contaminated Aquatic ecosystems and drainage areas) to the fresh water environment in Italy. MOIRA-PLUS is aimed at evaluating the behaviour of radiocaesium and radiostrontium in fresh water ecosystems and at assessing the appropriateness of suitable strategies for the management of contaminated water bodies by the application of multi-attribute analysis techniques. MOIRA-PLUS can be applied to complex networks of lakes, rivers and tributaries and can be straightforwardly customised utilising data and information from readily accessible sources such as official websites provided by scientific or government organisations. The present work shows an application of the decision system to 10 lakes and 18 rivers in Italy contaminated with ¹³⁷Cs of Chernobyl origin. Site-specific values of some aggregated transfer parameters were estimated for the most important Italian lakes. Although high values of fish and water consumptions were hypothesised, very low doses to public from the fresh water pathway following the accident were calculated.     

Endocrine modulation, inhibition of ovarian development and hepatic alterations in rainbow trout exposed to polluted river water

Under laboratory conditions, female rainbow trout were exposed to graded concentrations of water from the River Lambro, a polluted tributary of the River Po, and to the effluent of a large wastewater treatment plant which flows into the River Lambro. In field exposures, trout were held in cages in the River Po upstream and downstream from the confluence of the River Lambro. After 10-day (laboratory) and 30-day (laboratory and field) exposures, trout were examined for several chemical, biochemical and histological endpoints. The results indicated that exposure to complex mixtures of chemicals, including estrogen receptor agonists, aryl-hydrocarbon receptor agonists, and probably antiandrogens, had occurred. Exposure altered the plasma levels of 17β-estradiol and testosterone, and some treatments also enhanced the activity of hepatic ethoxyresorufin O-deethylase. Gonadal histology showed varying levels of degenerative processes characterised by oocyte atresia, haemorrhages, melano-macrophage centres (MMCs), and oogonia proliferation. Liver histology showed less severe effects.     

Meteorological and pedological influence on the PCBs distribution in mountain soils

Polychlorinated biphenyls (PCBs) are a threat to environmental and human health due to their persistence and toxicological effects. In this paper, we analyse some meteorological and organic-matter-related effects on their distribution in the soils of an Alpine environment that is not subject to direct contamination. We collected samples and measured the contamination of 12 selected congeners from three soil layers (O, A1 and A2) and from North-, plain- and South-facing slopes on six different dates spanning the entire snowless portion of the year. We recorded the hourly air and soil temperatures, humidity and rainfall in the study period. We found evidence that PCBs contamination in soils varies significantly, depending on sampling date, layer and aspect. The observed seasonal trend shows an early summer peak and a rapid decrease during June. The layer effect demonstrates higher dry-weight-based concentrations in the O layer, whereas the differences are much smaller for SOM-based concentrations. Different factors caused significantly higher concentrations in northern soils, with a N/S enrichment factor ranging from 1.8 to 1.5 during the season. The southern site has significantly more rapid early-summer re-volatilisation kinetics (half-time of 16 d for South, 25 d for North).     

Residues of pirimiphos-methyl in cereals and processed fractions following post harvest spray application

The aim of this work was to comparatively assess the persistence of pirimiphos methyl residues in cereals and in their milling fractions after spray application in post harvest. An analytical method, based on a slightly modified QuEChERS extraction followed by liquid chromatography tandem mass spectrometry (LC-MS/MS) determination was validated: mean recovery was in the range 73% to 92% depending on the spiking level, and precision as RSD ranged from 11% to 16%. The analysis of treated samples revealed that pirimiphos-methyl residues were highly persistent and that no differences could be observed between wheat, durum wheat and oat. As far as the impact of the milling process on residues is concerned, pirimiphos methyl contamination was significantly reduced during both cleaning and processing, and most of the contamination was related to outer kernel fractions.     

Predicting the migration of dissolved toxic substances from catchments by a collective model

In the present paper a collective model for predicting the migration of dissolved toxic substances through drainage areas is described. The model has been validated using data for ¹³⁷Cs and ⁹⁰Sr concentrations in water of some European contaminated rivers following the atmospheric fall-out from the accident at the Chernobyl power plant. It has been demonstrated that the migration rate λ (s⁻¹) of a dissolved toxic substance from a catchment may be evaluated by the following approximate formula: λ=(c ln t+d)/t, where t is the time from a pulse deposition event and the coefficients c and d depend on the characteristics of the substance. It has been shown that the mathematical form of the transfer function (flux of dissolved substance at time t following a single pulse deposition of a pollutant onto the catchment) of a toxic substance from a drainage area is very simple. Moreover, the values of the transfer function parameters are slightly variable despite the large range of characteristics of the catchments here examined. Indeed, the statistical aggregation of competing migration processes can lead to ‘stable’ collective behaviours that are less variable than each single process.     

Geochemical characterization and biomonitoring of reclaimed soils in the Po River Delta (Northern Italy): implications for the agricultural activities

This geochemical study is focused on the easternmost part of the Po River alluvial plain in Northern Italy, which is interested by widespread agricultural activities, investigating a reclaimed sector of the Province of Ferrara, known as “Valle del Mezzano” (Mezzano Low Land, hereafter reported as MLL) characterized by peat-rich soils. The chemical–mineralogical characterization of these reclaimed soils is important to compare the local geochemical backgrounds with those recorded in other sectors of the River Po plain and to monitor if the observed concentration exceeds critical thresholds. The reported analyses include (a) measurement of the soil salinity, (b) nutrient evaluation, (c) major and trace element concentrations carried out on bulk soils, (d) tests of metal extraction with both aqua regia and EDTA to highlight the distinct elemental mobility and (e) phyto-toxicological measurement of heavy metal concentrations in plants (Lactuca sativa acephala) grown on the studied soils. The results indicate (1) high soil salinity, often with drastic increase of sodium and chloride along the soil profiles, (2) high nitrogen content (in part related to anthropogenic activities) on superficial horizons and nitrate decrease along the soil profiles and (3) comparative enrichments in heavy metals with respect to other soils of the province, which indicate that peat deposits are effective in trapping metals from anthropogenic sources. This, in turn, implies potential geochemical risks for the agricultural activities. In this regard, specific concerns are related to the high nickel and arsenic content of MLL soils due to the mobility of these elements and their attitude to be taken up by plants.     

TEQ(S) and body burden for PCDDs, PCDFs, and dioxin-like PCBs in human adipose tissue

Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), mono-ortho and non-ortho polychlorinated biphenyls (dioxin-like PCBs) were determined in samples of human fat tissue from nine Italian obese patients. The toxicity equivalent (TEQ) values ranged from 9 to 25pgTEQg(-1) lipid (WHO-TEF values, 2005 [Van den Berg, M., Birnbaum, L.S., Denison, M., De Vito, M., Farland, W., Feeley, M., Fiedler, H., Hakansson, H., Hanberg, A., Haws, L., Rose, M., Safe, S., Schrenk, D., Tohyama, C., Tritscher, A., Tuomisto, J., Tysklind, M., Walker, N., Peterson, R.E., 2006. The 2005 World Health Organization reevaluation of human and mammalian Toxic Equivalency Factors for dioxins and dioxin-like compounds. Toxicol. Sci. 93, 223-241]), the contribution of dioxin-like PCBs was more than 30% of the total TEQ values. The obese body burdens varied from 6 to 11ngTEQkg(-1) body weight (BW), exceeding the estimated steady-state body burden 5ngTEQkg(-1) BW, based on lipid adjusted serum concentrations from several populations in the mid-1990s, calculated in the risk assessment US EPA document.