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71.
Triclosan in Fresh Water Fish Gibelion Catla from the Kaveri River,India, and Its Consumption Risk Assessment 总被引:1,自引:0,他引:1
Govindaraj Shanmugam Karthik Ramasamy Krishna Kumar Selvaraj Srimurali Sampath 《Environmental Forensics》2014,15(3):207-212
Triclosan is a common antimicrobial agent that is found in significant levels in the aquatic environment and may elicit effects on aquatic organisms through unexpected modes of action. In this study, triclosan was quantified in fish from the Kaveri River, India, by using the gas chromatography and mass spectrometry technique and it was found in the range of 0.73–50 ng/g wet weight (ww). The mean bioaccumulation factor based on water (BAFw 820) and sediment (BAFs 2.12) in the Kaveri River showed that triclosan is accumulative in fish, and reflects its feeding behavior. The bioaccumulation indicates triclosan's persistence or prevalence throughout the river stretch. Human risk assessment through dietary intake demonstrated that the triclosan exposure is five orders of magnitude lower than the acceptable daily intake (50 μg/kg bw) and US EPA reference dose (300 μg/kg bw/day). This investigation is the first to report the bioaccumulation of triclosan in freshwater fish from India. Further, the results indicate that this fish acts as a biomarker of exposure for triclosan and thus shall be used to report triclosan pollution in the future. 相似文献
72.
Abdulatif A. Mansur Eric M. Adetutu Krishna K. Kadali Paul D. Morrison Yuana Nurulita Andrew S. Ball 《Environmental science and pollution research international》2014,21(18):10725-10735
The disposal of hazardous crude oil tank bottom sludge (COTBS) represents a significant waste management burden for South Mediterranean countries. Currently, the application of biological systems (bioremediation) for the treatment of COTBS is not widely practiced in these countries. Therefore, this study aims to develop the potential for bioremediation in this region through assessment of the abilities of indigenous hydrocarbonoclastic microorganisms from Libyan Hamada COTBS for the biotreatment of Libyan COTBS-contaminated environments. Bacteria were isolated from COTBS, COTBS-contaminated soil, treated COTBS-contaminated soil, and uncontaminated soil using Bushnell Hass medium amended with Hamada crude oil (1 %) as the main carbon source. Overall, 49 bacterial phenotypes were detected, and their individual abilities to degrade Hamada crude and selected COBTS fractions (naphthalene, phenanthrene, eicosane, octadecane and hexane) were evaluated using MT2 Biolog plates. Analyses using average well colour development showed that ~90 % of bacterial isolates were capable of utilizing representative aromatic fractions compared to 51 % utilization of representative aliphatics. Interestingly, more hydrocarbonoclastic isolates were obtained from treated contaminated soils (42.9 %) than from COTBS (26.5 %) or COTBS-contaminated (30.6 %) and control (0 %) soils. Hierarchical cluster analysis (HCA) separated the isolates into two clusters with microorganisms in cluster 2 being 1.7- to 5-fold better at hydrocarbon degradation than those in cluster 1. Cluster 2 isolates belonged to the putative hydrocarbon-degrading genera; Pseudomonas, Bacillus, Arthrobacter and Brevundimonas with 57 % of these isolates being obtained from treated COTBS-contaminated soil. Overall, this study demonstrates that the potential for PAH degradation exists for the bioremediation of Hamada COTBS-contaminated environments in Libya. This represents the first report on the isolation of hydrocarbonoclastic bacteria from Libyan COTBS and COTBS-contaminated soil. 相似文献
73.
Phytoremediation is a sustainable process in which green plants are used for the removal or elimination of contaminants in soils. Both organic and inorganic contaminants can be removed or degraded by growing plants by several mechanisms, namely phytoaccumulation, phytostabilization, phytodegradation, rhizofiltration and rhizodegradation. Phytoremediation has several advantages: it can be applied in situ over large areas, the cost is low, and the soil does not undergo significant damages. However, the restoration of a contaminated site by phytoremediation requires a long treatment time since the remediation depends on the growth and the biological cycles of the plant. It is only applicable for shallow depths within the reach of the roots, and the remediation efficiency largely depends on the physico-chemical properties of the soil and the bioavailability of the contaminants. The combination of phytoremediation and electrokinetics has been proposed in an attempt to avoid, in part, the limitations of phytoremediation. Basically, the coupled phytoremediation–electrokinetic technology consists of the application of a low intensity electric field to the contaminated soil in the vicinity of growing plants. The electric field may enhance the removal of the contaminants by increasing the bioavailability of the contaminants. Variables that affect the coupled technology are: the use of AC or DC current, voltage level and mode of voltage application (continuous or periodic), soil pH evolution, and the addition of facilitating agents to enhance the mobility and bioavailability of the contaminants. Several technical and practical challenges still remain that must be overcome through future research for successful application of this coupled technology at actual field sites. 相似文献
74.
Anthropogenic activities associated with industrialization, agriculture and urbanization have led to the deterioration in
water quality due to various contaminants. To assess the status of urban drinking water quality, samples were collected from
the piped supplies as well as groundwater sources from different localities of residential, commercial and industrial areas
of Lucknow City in a tropical zone of India during pre-monsoon for estimation of coliform and faecal coliform bacteria, organochlorine
pesticides (OCPs) and heavy metals. Bacterial contamination was found to be more in the samples from commercial areas than
residential and industrial areas. OCPs like α,γ-hexachlorocyclohexane and 1,1 p,p-DDE {dichloro-2, 2-bis(p-chlorophenyl) ethene)}
were found to be present in most of the samples from study area. The total organochlorine pesticide levels were found to be
within the European Union limit (0.5 μg/L) in most of the samples. Most of the heavy metals estimated in the samples were
also found to be within the permissible limits as prescribed by World Health Organization for drinking water. Thus, these
observations show that contamination of drinking water in urban areas may be mainly due to municipal, industrial and agricultural
activities along with improper disposal of solid waste. This is an alarm to safety of public health and aquatic environment
in tropics. 相似文献
75.
Anand Prabha Rawat Krishna Giri J. P. N. Rai 《Environmental monitoring and assessment》2014,186(3):1679-1687
Biosorption of Cu2+, Zn2+, and Cr6+ from aqueous solutions by leaf biomass of Jatropha curcas was investigated as a function of biomass concentration, initial metal ion concentration, contact time, and pH of the solution systematically. The aim of this study was to optimize biosorption process and find out a suitable kinetic model for the metal removal in single and multi-metal system. The experimental data were analyzed using two sorption kinetic models, viz., pseudo-first- and pseudo-second-order equations, to determine the best fit equation for the biosorption of metal ions Cu2+, Zn2+, and Cr6+ onto the leaf biomass of J. curcas in different metal systems. The experimental data fitted well the pseudo-second-order equation and provided the best correlation for the biosorption process. The findings of the present investigation revealed that J. curcas leaf biomass was an eco-friendly and cost-effective biosorbent for the removal of heavy metal ions from wastewater. 相似文献
76.
Biswas S Prabhu RK Hussain KJ Selvanayagam M Satpathy KK 《Environmental monitoring and assessment》2012,184(8):5097-5104
Concentrations of Cu, Mn, Zn, Fe, Cr, and Pb were estimated using ICP-MS in nine commercially important and locally consumed fish species (Sarda orientalis, Scomberomorus commerson, Rastrelliger kanagurta, Sardinella longiceps, Paraplagusia bilineata, Cynoglossus lida, Cynoglossus macrostomus, Lepturacanthus savala, and Siganus javus) collected from coastal waters of Kalpakkam, eastern part of India. Their concentration (μg g(-1)) in the examined fish species ranged as follows: Cu (0.8-6.5), Zn (14.3-27.9), Mn (0.5-8.8), Fe (17.6-117.0), Cr (0.24-1.78), and Pb (0.18-2.29). Concentrations of most of the metals in the fish species studied were found to be safe for human consumption barring Mn. 相似文献
77.
78.
Jay Krishna Thakur P. K. Srivastava S. K. Singh Zoltán Vekerdy 《Regional Environmental Change》2012,12(1):133-144
Wetland ecosystems are of global significance having productive, regulatory and informative function. These wetlands are crucial
for the long-term protection of water sources, as well as the survival of its unique biodiversity. Most of the wetlands of
Turkey are now facing serious threat from the anthropogenic sources and now near to the verge of extinction. This study has
been carried out to monitor vegetation dynamics and ecological status of wetlands of Koyna basin at spatial and temporal scale.
This study has involved MODerate-resolution Imaging Spectroradiometer (MODIS) images of the year 2000, 2004 and 2008 on daily
basis with spatial resolution of 1 km. The MODIS 16 days composite NDVI time series products of 250-m spatial resolution from
year 2000 to 2008 has been utilized to monitor the ecological status of the wetlands. The European Nature Information System
habitat classification map, meteorological data (precipitation, temperature) coupled with field data has been utilized to
validate NDVI values of nine habitats in the wetlands. The time series analyses of NDVI data values have been correlated with
the groundwater level depth from 1996 to 2004. The overall analysis has shown a declining trend of NDVI over the year 2000
to 2008, indicated a degraded wetland condition in span of 9 years. 相似文献
79.
Monica Rawat A. P. Rawat Krishna Giri J. P. N. Rai 《Environmental science and pollution research international》2013,20(8):5198-5211
Chromate-resistant bacterial strain isolated from the soil of tannery was studied for Cr(VI) bioaccumulation in free and immobilised cells to evaluate its applicability in chromium removal from aqueous solution. Based on the comparative analysis of the 16S rRNA gene, and phenotypic and biochemical characterization, this strain was identified as Paenibacillus xylanilyticus MR12. Mechanism of Cr adsorption was also ascertained by chemical modifications of the bacterial biomass followed by Fourier transform infrared spectroscopy analysis of the cell wall constituents. The equilibrium biosorption analysed using isotherms (Langmuir, Freundlich and Dubinin–Redushkevich) and kinetics models (pseudo-first-order, second-order and Weber–Morris) revealed that the Langmuir model best correlated to experimental data, and Weber–Morris equation well described Cr(VI) biosorption kinetics. Polyvinyl alcohol alginate immobilised cells had the highest Cr(VI) removal efficiency than that of free cells and could also be reused four times for Cr(VI) removal. Complete reduction of chromate in simulated effluent containing Cu2+, Mg2+, Mn2+ and Zn2+ by immobilised cells, demonstrated potential applications of a novel immobilised bacterial strain MR12, as a vital bioresource in Cr(VI) bioremediation technology. 相似文献
80.
Li X Wang T Sattayatewa C Venkatesan D Noll KE Pagilla KR Moschandreas DJ 《Journal of the Air & Waste Management Association (1995)》2011,61(8):872-881
Odor emission rates are commonly measured in the laboratory or occasionally estimated with inverse modeling techniques. A modified inverse modeling approach is used to estimate source emission rates inside of a postdigestion centrifuge building of a water reclamation plant. Conventionally, inverse modeling methods divide an indoor environment in zones on the basis of structural design and estimate source emission rates using models that assume homogeneous distribution of agent concentrations within a zone and experimentally determined link functions to simulate airflows among zones. The modified approach segregates zones as a function of agent distribution rather than building design and identifies near and far fields. Near-field agent concentrations do not satisfy the assumption of homogeneous odor concentrations; far-field concentrations satisfy this assumption and are the only ones used to estimate emission rates. The predictive ability of the modified inverse modeling approach was validated with measured emission rate values; the difference between corresponding estimated and measured odor emission rates is not statistically significant. Similarly, the difference between measured and estimated hydrogen sulfide emission rates is also not statistically significant. The modified inverse modeling approach is easy to perform because it uses odor and odorant field measurements instead of complex chamber emission rate measurements. 相似文献