Phosphorus and nitrogen runoff from a forested watershed fertilized with biosolids

Municipal biosolids are typically not used on the steepest of forested slopes in the U.S. Pacific Northwest. The primary concern in using biosolids on steep slopes is movement of biosolids particles and soluble nutrients to surface waters during runoff events. We examined the pattern and extent of P and N runoff from a perennial stream draining a small, forested 21.4-ha watershed in western Washington before and after biosolids application. In this study, we applied biosolids at a rate of 13.5 Mg ha(-1) (700 kg N ha(-1) and 500 kg P ha(-1)) to 40% of the watershed following nearly 1.5 years of pre-application water sampling and 1.5 years thereafter. There was no evidence of direct runoff of P or N from biosolids into surface water. Elevated surface water discharge did not change the concentration of PO4-P, biologically available phosphorus (BAP), bioavailable particulate phosphorus (BPP), or total P nor did it affect the concentration-discharge relationship. Some instances of total P concentrations exceeding the USEPA surface water standard of 0.1 mg L(-1) were observed following biosolids application. However, total P in 27 Creek was predominately in particulate form and not labile, suggesting that detritus moving into the main creek channel and ephemeral drainage courses may be the principal P source. Ammonium N concentrations in runoff water were consistent before and after biosolids application, ranging from below detection limits (0.01 mg L(-1)) to 0.1 mg L(-1); no concentration-discharge relationship existed. Biosolids application changed the 27 Creek concentration-discharge relationship for NO3(-)-N. Before application, no relationship existed. Beginning nine months after biosolids application, increases in discharge were positively related to increases in NO3(-)-N concentrations. Nitrate concentrations in runoff following biosolids application were approximately 10 times less than the USEPA drinking water standard of 10 mg L(-1).     

Refinement of the density-modified displacement method for efficient treatment of tetrachloroethene source zones

A novel method to remediate dense nonaqueous phase liquid (DNAPL) source zones that incorporates in situ density conversion of DNAPL via alcohol partitioning followed by displacement with a low interfacial tension (IFT) surfactant flood has been developed. Previous studies demonstrated the ability of the density-modified displacement (DMD) method to recover chlorobenzene (CB) and trichloroethene (TCE) from heterogeneous porous media without downward migration of the dissolved plume or free product. However, the extent of alcohol (n-butanol) partitioning required for in situ density conversion of high-density NAPLs, such as tetrachloroethene (PCE), could limit the utility of the DMD method. Hence, the objective of this study was to compare the efficacy of two n-butanol delivery approaches: an aqueous solution of 6% (wt) n-butanol and a surfactant-stabilized macroemulsion containing 15% (vol) n-butanol in water, to achieve density reduction of PCE-NAPL in two-dimensional (2-D) aquifer cells. Results of liquid-liquid equilibrium studies indicated that density conversion of PCE relative to water occurred at an n-butanol mole fraction of 0.56, equivalent to approximately 5 ml n-butanol per 1 ml of PCE when in equilibrium with an aqueous solution. In 2-D aquifer cell studies, density conversion of PCE was realized using both n-butanol preflood solutions, with effluent NAPL samples exhibiting density reductions ranging from 0.51 to 0.70 g/ml. Although the overall PCE mass recoveries were similar (91% and 93%) regardless of the n-butanol delivery method, the surfactant-stabilized macroemulsion preflood removed approximately 50% of the PCE mass. In addition, only 1.2 pore volumes of the macroemulsion solution were required to achieve in situ density conversion of PCE, compared to 6.4 pore volumes of the 6% (wt) n-butanol solution. These findings demonstrate that use of the DMD method with a surfactant-stabilized macroemulsion containing n-butanol holds promise as an effective source zone remediation technology, allowing for efficient recovery of PCE-DNAPL while mitigating downward migration of the dissolved plume and free product.     

The Identification of Xenobiotics in the New UK Context of Drinking Water Safety Planning and Related Environmental Legislation

Recent European environmental legislation (the Water Framework Directive, the Environmental Liability Directive, and the REACH Regulation) should provide better protection of terrestrial water bodies but their focus is on the more conspicuous pollutants, as opposed to the large number of xenobiotic micro-pollutants that are increasingly being detected in the urban water cycle. The development of Drinking Water Safety Plans (DWSPs), as promoted by the World Health Organization, utilises a proactive risk assessment—risk management approach that necessarily should include micro-pollutants, although currently in the UK micro-pollutants have largely been ignored. The generic assessment of the risks posed by micro-pollutants is proposed and will require a consensus on analytical screening methods, sampling points and frequencies, and a method for prioritising concern, and would enable DWSPs to take fuller account of the risks posed.     

Molecular structures and associations of humic substances in the terrestrial environment

Here we show, for the first time, evidence of the primary molecular structures in humic substances (HS), the most abundant naturally occurring organic molecules on Earth, and their associations as mixtures in terrestrial systems. Multi-dimensional nuclear magnetic resonance (NMR) experiments show us that the major molecular structural components in the mixtures operationally defined as HS are aliphatic acids, ethers, esters and alcohols; aromatic lignin derived fragments; polysaccharides and polypeptides. By means of diffusion ordered spectroscopy, distinct diffusion coefficients consistent with relatively low molecular weight molecules were observed for all the components in the mixtures, and saccharides were the largest single class of component present. Liquid chromatography NMR confirmed that HS components can be easily separated and nuclear Overhauser effect (NOE) enhancements support the finding that the components are of relatively low molecular weight <~2,000 Da. The widely recognized properties of HS, i.e., characteristics indicative of crosslinked, macromolecular networks, can now be explained as aggregation of mixtures, most likely instigated by complexation with metal cations.     

LOW FLOW SPATIAL CHARACTERISTICS IN FORESTED HEADWATER CHANNELS OF SOUTHWEST WASHINGTON1

ABSTRACT: Patterns of dry season surface flow in forested headwater channels of southwest Washington were observed during August to September 2001 and July to October 2002. In 2001, 17 channels were sampled once, and the uppermost points of continuous flow (CF) and surface water (SW) were located. In 2002, sampling was replicated three to five times at each of 21 channels. Annual and seasonal data suggested that the location of SW varied less than CF. In most channels, SW remained at or near the channel head year around. The pattern of surface flow between CF and the channel head was used to test alternative hypotheses describing dry season recession patterns: (A) surface flow consistently retreats in a downstream direction, and (B) flow comes from fixed sources along the channel, thus surface flow retreats up‐channel towards these sources. The dominant surface flow spatial pattern in streams less than 30 percent slope was increased intermittency without a clear pattern of retreat, and thus inconsistent with either hypothesis. High gradient channels (< 30 percent slope) exhibited a combination of increased intermittency, and extensive upward retreats of surface water consistent with Hypothesis B. Differences between 2001 and 2002 suggest late summer flows in small headwater basins were controlled by spring precipitation, rather than the typically greater winter precipitation.     

Chemically mediated avoidance of a predatory odonate (Anaxjunius) by American toad (Bufoamericanus) and wood frog (Ranasylvatica) tadpoles

Predators can have significant nonlethal effects on prey by modifying prey behaviour through chemically mediated interactions. We examined behavioural responses of wood frog (Ranasylvatica) and American toad (Bufoamericanus) tadpoles to both direct and indirect chemical signals associated with a predatory odonate (Anaxjunius). In laboratory trials, tadpoles of both species responded strongly to water conditioned with Anax nymphs by decreasing foraging rates, becoming immobile, and moving away from the stimulus. The responses to water conditioned with starved Anax versus Anax that fed on conspecific tadpoles did not differ significantly; these results suggest that tadpoles rely primarily on direct signals to detect odonates. Rana did not respond to water conditioned with conspecific tissue extracts, while Bufo responded with behaviours that were indistinguishable from those of tadpoles exposed to Anax chemicals. In a field experiment, the responses of R. sylvatica tadpoles to Anax chemicals were similar to those of tadpoles observed in the laboratory. Collectively, our data indicate that tadpoles of both species use chemical cues to assess predation risk from other community members. Tadpoles can selectively distinguish members who pose a threat, and only evacuate food patches or reduce foraging rates when in danger. These behaviours appear to be adaptive and are consistent with the predictions of optimality theory. Received: 1 August 1997 / Accepted after revision: 22 November 1997     

A Technique for Plume Visualization in Power Plant Siting

Because of the increasing demand for energy, construction of a number of large power plants is planned, particularly in the southwestern U.S. Before construction of a plant can begin, however, it must be shown that its emissions will not degrade air quality beyond certain acceptable limits. A new plant must undergo not only a New Source Review¹ to demonstrate compliance with New Source Performance Standards,² but also an analysis to show that it will not produce significant deterioration of air quality in designated pristine areas (often these areas are state or federal parks.) Further, as a result of the 1977 amendments³ to the Clean Air Act, visibility must not be impaired where impairment is defined as a reduction in visual range or as atmospheric discoloration. Plume visual impact must thus be considered before permission for construction will be granted. Because of these requirements, it is important to be able to visualize the plume from a power plant as it travels through surrounding terrain.