The objective of this study was to investigate the nitritation performance in a biofilm reactor for treating domestic wastewater.The reactor was operated in continuous feed mode from phases 1 to 3.The dissolved oxygen(DO)was controlled at 3.5–7 mg/L throughout the experiment.The biofilm reactor showed excellent nitritation performance after the inoculation of nitrifying sludge,with the hydraulic retention time being reduced from 24 to 7 hr.Above 90%nitrite accumulation ratio(NAR)was maintained in phase 1.Afterwards,nitratation occurred with the low NH_4~+–N concentration in the reactor.The improvement of NH_4~+–N concentration to 20–35 mg/L had a limited effect on the recovery of nitritation.However,nitritation recovered rapidly when sequencing batch feed mode was adopted in phase 4,with the effluent NH_4~+-N concentration above 7 mg/L.The improvement of ammonia oxidizing bacteria(AOB)activity and the combined inhibition effect of free ammonia(FA)and free nitrous acid(FNA)on the nitrite oxidizing bacteria(NOB)were two key factors for the rapid recovery of nitritation.Sludge activity was obtained in batch tests.The results of batch tests had a good relationship with the long term operation performance of the biofilm reactor. 相似文献
As a convenient method, the closed chamber method has been applied to determine gaseous emission fluxes from fully open animal feeding operations despite the measured fluxes being theoretically affected by deployment time, wind speed over the emitting surface and detected gas mass. This laboratory study evaluated the effects of deployment time (0 to 120 min) and external surface wind speed (ESWS) (0.00, 0.25, 0.50, 0.75, 1.00, 1.50 and 2.00 m sec-1) on the measurement accuracy of a 300 mm (diameter) × 400 mm (height) (D300×H400) closed chamber using methane (CH4), nitrous oxide (N2O) and sulfur hexafluoride (SF6) as reference gases. The results showed that the overall deviation ratio between the measured and reference CH4 fluxes ranged from 9.99 % to -37.32 % and the flux was overestimated in the first 20 min. The measured N2O and SF6 emissions were smaller than the reference fluxes using the chamber. N2O measurement accuracy decreased from -14.47 to -35.09% with deployment time extended to 120 min, while SF6 accuracy sharply increased in the first 40 min, with the deviation stabilizing at approximately -5.00%. CH4, N2O and SF6 measurements were significantly affected by deployment time and ESWS (P<0.05), and the interaction of those two factors greatly influenced CH4 and SF6 measurements (P<0.05). With the D300×H400 closed chamber, deployment times of 20 to 30 min and 10 to 20 min are recommended to measure CH4 and N2O, respectively, from the open operations of dairy farms under wind speeds lower than 2 m sec-1.
Implications: This study recommended the suitable deployment times and wind speeds for using a D300 × H400 closed chamber to measure CH4, N2O, and SF6 in an open system, such as a dairy open lot and manure stockpile, to help researchers and other related industry workers get accurate data for gas emission rate. Deployment times of 20 to 30 min and 10 to 20 min were recommended to measure CH4 and N2O emissions using the D300 × H400 closed chamber, respectively, from the open operations of dairy farms under wind speeds lower than 2 m sec?1. For the measurement of SF6, a typical tracer gas, a deployment of 70 to 90 min was suggested. 相似文献
Semiconductor photocatalytic technology has shown great prospects in converting solar energy into chemical energy to mitigate energy crisis and solve environmental pollution problems. The key issue is the development of high-efficiency photocatalysts. Various strategies in the state-of-the-art advancements, such as heterostructure construction, heteroatom doping, metal/single atom loading, and defect engineering, have been presented for the graphitic carbon nitride (g-C3N4)-based nanocomposite catalysts to design their surface chemical environments and internal electronic structures to make them more suitable for different photocatalytic applications. In this review, nanoarchitecture design, synthesis methods, photochemical properties, potential photocatalytic applications, and related reaction mechanisms of the modified high-efficiency carbon nitride-based photocatalysts were briefly summarized. The superior photocatalytic performance was identified to be associated with the enhanced visible-light response, fast photoinduced electron-hole separation, efficient charge migration, and increased unsaturated active sites. Moreover, the further advance of the visible-light harvesting and solar-to-energy conversions are proposed. 相似文献
能源转型是全球落实联合国2030可持续发展目标过程中的重要议题,在发展中国家尤为突出。中国和印度作为世界上最大的两个发展中国家,面临着相似的能源转型挑战。本文利用能源发展指数(Energy Development Index,EDI)方法,从能源可获得性与可负担性两个维度衡量比较了中印能源发展利用情况。研究结果表明,印度能源发展在总体上落后于中国,其主要差距表现在能源价格与能源结构两方面。其中,印度能源价格呈增长态势,2010—2014年年均增速达9.6%;而中国能源平均价格整体呈下降趋稳态势(除煤气价格外)。同时,印度能源消费结构中的传统生物质能源占比较高,是中国传统生物质能源占比的6.6倍(2017年)。研究指出,从传统能源向可再生能源的转变是中印两国提升能源可持续供给能力和现代能源服务体系的重要途径,两国可以通过绿色技术合作共同解决能源可持续转型问题,携手实现全球低碳可持续发展目标。 相似文献