全文获取类型
收费全文 | 4380篇 |
免费 | 204篇 |
国内免费 | 1628篇 |
专业分类
安全科学 | 310篇 |
废物处理 | 282篇 |
环保管理 | 338篇 |
综合类 | 2443篇 |
基础理论 | 739篇 |
污染及防治 | 1577篇 |
评价与监测 | 159篇 |
社会与环境 | 154篇 |
灾害及防治 | 210篇 |
出版年
2024年 | 5篇 |
2023年 | 62篇 |
2022年 | 230篇 |
2021年 | 179篇 |
2020年 | 129篇 |
2019年 | 142篇 |
2018年 | 149篇 |
2017年 | 230篇 |
2016年 | 227篇 |
2015年 | 248篇 |
2014年 | 316篇 |
2013年 | 480篇 |
2012年 | 361篇 |
2011年 | 434篇 |
2010年 | 275篇 |
2009年 | 267篇 |
2008年 | 346篇 |
2007年 | 270篇 |
2006年 | 256篇 |
2005年 | 165篇 |
2004年 | 122篇 |
2003年 | 170篇 |
2002年 | 133篇 |
2001年 | 103篇 |
2000年 | 128篇 |
1999年 | 112篇 |
1998年 | 102篇 |
1997年 | 114篇 |
1996年 | 82篇 |
1995年 | 87篇 |
1994年 | 62篇 |
1993年 | 61篇 |
1992年 | 56篇 |
1991年 | 44篇 |
1990年 | 27篇 |
1989年 | 9篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 1篇 |
排序方式: 共有6212条查询结果,搜索用时 15 毫秒
231.
Humic acid superabsorbent polymer (P(AA/AM-HA)) and superabsorbent polymer (P(AA/AM)) were synthesized by aqueous solution polymerization method using acrylic acid (AA), acrylamide (AM) and humic acid (HA) as raw material. The effects of N,N'-methylenebisacrylamide (MBA) crosslinking agent, potassium peroxydisulfate (KPS) initiator, reaction temperature, HA content, ratio of AA to AM, concentration of monomer and neutralization of AA on water absorption were investigated. Absorption and desorption ratios of nitrogen fertilizer and phosphate fertilizer were also investigated by determination of absorption and desorption ratio of NH4+, PO43- on P(AA/AM-HA) and P(AA/AM). The P(AA/AM-HA) and P(AA/AM) were characterized by Fourier translation infrared spectroscopy, biological photomicroscope and scanning electron microscopy (SEM). The optimal conditions obtained were as follows: the weight ratio of MBA to AA and AM was 0.003; the weight ratio of KPS to AA and AM was 0.008; the weight ratio of HA to AA was 0.1; the mole ratio of AM to AA is 0.1; the mole ratio of NaOH to AA is 0.9; the reaction temperature was 60℃. P(AA/AMHA) synthesized under optimal conditions, has a good saline tolerance, its water absorbency in distilled water and 0.9 wt.% saline solution is 1180 g/g and 110 g/g, respectively. P(AA/AM-HA) achieves half saturation in 6.5 min. P(AA/AM-HA) is superior to P(AA/AM) on absorption of NH4+, PO43-. The SEM micrograph of P(AA/AM-HA) shows a fine alveolate structure. The biological optical microscope micrograph of P(AA/AM-HA) shows a network structure. Graft polymerization between P(AA/AM) and HA was demonstrated by infrared spectrum. The P(AA/AM-HA) superabsorbent has better absorbing ability of water and fertilizer, electrolytic tolerance and fewer cost than P(AA/AM) superabsorbent. 相似文献
232.
Xiangyun Zhong Shiyong Wu Yang Liu Zhenning Zhao Yaru Zhang Jinfeng Bai Jun Xu Bai Xi 《环境科学学报(英文版)》2013
The evolvement of morphology and structure of the coal with different metamorphic degrees during coking process in the vertical furnace was investigated by infrared Image detector. Moreover, the temperature distribution in the radial direction and the crack formation were also studied in heating process. The results show that the amount of crack and the shrinkage level of char decrease with the coal rank rising. In addition, the initial temperature of crack formation for char increases with the coal rank rising. 相似文献
233.
An online monitoring system for atmospheric nitrous acid (HONO) based on stripping coil and ion chromatography 总被引:1,自引:0,他引:1
Peng Cheng Yafang Cheng Keding Lu Hang Su Qiang Yang Yikan Zou Yanran Zhao Huabing Dong Limin Zeng Yuanhang Zhang 《环境科学学报(英文版)》2013,25(5):895-907
A new instrument for measuring atmospheric nitrous acid(HONO) was developed,consisting of a double-wall glass stripping coil sampler coupled with ion chromatography(SC-IC).SC-IC is featured by small size(50 × 35 × 25 cm) and modular construction,including three independent parts:the sampling unit,the transfer and supporting unit,and the detection unit.High collection efficiency(> 99%) was achieved with 25 μmol/L Na2CO3 as absorption solution even in the presence of highly acidic compounds.This instrument has a detection limit of 8 pptv at 15 min time resolution,with a measurement uncertainty of 7%.Potential interferences from NOx,NO2+SO2,NO2+VOCs,HONO+O3,HNO3,peroxyacetyl nitrite(PAN) and particle nitrite were quantified in laboratory studies and were found to be insignificant under typical atmospheric conditions.Within the framework of the 3C-STAR project,inter-comparison between the SC-IC and LOPAP(long path liquid absorption photometer) was conducted at a rural site in the Pearl River Delta.Good agreement was achieved between the two instruments over three weeks.Both instruments determined a clear diurnal profile of ambient HONO concentrations from 0.1 to 2.5 ppbv.However,deviations were found for low ambient HONO concentrations(i.e.< 0.3 ppbv),which cannot be explained by previous investigated interference species.To accurately determine the HONO budget under illuminated conditions,more intercomparison of HONO measurement techniques is still needed in future studies,especially at low HONO concentrations. 相似文献
234.
以重铬酸钾为供试物,用固体平板法和还原实验对铬(Ⅵ)土著还原菌进行筛选,用载片培养法、革兰氏染色法、鞭毛染色法、芽孢染色法对还原菌做初步的鉴定,共筛选出16株铬(Ⅵ)土著还原菌,并挑选出还原率相对较高的Z2(35.2%)、Z3(45.2%)、Z4(38.6%)、X8(30.4%)、X10(29.4%)作为铬(Ⅵ)的优势还原菌株。经初步鉴定,土著真菌Z2为黑曲霉(Aspergillusniger),Z3、Z4为镰刀菌属(Fusariumsp.),土著细菌X8、X10为芽孢杆菌(Bacillussp.)。实验的方法和成果将为铬(Ⅵ)污染土壤微生物治理技术的推广应用提供技术支持。 相似文献
235.
236.
237.
238.
介绍了火电厂除尘器应用现状,论述了电除尘器、袋式除尘器和电袋复合式除尘器的原理及特点,分析了电除尘器和袋式除尘器存在的问题,强调了根据火电厂情况合理选择除尘器类型. 相似文献
239.
240.