石英灯辐射加热条件下低密度碳/酚醛复合材料高温响应及分析

目的研究低密度碳/酚醛复合材料在不同地面加热实验测试响应的差异性,指导材料在实际应用环境下的高温响应分析。方法对低密度碳/酚醛复合材料开展了热流为400 kW/m~2的单侧石英灯辐射加热实验,利用热电偶测温系统测量试件在加热过程中不同位置的温度时间历程,并对试件的烧蚀形貌和微观结构进行观测。同时与热流为464k W/m~2的氧乙炔加热陶瓷板辐射加热实验结果进行对比分析,并且采用有限元方法对材料的传热传质多场耦合计算进行分析。结果对于石英灯辐射加热,在测量点升温到接近200℃时,温度响应拐点都依次出现。由于加热的辐射热源不同,在不同的辐射波段下,多孔材料吸收和发射的热量不同,短时间内氧乙炔加热陶瓷板辐射加热使材料内部升温速率比石英灯辐射加热实验的要快,但长时间加热时现象刚好相反。结论进行传热传质多场耦合计算材料高温响应时,合理确定材料宏观性能随温度的变化至关重要。     

专家笔谈：资源环境热点问题

重大的资源开发利用工程建设设想或实施往往容易引起社会各界的广泛关注。如何正确认识和科学评价各种资源环境热点问题是大家讨论的重点。文章认为任何重大资源开发工程必须遵循自然规律、生态规律、资源规律和经济规律,必须结合国家战略需求和地缘政治关系,开展前期深入的系统性综合调查,进行生态安全与资源工程安全评价和交叉学科论证,并对其科学价值、社会价值和经济价值等做出正确的判断。建议：未来的资源环境工程建设要谨防“大跃进”,要科学认识自然资源系统规律,守护好美丽的地球家园;要切实履行资源科学家的社会责任,提倡基于科学研究和科学态度的学术争鸣,科学问题最好还是由科学家去讨论;一些争议大的科研课题慎用公益性研发经费来支持。     

Effects of Na+ on Cu/SAPO-34 for ammonia selective catalytic reduction

Copper-exchanged chabazite (Cu/CHA) catalysts have been found to be affected by alkali metal and alkaline earth ions. However, the effects of Na⁺ ions on Cu/SAPO-34 for ammonia selective catalytic reduction (NH₃-SCR) are still unclear. In order to investigate the mechanism, five samples with various Na contents were synthesized and characterized. It was observed that the introduced Na⁺ ion-exchanges with H⁺ and Cu^2 + of Cu/SAPO-34. The exchange of H⁺ is easier than that of isolated Cu^2 +. The exchanged Cu^2 + ions aggregate and form “CuAl₂O₄-like” species. The NH₃-SCR activity of Cu/SAPO-34 decreases with increasing Na content, and the loss of isolated Cu^2 + and acid sites is responsible for the activity loss.     

广东省生活垃圾焚烧设施环境与健康风险评估构架研究

生活垃圾焚烧设施的建立是解决城市生活垃圾逐年增多的有效方式之一,但其所引发的环境与健康问题成为公众关注的热点。基于广东省对生活垃圾焚烧设施的研究,以环境管理为目标,结合国内外在该领域的研究现状,提出广东省生活垃圾焚烧设施环境与健康风险评估构架。通过该构架的多年实践,总结了广东省生活垃圾焚烧设施环境与健康风险评估研究所取得的成效,有望将该成果推而广之,从而使该行业实现绿色生态的蓬勃发展。     

绿色环境保护节能建筑的设计与实现研究

为了实现建筑行业的可持续发展,设计并实现绿色环保节能建筑,将节能环保理念渗透在建筑设计的每个细节中。分析融入节能环保理念的建筑设计过程,对其中的架构环保节能设计、节能环保材料的选用以及节能环保技术发展进行研究,并重点分析了资源可持续利用、太阳能利用以及电气节能技术在绿色环保节能建筑设计中的应用过程。通过绿色建筑节能环保总设计,绿色节能环保建筑构造的优化设计以及绿色建筑的暖通空调设计,实现绿色环保节能建筑的高质量设计。     

污染物在地下水毛细饱水带的运移规律浅释

分析了毛细饱水带的水动力学特性，指出在地下水污染研究中，污染物在毛细饱和水带和潜水怪具有相同的水平运动规律，并以实例分析说明该带对污染物运移的重要性。建议在研究和一非饱和条件地下水及污染物运动问题时把毛细饱水带与潜水含水层统一为饱马毛细饱水带顶面作为饱水面。     

乌鲁木齐市餐饮业油烟污染的调查及防治初探

通过对乌鲁木齐市20家餐饮业油烟污染的调查分析，结果表明，乌鲁木齐市餐饮业油烟污染严重，并提出了防治措施。     

Groundwater quality under the influence of spent mushroom substrate weathering

Nitrate and other solutes resulting from field-weathering of spent mushroom substrate (SMS) percolate into underlying soils and may migrate to groundwater. A field trial was conducted to investigate the potential influences of SMS weathering on groundwater quality. Spent mushroom substrate was deposited at 90 and 150 cm pile depths over a Typic Hapludult and weathered for 2 years. Eight casing wells were installed around the SMS piles to monitor the quality changes of groundwater with a high seasonal water table of 760 cm below the surface. Although leachate solutes had moved more than 200 cm deep in soil from the surface, no significant changes of groundwater quality caused by SMS weathering were observed even one year after removal of the SMS piles (3 years total). The groundwater had pH, electrical conductivity (EC) and dissolved organic carbon (DOC) of 4.3-5.7, 0.2-0.3 dS m(-1) and 0.7-2.2 mg L(-1), respectively. The major inorganic ions were Mg(2+), Ca(2+), Na(+), Cl(-), SO(4)(2-) and NO(3)(-), with a concentration range of 2.5-68.3 mg L(-1). The results suggest that SMS leachate solutes migrated fairly slow in deep subsurface soils of the experimental field. Considering that leachate solutes may move several meters in soil through preferential flow channels, weathering of SMS in fields with a high seasonal groundwater table >or=5 m below the ground is recommended. Conservatively, SMS weathering should be conducted on compact surfaces and leachate be collected and reused as liquid fertilizers.     

石河子市空气污染成因及防治对策

对石河子市空气环境质量状况进行了评价，对影响石河子市环境质量的主要因素进行了分析，得出石河子市空气污染属煤烟沙尘型，提出了相应的治理措施和建议。     

Occurrence of dissolved PAHs in the Jinsha River (Panzhihua)--upper reaches of the Yangtze River,Southwest China

16 priority polycyclic aromatic hydrocarbons (PAHs) were determined in water samples from the Jinsha River (Panzhihua part), Southwest China. Total dissolved PAH concentrations varied from 21.89 microg l(-1) to 382.8 microg l(-1). It was found that the concentration of PAHs decreased along the flow direction due to the higher density distribution of coal chemical industry in the upstream of our study rivers. The pollution levels in our study area are significantly higher than previously reported values in other waters both in China and other countries. The predominance of benzo[k]fluoranthene and indeno[1,2,3-cd]pyrene was clearly observed in all water samples. On average these two compounds accounted for 98.3% of the total dissolved PAH concentration in water. The results showed the positive correlations among total dissolved PAHs, benzo[k]fluoranthene and indeno[1,2,3-cd]pyrene, which suggested that these two predominant PAHs have similar source and environmental behaviors in our study area. When compared with the survey results of organic micropollutants two decades ago, it was found that hydrocarbon pollution both predominated and even increased with the development of coal chemical industry in this area during the past 20 years. The results therefore provide important information on the current contamination status of a key industrial city in China, and points to the need for urgent action to investigate the relationship between the PAH composition and concentration in water from the Jinsha River and the wastewater discharge from coal chemical industry, and to identify the source, transport pathway and fate of PAHs in the area. It should then be necessary to adopt appropriate and instant measures to control the pollution around this area.