Persistence and vertical distribution of termiticide fipronil in modified ground board test

Fipronil termiticide belongs to phenyl-pyrazole class of chemical compounds. It has broad-spectrum activity particularly against house hold pests such as cockroaches, mosquitoes, locusts, ticks, and fleas at both larval and adult stages. At high dosage it can be used to control subterranean termites in building foundations. To evaluate long term efficacy against termites the persistence and vertical distribution of fipronil was studied under natural weather conditions of Dehradun, India. Fipronil was applied at four concentrations i.e. 0.05, 0.1, 0.25 and 0.5% a.i ha⁻¹ by drenching 17 × 17 in.² plot prepared as per modified ground board test. Soil samples were collected after 22, 38 and 56 months of treatment up to the depth of 75 cm. The soil core was cut into five distinct sections i.e. 0–15, 15–30, 30–45, 45–60 and 60–75 cm depth. The residues were extracted by shaking 20 g soil sample with acetone. The acetone extract was concentrated and cleaned-up over florisil column. Fipronil residues were estimated on GLC at 220, 260, and 300°C oven, injector and detector temperature respectively. Fipronil was found to persist beyond 56 months after application. Two metabolites viz. desulfinyl and sulfide-fipronil were detected in sampling after 22 months of application that also dissipated with time. Fipronil residues were found up to 60 cm depth. The residues in deeper layers dissipate slowly with time and after 56 months of treatment residues were detected only up to 30 cm depth.     

Predicting dissolved oxygen concentration using kernel regression modeling approaches with nonlinear hydro-chemical data

Kernel function-based regression models were constructed and applied to a nonlinear hydro-chemical dataset pertaining to surface water for predicting the dissolved oxygen levels. Initial features were selected using nonlinear approach. Nonlinearity in the data was tested using BDS statistics, which revealed the data with nonlinear structure. Kernel ridge regression, kernel principal component regression, kernel partial least squares regression, and support vector regression models were developed using the Gaussian kernel function and their generalization and predictive abilities were compared in terms of several statistical parameters. Model parameters were optimized using the cross-validation procedure. The proposed kernel regression methods successfully captured the nonlinear features of the original data by transforming it to a high dimensional feature space using the kernel function. Performance of all the kernel-based modeling methods used here were comparable both in terms of predictive and generalization abilities. Values of the performance criteria parameters suggested for the adequacy of the constructed models to fit the nonlinear data and their good predictive capabilities.     

Seasonal variations and source profile of <Emphasis Type="Italic">n</Emphasis>-alkanes in particulate matter (PM<Subscript>10</Subscript>) at a heavy traffic site,Delhi

Delhi is one of the most polluted cities in the world. The generation of aerosols in the lower atmosphere of the city is mainly due to a large amount of natural dust advection and sizable anthropogenic activities. The compositions of organic compounds in aerosols are highly variable in this region and need to be investigated thoroughly. Twenty-four-hour sampling to assess concentrations of n-alkanes (ng/m³) in PM₁₀ was carried out during January 2015 to June 2015 at Indira Gandhi Delhi Technical University for Women (IGDTUW) Campus, Delhi, India. The total average concentration of n-alkanes, 243.7 ± 5.5 ng/m³, along with the diagnostic tools has been calculated. The values of CPI₁, CPI₂, and CPI₃ for the whole range of n-alkanes series, petrogenic n-alkanes, and biogenic n-alkanes were 1.00, 1.02, and 1.04, respectively, and C _max were at C₂₅ and C₂₇. Diagnostic indices and curves indicated that the dominant inputs of n-alkanes are from petrogenic emissions, with lower contribution from biogenic emissions. Significant seasonal variations were observed in average concentrations of n-alkanes, which is comparatively higher in winter (187.4 ± 4.3 ng/m³) than during the summer season (56.3 ± 1.1 ng/m³).     

Sulfamethazine uptake by plants from manure-amended soil

Animal manure is applied to agricultural land as a means to provide crop nutrients. However, animal manure often contains antibiotics as a result of extensive therapeutic and subtherapeutic use in livestock production. The objective of this study was to evaluate plant uptake of a sulfonamide-class antibiotic, sulfamethazine, in corn (Zea mays L.), lettuce (Lactuca sativa L.), and potato (Solanum tuberosum L.) grown in a manure-amended soil. The treatments were 0, 50, and 100 microg sulfamethazine mL(-1) manure applied at a rate of 56 000 L ha(-1). Results from the 45-d greenhouse experiment showed that sulfamethazine was taken up by all three crops, with concentrations in plant tissue ranging from 0.1 to 1.2 mg kg(-1) dry weight. Sulfamethazine concentrations in plant tissue increased with corresponding increase of sulfamethazine in manure. Highest plant tissue concentrations were found in corn and lettuce, followed by potato. Total accumulation of sulfamethazine in plant tissue after 45 d of growth was less than 0.1% of the amount applied to soil in manure. These results raise potential human health concerns of consuming low levels of antibiotics from produce grown on manure-amended soils.     

Comparisons of TGA and DSC approaches to evaluate nitrocellulose thermal degradation energy and stabilizer efficiencies

This study investigated the thermal degradation energy (activation energy, E_a) for nitrocellulose (NC) with low nitrogen content of 11.71 mass%, so-called NC3, by using two different kinds of thermal analysis instruments: thermogravimetric analyzer (TGA) and differential scanning calorimetry (DSC). A comparison of E_a for various nitrogen content NC samples at two scanning rates (5 and 10 °C min^?1) tested by TGA and DSC is also discussed in this paper. Meanwhile, our aim was to analyze the anti-degradation of E_a for NC with high nitrogen content, as so-called NC1. Thermal stability for NC1 with diphenylamine (DPA) was tested via DSC with 10 DPA concentrations in weights of 0, 0.25, 0.50, 0.75, 1.0, 1.25, 1.50, 1.75, 2.0, and 3.0 mass%. Experimental results indicated that E_a of NC3s was 319.91 kJ mol^?1. Moreover, that while dosing DPA into NC1 the best recipe could be employed to avoid any violent NC1 runaway and also can be used to distinguish the differences of thermal decomposition E_a between NC with different nitrogen contents. This study established a fast and efficient procedure for thermal decomposition properties of NC, and could be applied as an intrinsically safer design during relevant operations.     

Air pollution perception in ten countries during the COVID-19 pandemic

As largely documented in the literature, the stark restrictions enforced worldwide in 2020 to curb the COVID-19 pandemic also curtailed the production of air pollutants to some extent. This study investigates the perception of the air pollution as assessed by individuals located in ten countries: Australia, Brazil, China, Ghana, India, Iran, Italy, Norway, South Africa and the USA. The perceptions towards air quality were evaluated by employing an online survey administered in May 2020. Participants (N = 9394) in the ten countries expressed their opinions according to a Likert-scale response. A reduction in pollutant concentration was clearly perceived, albeit to a different extent, by all populations. The survey participants located in India and Italy perceived the largest drop in the air pollution concentration; conversely, the smallest variation was perceived among Chinese and Norwegian respondents. Among all the demographic indicators considered, only gender proved to be statistically significant.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-021-01574-2.     

Salt-induced land and water degradation in the Aral Sea basin: A challenge to sustainable agriculture in Central Asia

Expansion of irrigated agriculture in the Aral Sea Basin in the second half of the twentieth century led to the conversion of vast tracks of virgin land into productive agricultural systems resulting in significant increases in employment opportunities and income generation. The positive effects of the development of irrigated agriculture were replete with serious environmental implications. Excessive use of irrigation water coupled with inadequate drainage systems has caused large‐scale land degradation and water quality deterioration in downstream parts of the basin, which is fed by two main rivers, the Amu‐Darya and Syr‐Darya. Recent estimates suggest that more than 50% of irrigated soils are salt‐affected and/or waterlogged in Central Asia. Considering the availability of natural and human resources in the Aral Sea Basin as well as the recent research addressing soil and water management, there is cause for cautious optimism. Research‐based interventions that have shown significant promise in addressing this impasse include: (1) rehabilitation of abandoned salt‐affected lands through halophytic plant species; (2) introduction of 35‐day‐old early maturing rice varieties to withstand ambient soil and irrigation water salinity; (3) productivity enhancement of high‐magnesium soils and water resources through calcium‐based soil amendments; (4) use of certain tree species as biological pumps to lower elevated groundwater levels in waterlogged areas; (5) optimal use of fertilizers, particularly those supplying nitrogen, to mitigate the adverse effects of soil and irrigation water salinity; (6) mulching of furrows under saline conditions to reduce evaporation and salinity buildup in the root zone; and (7) establishment of multipurpose tree and shrub species for biomass and renewable energy production. Because of water withdrawals for agriculture from two main transboundary rivers in the Aral Sea Basin, there would be a need for policy level interventions conducive for enhancing interstate cooperation to transform salt‐affected soil and saline water resources from an environmental and productivity constraint into an economic asset.     

Oxidative stress and arsenic toxicity: Role of NADPH oxidases

The effect of arsenic (25 and 50 μM As for 1 and 5 d) was analysed in wild type (WT) and Arabidopsis thaliana (L.) Heynh plants deficient in NADPH oxidase C (AtrbohC). The content of H₂O₂ and malondialdehyde (MDA) increased with the As concentration, while the opposite effect was found for NO in WT and AtrbohC plants. The As treatment reduced catalase and increased glutathione reductase activities to the same extent in WT and AtrbohC plants, although the induction of all SOD isoforms (mainly CuZn–SODs) was observed in WT plants, the opposite effects being found in AtrbohC plants. Glycolate oxidase (H₂O₂ producers) considerably increased with the concentration and time of treatment with As in WT and AtrbohC mutants. Arsenic induced the uptake and translocation of P, S, Cu, Zn, and Fe in WT plants, while in AtrbohC plants the opposite trend was noted and the uptake of As became considerably lower than in WT plants. These results suggest that As causes oxidative stress by inducing glycolate oxidase, while NADPH oxidase does not appear to participate in ROS overproduction but could be critical in regulating antioxidant defences as well as the transport and translocation of As and macro/micronutrients.     

Association between environmental exposure to p,p′-DDE and lindane and semen quality

Scientific concern exists about the toxic effect of dichlorodiphenyldichloroethylene (p, p′-DDE) and lindane on male infertility, and the mechanism underlying male reproductive toxicity of this pesticide remains unanswered. We investigated not only the possible association between the chlorinated pesticide levels and semen quality in nonoccupationally exposed men, but also the probable mode of action using mitochondrial membrane potential (MMP), reactive oxygen species (ROS), lipid peroxidation (LPO), and sperm chromatin structure assay (SCSA). A study in 278 men (21–40 years old) who visited Obstetrics and Gynecology Department, KGMU, Lucknow, for semen analysis was conducted. We performed semen analysis according to the WHO guidelines, while p, p′-DDE and lindane analysis was done by the GLC and LPO by the spectrophotometer, and the sperm mitochondrial status, ROS, and SCSA with the flow cytometer. The questionnaire data showed no significant difference in the demographic characteristics between the two groups, i.e., trying to conceive >1 year and proven fertility. However, a significant difference in the concentration of p, p′-DDE and lindane was observed between the groups. When the subjects were divided among four categories by quartile of exposure, the subjects in the highest quartile showed low sperm motility as compared to the subjects in the lowest quartile. Pearson’s correlation showed a significant negative correlation between semen p, p′-DDE, lindane level, and sperm quality and positive association with the number of cells with depolarized mitochondria, elevation in ROS production and LPO, and DNA fragmentation index (DFI). The findings are suggestive that these toxicants might cause a decline in semen quality, and these effects might be ROS, LPO, and mitochondrial dysfunction mediated.