Trends in environmental education for biodiversity conservation in Costa Rica

Costa Rica is internationally recognized for its abundant biodiversity and being a leader in the promotion of education strategies for biodiversity conservation. We interviewed staff from 16 institutions developing key environmental communication, education, and participation projects for biodiversity conservation in the country. Through content analysis, hierarchical cluster analysis and Chi-square tests, we examined the characteristics of the projects carried out by these institutions and developed a typology of four categories derived from six variables: primary audience, content, project purpose, location, scale, and facility. Then, we designed a conceptual model describing the integration of conservation and economic development in the educational projects. We found two key approaches related to this integration: vision of nature protection which aims to inform audiences of ecological concepts and focuses on schoolchildren and vision of sustainability which engages adult audiences and is management-oriented. Education for community-based environmental management may serve as a good example of educational projects which integrate conservation and economic development, implementing a vision of sustainability.     

Climate change impacts in Sub-Saharan Africa: from physical changes to their social repercussions

Regional Environmental Change - The repercussions of climate change will be felt in various ways throughout both natural and human systems in Sub-Saharan Africa. Climate change projections for this...     

Downscaling scenarios of future land use and land cover changes using a participatory approach: an application to mountain risk assessment in the Pyrenees (France)

Regional Environmental Change - Better understanding the pathways through which future socioeconomic changes might influence land use and land cover changes (LULCCs) is a crucial step in accurately...     

Investigating soils retention ratios and modelling geochemical factors affecting heavy metals retention in soils in a tropical urban watershed

This study aimed at investigating the retention of Pb and Cd in soils and the geochemical factors influencing the adsorption of these pollutants. Soil samples were air-dried and ground to pass through a 2-mm sieve, and different soil extracts were prepared for chemical analysis (organic matter, cation exchange capacity and pH). Total Pb and Cd were extracted with diacid using digestion method and determined by atomic adsorption spectrophotometer (AAS) after filtration. Results revealed that the heavy metals retention ratio (RR) of the Rhodic ferralsol, Xanthic ferralsol and Mollic gleysol (2) were very high for Cd (>80 %) and was relatively low (generally < 60 %) for Pb. In contrast, RRs for the Plinthic gleysol and the Mollic gleysol (1) were relatively low (<60 %), regardless of the heavy metal concerned. Multiple regression equations indicated for Pb and Cd concentrations different linear relationships over simple linear regression, when pH, organic matter, clay percentage and cation exchange capacity (CEC) were used as independent variables. Results indicate that organic matter exerts major influences on the retention of Pb and Cd in soils, while CEC, clay content and pH have a minor influence in this process in the Ntem watershed. From these observations, the application of soil organic matter could be a solution in protecting shallow aquifers from heavy metal pollution and thus insuring that they are not a hazard to public health.     

Seasonal ecophysiology of an endangered coastal species,the yellow-horned poppy (Glaucium flavum Crantz)

Glaucium flavum Crantz. is a short-lived perennial herb distributed in coastal zones from the Black Sea to southern, western and north-western Europe. Despite its diminishing area of distribution and potential pharmacological value, little is known about the ecophysiological features of this coastal species. We investigated the photosynthetic performance of G. flavum by measuring gas exchange, chlorophyll fluorescence, photosynthetic pigment concentration and leaf water content over the space of a year in a coastal habitat of SW Spain. We also measured the variation in total concentrations of nitrogen, phosphorus, sulphur, potassium, calcium and magnesium, in the leaves and soil, throughout the study period. G. flavum showed a high resistance to summer drought conditions which appeared to be due to the high degree of stomatal control. The potential photochemical efficiency of photosystem II showed minimum values during the winter, indicating that low temperatures can produce negative effects within the photosynthetic apparatus. However, the marked decline in net photosynthesis during the winter seems to be mainly related to a loss of metabolic activity. Although leaf nutrient concentrations were, in general, within the normal ranges, phosphorus availability seems to be limited by the high calcium concentrations detected in the soil of the study site. Our study points out the efficiency of the different physiological adaptations of this rare and endangered coastal species in coping with the strong seasonal variability of the Mediterranean climate.     

Evaluation of heavy metal content in digestate from batch anaerobic co-digestion of sunflower hulls and poultry manure

In this experimental study, the biogas digestate from mesophilic batch anaerobic co-digestion of poultry manure and an agricultural residue, sunflower hulls, was characterized, particularly in terms of heavy metal content, in order to evaluate whether the biogas digestate was suitable for land applications. Ni, Zn, Cu, Pb, Cr, Cd, and Hg were detected in the biogas digestate in each trial, however, their concentrations were always lower than the limit values stated in Turkish regulations. The main source of heavy metals in the biogas digestate seemed to be the poultry manure, not the agricultural residue. The commercial feedstuffs that are frequently supplemented with various essential elements to promote optimum nutrient supply and optimum growth rates may have contributed to heavy metals presence in the biogas digestate. The results indicated that the biogas digestate from anaerobic co-digestion of manure and agricultural residue could be utilized as fertilizer in agricultural applications.     

Advances in the recycling of plastic wastes for metallurgical coke production

This paper aims to provide useful knowledge on the use of plastic wastes as additives to coking blends for the production of metallurgical coke. It focuses on the influence that the composition of plastic wastes has upon the development of coal fluidity, the generation of pressure during the coking process and the quality of the cokes produced in a semipilot oven. Several plastic mixtures of two types of thermoplastics, polyolefins (HDPE, LDPE and PP) and aromatic polymers such as PET, were used. The overall addition rate of plastics to a medium-fluid coal blend was 2 wt%. It is shown that polyolefins, weaker modifiers of coal fluidity, may be employed to maintain coke quality but that they have a negative effect on the generation of coking pressure, while plastics of the aromatic type such as PET, a strong modifier of coal fluidity, can be used to counteract the generation of coking pressure. From the results, it is deduced that the protocol developed is useful for determining the optimum amount of each type of polymer (polyolefins and aromatic polymers) that is needed in order to counteract the generation of pressure during the coking process and to maintain the quality of the cokes.     

Comparative Sustainability Assessment of Starch Nanocrystals

Fossil energy depletion and growing environmental concerns have brought up increasing interest in bio-based eco-efficient and high technology materials. Among them, starch nanocrystals (SNC) consist of crystalline nano-platelets produced from the hydrolysis of starch and mainly used as nano-fillers in polymeric matrix. New applications have brought up the need for scaling-up the SNC preparation process. However, for this new bio-based nano-material to be sustainable, its preparation and processing should have limited impacts on the environment. Thus, together with analyzing and making recommendations for the scaling-up of SNC production process, it is worth identifying “environmentally sensitive” steps using life cycle analysis (LCA). To that purpose, different scenarios have been proposed and compared according to different environmental impacts. Also, a comparison to its main competitor, i.e. organically modified nanoclay (OMMT), is proposed. From a LCA point of view, SNC preparation requires less energy than OMMT extraction, but global warming and acidification indicators were higher than for OMMT. However, SNC have the added advantages to be renewable and biodegradable contrary to OMMT which contribute to non-renewable energy and mineral depletion. Thus, used as filler, SNC have a positive impact on the end of life of the filled material. From these observations, recommendations for the scaling-up of the SNC preparation process are made and deal mainly with the use of land and water.     

Preparation and Characterization of Three Different Derivatized Potato Starches

The use of native starch as a thermoplastic polymer is limited by its fragility and high water absorption. Due to the presence of several hydroxyl groups in its structure, water acts as a natural plasticizer of starch, modifying its properties. It is necessary to chemically modify starch molecules by replacing hydroxyl groups with other functional groups to reduce water absorption. Chemical modification of starch granules also alters its swelling and gelatinization behavior. In this contribution we describe the chemical modification of starch and its influence on its hydrophilicity and heat resistance. Acetic acid, maleic anhydride and octanoyl chloride were used as derivatizing reagents. The effectiveness of the treatments was evaluated by means of infrared spectroscopy. Different tests were conducted in order to evaluate the influence of the different chemical modifications on starch structure and properties. Results showed that the treatments effectively reduced starch moisture susceptibility, while substantially altering other properties such as amylose content, swelling power, solubility, and heat resistance. Finally, films were prepared from native and derivatized starch and their surface polarity was evaluated.     

Developmental toxicity of PAH mixtures in fish early life stages. Part II: adverse effects in Japanese medaka

In aquatic environments, polycyclic aromatic hydrocarbons (PAHs) mostly occur as complex mixtures, for which risk assessment remains problematic. To better understand the effects of PAH mixture toxicity on fish early life stages, this study compared the developmental toxicity of three PAH complex mixtures. These mixtures were extracted from a PAH-contaminated sediment (Seine estuary, France) and two oils (Arabian Light and Erika). For each fraction, artificial sediment was spiked at three different environmental concentrations roughly equivalent to 0.5, 4, and 10 μg total PAH g^?1 dw. Japanese medaka embryos were incubated on these PAH-spiked sediments throughout their development, right up until hatching. Several endpoints were recorded at different developmental stages, including acute endpoints, morphological abnormalities, larvae locomotion, and genotoxicity (comet and micronucleus assays). The three PAH fractions delayed hatching, induced developmental abnormalities, disrupted larvae swimming activity, and damaged DNA at environmental concentrations. Differences in toxicity levels, likely related to differences in PAH proportions, were highlighted between fractions. The Arabian Light and Erika petrogenic fractions, containing a high proportion of alkylated PAHs and low molecular weight PAHs, were more toxic to Japanese medaka early life stages than the pyrolytic fraction. This was not supported by the toxic equivalency approach, which appeared unsuitable for assessing the toxicity of the three PAH fractions to fish early life stages. This study highlights the potential risks posed by environmental mixtures of alkylated and low molecular weight PAHs to early stages of fish development.