全文获取类型
收费全文 | 6739篇 |
免费 | 54篇 |
国内免费 | 34篇 |
专业分类
安全科学 | 141篇 |
废物处理 | 351篇 |
环保管理 | 521篇 |
综合类 | 1015篇 |
基础理论 | 1645篇 |
环境理论 | 7篇 |
污染及防治 | 2191篇 |
评价与监测 | 539篇 |
社会与环境 | 395篇 |
灾害及防治 | 22篇 |
出版年
2023年 | 70篇 |
2022年 | 173篇 |
2021年 | 178篇 |
2020年 | 90篇 |
2019年 | 104篇 |
2018年 | 226篇 |
2017年 | 239篇 |
2016年 | 330篇 |
2015年 | 220篇 |
2014年 | 356篇 |
2013年 | 555篇 |
2012年 | 376篇 |
2011年 | 468篇 |
2010年 | 316篇 |
2009年 | 273篇 |
2008年 | 400篇 |
2007年 | 378篇 |
2006年 | 314篇 |
2005年 | 245篇 |
2004年 | 210篇 |
2003年 | 191篇 |
2002年 | 161篇 |
2001年 | 118篇 |
2000年 | 71篇 |
1999年 | 60篇 |
1998年 | 35篇 |
1997年 | 30篇 |
1996年 | 25篇 |
1995年 | 43篇 |
1994年 | 41篇 |
1993年 | 15篇 |
1992年 | 31篇 |
1991年 | 27篇 |
1990年 | 25篇 |
1989年 | 20篇 |
1988年 | 17篇 |
1987年 | 12篇 |
1986年 | 26篇 |
1985年 | 13篇 |
1984年 | 13篇 |
1983年 | 16篇 |
1982年 | 21篇 |
1981年 | 10篇 |
1980年 | 13篇 |
1966年 | 17篇 |
1965年 | 13篇 |
1964年 | 10篇 |
1958年 | 13篇 |
1957年 | 11篇 |
1956年 | 13篇 |
排序方式: 共有6827条查询结果,搜索用时 796 毫秒
551.
Pérez-de-Mora A Madejón P Burgos P Cabrera F Lepp NW Madejón E 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):3018-3027
We investigated the efficiency of various by-products (sugarbeet lime, biosolid compost and leonardite), based on single or repeated applications to field plots, on the establishment of a vegetation cover compatible with a stabilization strategy on a multi-element (As, Cd, Cu, Pb and Zn) contaminated soil 4-6 years after initial amendment applications. Results indicate that the need for re-treatment is amendment- and element-dependent; in some cases, a single application may reduce trace element concentrations in above-ground biomass and enhance the establishment of a healthy vegetation cover. Amendment performance as evaluated by % cover, biomass and number of colonizing taxa differs; however, changes in plant community composition are not necessarily amendment-specific. Although the translocation of trace elements to the plant biotic compartment is greater in re-vegetated areas, overall loss of trace elements due to soil erosion and plant uptake is usually smaller compared to that in bare soil. 相似文献
552.
Ruiz I Morales A Oliva J Barba A 《Journal of environmental science and health. Part. B》2011,46(6):530-534
An analytical procedure has been developed for the determination of natural pyrethrins (pyrethrin I, pyrethrin II, jasmolin I, jasmolin II, cinerin I and cinerin II) in lemon and apricot. The QuEChERS method, which stands for quick, easy, cheap, effective, rugged and safe was used for extraction. Analysis of the extract was performed by liquid-chromatography-electrospray ionisation-tandem mass spectrometry. The ions prominent in the ESI spectra were [M+H]+ for the six compounds. A Zorbax SB-C18 column was used with a programmed gradient mobile phase consisting of (A) water containing 0.1% formic acid and 5 mM ammonium formate and (B) ACN. The method was linear within the investigated concentration range, displaying a calibration curve correlation factor of 0.99. The coefficients of variation obtained (RSD) were below 20% and the recoveries were in the 70-110% range. 相似文献
553.
Morales A Ruiz I Oliva J Barba A 《Journal of environmental science and health. Part. B》2011,46(6):525-529
A method for the detection and quantification of 16 pesticides: flufenoxuron, fenoxycarb, dimethomorph, acetamiprid, imidacloprid, lufenuron, thiacloprid, thiabendazole, thiophanate-methyl, spinosad, fenbutatin oxide, methoxyfenozide, oxamyl, clothianidin, thiamethoxam and carbendazim has been developed based on high-performance liquid chromatography-mass spectrometry. Pesticide residues were extracted from the samples according to the QuEChERS method which stands for quick, essay, cheap, effective, rugged and safe. Homogenised analytical portions (10 g ± 0.1) of samples of peppers were spiked at two levels (10 and 100 μg kg?1) with a small volume of an appropriate standard mixture solution containing each pesticide. Analyses were performed using electrospray ionization (ESI) and a MSD trap system. Chromatography separation was achieved using a ZORBAX SB-C18 3.5 μm particle size analytical column, 2.1 × 50 mm from Agilent, with gradient elution at a flow-rate of 0.4 mL/min with mobile phases: waters-0.1 % HCOOH-5 mM HCOONH? and MeOH-5 mM HCOONH?. The method has been validated based on the SANCO European Guidelines. Under the optimized conditions the recoveries (n = 7) were in the range 70-110 % with satisfactory precision (CV ≤ 20 %). A linear dynamic range was obtained over a range of concentrations from 10 to 100 μg kg?1 for each of the analytes, with correlation coefficients >0.997. 相似文献
554.
Stefanie Grund Eric Higley René Schönenberger Marc J-F. Suter John P. Giesy Markus Hecker Henner Hollert 《Environmental science and pollution research international》2011,18(3):446-460
Introduction
The present study was part of a comprehensive weight-of-evidence approach with the goal of identifying potential causes for the declines in fish populations, which have been observed during the past decades in the Upper Danube River. 相似文献555.
Jofré MB Antón RI Caviedes-Vidal E 《Environmental science and pollution research international》2011,19(7):2889-2897
Purpose
Heavy metals have been detected in water and sediments from the Embalse La Florida, an artificial lake in the arid region of San Luis province, Argentina, representing one of the few sources of permanent water for reproduction of native anuran species. This study assesses lead (Pb) and cadmium (Cd) concentrations in the anuran species found in this water reservoir as well as differences between compounds, species and sites of collection.Methods
Adult anuran amphibians were collected on the north and south shores of the Embalse La Florida and Pb and Cd concentrations were measured in whole body homogenates digested using wet ashing techniques.Results
All individuals of the six species assayed had detectable levels of Pb and Cd that ranged from 1.19 to 5.57 ??g/g dry mass and from 1.09 to 6.86 ??g/g dry mass, respectively. Anuran amphibians collected in the more contaminated south shore accumulated 21% more Cd and 40% more Pb than individuals from the less altered north shore. Cd and Pb accumulation was not significantly correlated with the concentration in water at the site of collection.Conclusions
Amphibians of the Embalse La Florida accumulate Cd and Pb. Between and within species, differences were detected in Cd and Pb concentrations. Differences in metal concentrations between species, metals, and individuals collected on shores of the Embalse La Florida with different contamination, were detected. Therefore, it is crucial to implement adequate policies to protect amphibians from the accelerated urban development experienced in this location. 相似文献556.
Giloteaux L Solé A Esteve I Duran R 《Environmental science and pollution research international》2011,18(7):1147-1159
Introduction
A Microcoleus sp. consortium, obtained from the Ebro delta microbial mat, was maintained under different conditions including uncontaminated, lead-contaminated, and acidic conditions. 相似文献557.
Ventura-Lima J Ramos PB Fattorini D Regoli F Ferraz L de Carvalho LM Monserrat JM 《Environmental science and pollution research international》2011,18(8):1270-1278
Introduction
This study aimed to analyze antioxidant responses and oxidative damage induced by two inorganic forms of arsenic (As; AsIII and AsV) in an estuarine polychaete species, Laeonereis acuta (Nereididae). The capacity of arsenic biotransformation was also evaluated through the methylation process considering the activity of a key enzyme involved in the metabolization process. 相似文献558.
Spectrofluorimetric study of the ageing of mixtions used in the gildings of mediaeval wall paintings
Mounier A Belin C Daniel F 《Environmental science and pollution research international》2011,18(5):772-782
Introduction
In the Middle Ages, we could find gildings on mural paintings. Gold, silver or tin leaves were applied according to distemper or mixtion technique. For the first one, a binder as glue is necessary, and for the second, a lipidic binder is used to stick the metallic leaf. Studies of gildings materials characterization show that the mixtion technique, with a mordant, is the most common. Linseed oil seems to be the binder used. It is always mixed with a siccative agent as lead. Because of bad conditions of conservation, the gildings do not resist anymore, only remain traces of metal or the adhesive under-layer. Thanks to the binder fluorescence, we can nowadays detect ancient gildings. 相似文献559.
Column experiments were conducted to validate a screening model predicting the influence of pentachlorophenol (PCP) pole-treating oil on the vertical migration of its impurities, chlorinated dioxins and furans (PCDD/Fs). PCP pole-treating oil (15 mL d−1) and water (20 mL d−1) were added daily to the top of sand and organic soil columns during 35 d. Column soil samples were analyzed to determine concentrations of hydrocarbons and PCDD/Fs at several depths in the columns (0-30 cm) and their evolution in time (7, 14, 21 and 35 d).The model predicted a significant vertical migration of PCDD/Fs due to the presence of oil as a free phase and PCDD/Fs were found in the different column layers at concentrations consistent with model predictions (same order of magnitude). Measured PCDD/Fs concentrations are in total disagreement with literature data and with model prediction in the absence of oil free phase, which implies PCDD/F properties alone cannot be used to predict their fate in the current context: the influence of PCP pole-treating oil must be accounted for to properly explain their migration. 相似文献
560.
Kabiersch G Rajasärkkä J Ullrich R Tuomela M Hofrichter M Virta M Hatakka A Steffen K 《Chemosphere》2011,83(3):226-232
Bisphenol A is an endocrine disrupting compound, which is ubiquitous in the environment due to its wide use in plastic and resin production. Seven day old cultures of the litter-decomposing fungus Stropharia coronilla removed the estrogenic activity of bisphenol A (BPA) rapidly and enduringly. Treatment of BPA with purified neutral manganese peroxidase (MnP) from this fungus also resulted in 100% reduction of estrogenic activity, as analyzed using a bioluminescent yeast assay, and in the formation of polymeric compounds. In cultures of Stropharia rugosoannulata, estrogenic activity also quickly disappeared but temporarily re-emerged in the further course of cultivation. LC-MS analysis of the extracted estrogenic culture liquid revealed [M−H]− ions with m/z values of 219 and 235. We hypothesize that these compounds are ring fission products of BPA, which still exhibit one intact hydroxyphenyl group to interact with estrogen receptors displayed by the yeast. 相似文献