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211.
Jenkins TF Hewitt AD Grant CL Thiboutot S Ampleman G Walsh ME Ranney TA Ramsey CA Palazzo AJ Pennington JC 《Chemosphere》2006,63(8):1280-1290
Environmental investigations have been conducted at 23 military firing ranges in the United States and Canada. The specific training facilities most frequently evaluated were hand grenade, antitank rocket, and artillery ranges. Energetic compounds (explosives and propellants) were determined and linked to the type of munition used and the major mechanisms of deposition. 相似文献
212.
Guy D. Griffin Clay E. Easterly Isidor Sauers Harry W. Ellis Loucas G. Christophorou 《毒物与环境化学》2013,95(2):139-166
Sulfur hexafluoride decomposed by electrical sparks has been found to by cytotoxic to hamster cells when tested in an in vitro cell survival assay, while SF6 shows no cytotoxic activity. Chemical analysis of spark‐decomposed SF6 has identified and quantified the following compounds: SOF2, SO2F2, SF4, SOF4, SiF4, SO2 and HF. Each of these gases, at concentration ranges expected in spark‐decomposed SF6, were tested for cytotoxic activity toward hamster cells. Of the gases showing cytotoxic activity, SO2F2 and SOF4 were similar in activity, as were SOF2 and SF4, while the behavior of SiF4 was different from the rest. None of these individual gases, at concentrations expected in spark‐decomposed SF6, has sufficient cytotoxic activity to account for the cytotoxic effect of spark‐decomposed SF6 observed in our assay system. A four‐component mixture of some of the gases enumerated above (at concentrations overestimating their abundance in spark‐decomposed SF6) was much less cytotoxic than the spark‐decomposed SF6 gas. A mathematical simulation of the cytotoxic activity of a mixture of gases at concentrations found in spark‐decomposed SF6 was made, assuming independent cytotoxic effects from each component. The simulated cytotoxic effect thus computed was less than that seen in spark‐decomposed SF6. Since individual components or mixtures of the major decomposition products do not account for the observed biological activity of spark‐decomposed SF6, this suggests there may be one or more components, present in the spark‐decomposed gas at very low concentrations, which may have a very strong cytotoxic activity. 相似文献
213.
Chia Shun Shih Joseph K. Garner Guy L. Curry 《Journal of the American Water Resources Association》1974,10(1):101-118
ABSTRACT The reduction of the liability of pollution to urban water resources is considered as one of the common goals of all elements of our society. To approach the challenge with a sense of realism the probabilistic nature of the performance of pollution control facilities as well as environmental responses must not be ignored and cannot be eliminated. Reliability is defined herein as the measure of effectiveness for the attainment of water quality managerial goals. The objective of this paper is to develop an optimization model for the determination of the best pollution control policies for each treatment facility in terms of the minimization of total regional cost requirements, the quality control requirements, and the reliability desired. A chance-constrained quadratic programming technique coupled with parametric analysis is utilized as the basic solution approach. A practical problem based on the situation existing in the San Antonio River Basin Region of Texas was used for the illustration of this application. The implications resulting from the sensitivity analysis of this model will be discussed. 相似文献
214.
The authors demonstrate the difficulties inherent in predicting vegetation changes in floodplains affected by hydroelectric
developments. The results are based on phytoecological studies in the Rhone River valley between Geneva and Lyon. The study
is based in a 200-km stretch of river where the floodplain can attain 10 km in width. Vegetation is described for the area
prior to the construction of four dams and compared with the situations 8 yr later. Research methods include systematic sampling
of geomorphological, soils, and floristic factors; collection of a data base of spatial information; and large-scale vegetation
mapping. 相似文献
215.
Few studies have assessed the transport of dissolved nutrients at the field scale under natural rainfall conditions. Hysteresis between dissolved nutrients and discharge behavior can complicate such assessments and this effect has only been examined qualitatively. In this study, we investigated factors contributing to short-term variations of dissolved cation (Ca, Mg, Na, and K) and anion (soluble reactive phosphorus [SRP], NO3, and SO4) concentrations in runoff water and developed a quantitative method to study their hysteretic behavior. Within-storm variations of dissolved nutrient concentrations were determined in two agricultural fields during four natural rainfall events along with discharge, sediment, antecedent soil water conditions, and nutrient contents. For each event, nutrient loads were plotted against discharge during the rising and falling limb of the runoff hydrograph. The resulting hysteresis curves were characterized by an index H, which is the ratio between the integrated areas under the rising and falling curves of the hydrograph. Results showed that nutrient concentrations increased with time during each event. Counterclockwise (H < 1) hysteresis, occurring when the falling limb had larger loads, was found when soils were initially dry whereas clockwise hysteresis (H > 1) was associated with prior wet soil conditions. Two hypotheses are suggested to explain these variations. First, suspended sediments could have acted as a sink for dissolved nutrients and the sensitivity of nutrients to hydrological conditions was determined by their preferential sorption on these sediments. Second, movement of nutrients into runoff occurred more readily as soils became wetter during an event. 相似文献
216.
Jean-Sébastien?PierreEmail author Joan?van?Baaren Guy?Boivin 《Behavioral ecology and sociobiology》2003,54(2):147-155
Within the framework of optimal foraging theory, models assume that parasitoid insects are able to evaluate the quality of the patch in which they are currently searching for hosts and the travel time between patches. They can adjust their residence time in consequence. Simple and more realistic decision mechanisms that induce behavior compatible with the predictions of these models have been proposed for a number of species. Most of these decision mechanisms only take into account the presence of unparasitized hosts. Here, we studied the consequences for leaving patches containing different proportions of unparasitized and parasitized hosts. We support the hypothesis that parasitoids sample their environment and we propose a binomial sequential model, based on the type of host encountered (unparasitized or parasitized) instead of on the time spent in a patch, to explain the giving-up behavior of a parasitoid in a patch. A motivational incremental/decremental stochastic process is proposed to explain a possible mechanism of the apparent sampling scheme followed by the insect. The empirical data support the hypothesis of a sequential, decisional, binomial sampling scheme performed with a limited memory. This memory is, in fact, more an effect of habituation than the "true memory" of the parasitoid. The theoretical model was applied to real data obtained with an encyrtid parasitoid. These data were also compared to realizations of the incremental/decremental process. 相似文献
217.
Effects of Motorized Tourboats on the Behavior of Nonbreeding American Flamingos in Yucatan, Mexico 总被引:3,自引:0,他引:3
We assessed the effect of motorized tourboats on the behavior of nonbreeding American flamingos ( Phoenicopterus ruber ruber) in the Celestún Estuary, a Special Biosphere Reserve in Yucatán, Mexico, from November 1994 through February 1995. We measured these effects by comparing activity budgets between flocks of flamingos disturbed and undisturbed by tourboats. Disturbance reduced feeding time from 40% before disturbance to 24% after, a 40% loss. Boat disturbance increased alert behavior by 400%. Tourboats averaged 13 per day and caused a disturbance 75% of the time or 3.3 hours per day. Potential loss of feeding time for individuals was estimated at 13% but is likely much higher on days with excessive numbers of tourboats. Flamingos returned to normal feeding rates (40%) within 20 minutes after disturbance. Most tourists (52%) were from Mexico, followed by Germany (14%), and 88% of Mexican visitors were willing to pay an entrance fee to the Celestún Reserve. Conservation efforts should focus on education of tourboat operators to reduce disturbance to flamingos, education of tourists through a visitor's center and brochures produced in Spanish and English, and expanded involvement of local people. 相似文献
218.
Interactions of secondary amines with bentonite clay and humic materials in dilute aqueous systems 总被引:1,自引:0,他引:1
The speciation of dimethylamine, diethylamine, dibutylamine, and diethanolamine on bentonite clay saturated with 1) Na and Ca cations, 2) dodecyltrimethylammonium cation, and 3) tannic acid, and on humic acid and peat, has been studied. Adsorption isotherms were determined and the effect of ionic strength and pH on the adsorption were studied. The results show that the amines react with the particulates by ion exchange mechanisms. Hydrogen bonding seems to also contribute to the binding of dibutylamine. 相似文献
219.
Fabrizia Ratto Tom D. Breeze Lorna J. Cole Michael P. D. Garratt David Kleijn Bill Kunin Denis Michez Rory O'Connor Jeff Ollerton Robert J. Paxton Guy M. Poppy Simon G. Potts Deepa Senapathi Rosalind Shaw Lynn V. Dicks Kelvin S.-H. Peh 《Conservation biology》2022,36(4):e13886
Pollinator declines have prompted efforts to assess how land-use change affects insect pollinators and pollination services in agricultural landscapes. Yet many tools to measure insect pollination services require substantial landscape-scale data and technical expertise. In expert workshops, 3 straightforward methods (desk-based method, field survey, and empirical manipulation with exclusion experiments) for rapid insect pollination assessment at site scale were developed to provide an adaptable framework that is accessible to nonspecialist with limited resources. These methods were designed for TESSA (Toolkit for Ecosystem Service Site-Based Assessment) and allow comparative assessment of pollination services at a site of conservation interest and in its most plausible alternative state (e.g., converted to agricultural land). We applied the methods at a nature reserve in the United Kingdom to estimate the value of insect pollination services provided by the reserve. The economic value of pollination services provided by the reserve ranged from US$6163 to US$11,546/year. The conversion of the reserve to arable land would provide no insect pollination services and a net annual benefit from insect-pollinated crop production of approximately $1542/year (US$24∙ha–1∙year–1). The methods had wide applicability and were readily adapted to different insect-pollinated crops: rape (Brassica napus) and beans (Vicia faba) crops. All methods were rapidly employed under a low budget. The relatively less robust methods that required fewer resources yielded higher estimates of annual insect pollination benefit. 相似文献
220.
Tchoffo Rodrigue Ngassa Guy B. P. Doungmo Giscard Kamdem Arnaud T. Tonlé Ignas K. Ngameni Emmanuel 《Environmental science and pollution research international》2022,29(1):222-235
Environmental Science and Pollution Research - A composite material prepared by polymerization of β-cyclodextrin (β-CD) on the surface of natural hydroxyapatite using citric acid as cross... 相似文献