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11.
Eiki Watanabe Shiro Miyake 《Journal of environmental science and health. Part. B》2013,48(11):707-712
ABSTRACTEasy-to-use commercial kit-based enzyme-linked immunosorbent assays (ELISAs) have been used to detect neonicotinoid dinotefuran, clothianidin and imidacloprid in Chinese chives, which are considered a troublesome matrix for chromatographic techniques. Based on their high water solubility, water was used as an extractant. Matrix interference could be avoided substantially just diluting sample extracts. Average recoveries of insecticides from spiked samples were 85–113%, with relative standard deviation of <15%. The concentrations of insecticides detected from the spiked samples with the proposed ELISA methods correlated well with those by the reference high-performance liquid chromatography (HPLC) method. The residues analyzed by the ELISA methods were consistently 1.24 times that found by the HPLC method, attributable to loss of analyte during sample clean-up for HPLC analyses. It was revealed that the ELISA methods can be applied easily to pesticide residue analysis in troublesome matrix such as Chinese chives. 相似文献
12.
Ikemoto T Tu NP Watanabe MX Okuda N Omori K Tanabe S Tuyen BC Takeuchi I 《Chemosphere》2008,72(1):104-114
The present study elucidated the biomagnification profiles of persistent organic pollutants (POPs) through a tropical aquatic food web of Vietnam based on trophic characterization using stable nitrogen analysis. Various biological samples collected from the main stream of the Mekong Delta were provided for the analysis for both POPs, and stable nitrogen and carbon isotope ratios. Of the POPs analyzed, dichlorodiphenyltrichloroethane and its metabolites (DDTs) were the predominant contaminants with concentrations ranging from 0.058 to 12 ng/g wet weight, followed by polychlorinated biphenyls (PCBs) at 0.017-8.9 ng/g, chlordane compounds (CHLs) at 0.0043-0.76 ng/g, tris-4-chlorophenyl methane (TCPMe) at N.D.-0.26 ng/g, hexachlorocyclohexane isomers (HCHs) at N.D.-0.20 ng/g and hexachlorobenzene (HCB) at 0.0021-0.096 ng/g. Significant positive increases of concentrations in DDTs, CHLs, and TCPMe against the stable nitrogen ratio (delta(15)N) were detected, while, concentrations of HCHs and HCB showed no significant increase. The slopes of the regression equations between the log-transformed concentrations of these POPs and delta(15)N were used as indices of biomagnification. The slopes of the POPs for which positive biomagnification was detected ranged from 0.149 to 0.177 on a wet weight basis. The slopes of DDTs and CHLs were less than those reported for a marine food web of the Arctic Ocean, indicating that less biomagnification had occurred in the tropical food web. Of the isomers of CHLs, unlike the studies of the Arctic Ocean, oxychlordane did not undergo significant biomagnification through the food web of the Mekong Delta. This difference is considered to be due to a lack of marine mammals, which might metabolize cis- and trans-chlordane to oxychlordane, in the Mekong Delta ecosystem. The biomagnification profile of TCPMe is reported for the first time in the present study. 相似文献
13.
Takeshi Sasaki Atsushi Iizuka Masayuki Watanabe Teruhisa Hongo Akihiro Yamasaki 《Waste management (New York, N.Y.)》2014,34(10):1829-1835
Solid adsorbent materials, prepared from waste cement powder and concrete sludge were assessed for removal of arsenic in the form of arsenic (As(V)) from water. All the materials exhibited arsenic removal capacity when added to distilled water containing 10–700 mg/L arsenic. The arsenic removal isotherms were expressed by the Langmuir type equations, and the highest removal capacity was observed for the adsorbent prepared from concrete sludge with heat treatment at 105 °C, the maximum removal capacity being 175 mg-As(V)/g. Based on changes in arsenic and calcium ion concentrations, and solution pH, the removal mechanism for arsenic was considered to involve the precipitation of calcium arsenate, Ca3(AsO4)2. The enhanced removal of arsenic for the adsorbent prepared from concrete sludge with heat treatment was thought to reflect ion exchange by ettringite. The prepared adsorbents, derived from waste cement and concrete using simple procedures, may offer a cost effective approach for arsenic removal and clean-up of contaminated waters, especially in developing countries. 相似文献
14.
15.
Hajime Yasuda Tohru Kamo Mariko Adachi Satoshi Sajima Hideki Nakagome 《Journal of Material Cycles and Waste Management》2010,12(2):123-127
The rapid hydropyrolysis of model compounds for epoxy resin oligomers and biomass tar was carried out in a hydrogen atmosphere
at 1073 K and 973 K. The assumed oligomers were partially pyrolyzed epoxy resin with biomass tar as solvent for the resin.
The product distributions obtained from rapid hydropyrolysis of phenol and bisphenol-A are shown. We also discuss the effects
of reaction temperature and hydrogen partial pressure on the product yield. In particular, more phenol was produced from bisphenol-A
at 973 K than at 1073 K. The yield of methane, which was the final hydropyrolysis product, increased with increasing hydrogen
partial pressure, whereas benzene and phenol were believed to behave as intermediate products in the hydropyrolysis reaction.
The results suggest that phenol could be obtained with high selectivity from tar by optimizing the reaction conditions. 相似文献
16.
In this study, we analyzed the sustainability and determinant factors of waste reduction through variable charging schemes.
We drew three main conclusions from the study. (1) Waste reduction was achieved by variable charging and was sustained over
an average of at least 10 years. The results regarding the sustainability of the price effect were inconclusive. (2) The main
factors contributing to the combustible waste reduction achieved through variable charging were two-tier pricing and the price
of waste bags. The effect of two-tier pricing programs was positive. (3) Waste paper recycling and variable charging reinforce
each other to promote waste reduction.
Received: September 3, 2001 / Accepted: January 13, 2002 相似文献
17.
Nobuhisa Watanabe Saburo Inoue Hisao Ito 《Journal of Material Cycles and Waste Management》1999,1(1):38-47
The arsenic and antimony balance in two municipal waste incinerators was investigated. Initially, the production rates of
ash and wet scrubber effluent were estimated. Then the arsenic and antimony in the ash and wet scrubber effluent were determined,
which gave an estimate of the elemental balance. The total amounts of arsenic and antimony in the municipal waste were 0.9 g/t
and 30–44 g/t, respectively. The distributions to fly ash were 45–47% and 33–74% for arsenic and antimony, respectively. The
distribution mechanisms of arsenic and antimony are discussed from the viewpoints of their thermodynamics as well as their
initial valencies, which greatly affect their behaviour.
Received: July 2, 1998 / Accepted: February 27, 1999 相似文献
18.
The influence of ice-nucleating active (INA) bacteria on cold hardiness of the house spider, Achaearanea tepidariorum, was determined by measuring the supercooling point (SCP) of hatchlings given either INA-bacteria-fed or bacteria-free prey (Drosophila melanogaster). Spiders that had eaten INA-bacteria-fed flies showed higher SCPs than those fed on bacteria-free flies. Through feeding, INA bacteria in the prey reduce the cold hardiness of spiders. This fact should be taken into account before using INA agents as a means of pest management. 相似文献
19.
A badge-type personal sampler was developed for measuring personal exposure to nitrogen dioxide (NO2). An absorbent sheet containing triethanolamine (TEA) solution absorbed NO2 which diffused through five layers of hydrophobic fiber filter. Wind effects on absorption rate were suppressed by these filter layers. NO2 was measured by the sampler with a sensitivity of 124.8 μg h/m3 (66 ppb h) and an accuracy of within ± 20%. It could be used for measuring personal exposure to NO2 without interfering with the wearer's daily activities. Nitric oxide (NO) could be measured after a small modification to the sampler provided oxidation ability to the layers of diffusion filter. Three layers of hydrophobic fiber filter were replaced by 12 layers of glass fiber filter containing chromium trioxide solution. NO was oxidized to NO2 in the oxidation layers and absorbed by the absorbent sheet together with the coexisting NO2. Sensitivity and accuracy of the sampler for NO were nearly equal to that for NO2. 相似文献
20.
This paper contains detailed data on atmospheric emissions from power plants with a capacity of more than 25 MW electric in the United States. The data are gathered from utility files as presented to the U.S. Environmental Protection Agency. Pollutants covered are CO, NOx, SOx3, particulates, and total hydrocarbons. The data indicate that in 1977 about 420×109 kg coal, 84×106 m3 oil, and 65×106 m3 of natural gas were used to generate electricity. Pollutants generated were 2×109kg particulates, 17×109 kg SO2, 6×109 kg NOx, 78×106 kg hydrocarbons and 0.3×106 kg of CO. 相似文献