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81.
Removal kinetics of phosphorus through use of basic oxygen furnace slag(BOF-slag)was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial p H, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant(kobs) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial p H, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage.A linear dependence of kobson total removed phosphorus(TRP) was established with kobs=(3.51 ± 0.11) × 10- 4× TRP. Finally, it was suggested that the Langmuir–Rideal(L–R)or Langmuir–Hinshelwood(L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag. 相似文献
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Zhaoxing Han Zhenyao Shen Yongwei Gong Qian Hong 《Frontiers of Environmental Science & Engineering in China》2011,5(1):119-129
Emission trading is one of the most effective alternatives to controlling water pollution. Water environmental functional
zone (WEFZ) is used to determine the water quality standard and identify the zone boundary for each river or reach. In this
study, a new emission trading scheme was addressed based on WEFZ, accounting for both the temporal dimension and water quality
control. A temporal factor of emission trading was proposed based on variations in the environmental capacity within a year
by dividing the year into three periods, including high, normal, and low periods of environmental capacity. During each period,
emission trading was implemented exclusively. A water quality-control scheme was suggested based on the water quality requirement
in the water functional zone, in which the water quality at the downstream boundary of the zone was required to meet the water
standard following auto-purification in the stream. Two methods of calculating water quality control are addressed for point-source
pollution and non-point-source pollution. The calculated temporal dimension and water quality control were located in Dongxi
River of the Daning Watershed in the Three Gorges Watershed. The high period was during June, July, and August, the normal
period was during April, May, September, and October, and the low period was during January, February, March, November, and
December. The results from the water quality calculation demonstrated that the discharge of point-source and non-point-source
pollutions led to an excess of common contaminants at the downstream boundary of WEFZ. The temporal and spatial factors above
should be incorporated into the emission trading scheme based on WEFZ. 相似文献
86.
Cribb BW Stewart A Huang H Truss R Noller B Rasch R Zalucki MP 《Die Naturwissenschaften》2008,95(5):433-441
Previously, the presence of metals in arthropod mandibles has been linked with harder cuticle, and in termites, a 20% increase in hardness has been found for mandibles containing major quantities of zinc. The current study utilises electron microscopy and energy-dispersive X-ray microanalysis to assess incidence and abundance of metals in all extant subfamilies of the Isoptera. The basal clades contain no zinc and little to no manganese in the cutting edge of the mandible cuticle, suggesting that these states are ancestral for termites. However, experimentation with mandibles in vitro indicates the presence of some elements of the cuticular biochemistry necessary to enable uptake of zinc. The Termopsidae, Serritermitidae, Rhinotermitidae and Termitidae all contain minor quantities of manganese, while trace to minor quantities of zinc occur in all except the Serritermitidae. In contrast, all Kalotermitidae or drywood termites contain major levels of zinc in the mandible edge. Diet and life type are explored as links to metal profiles across the termites. The presence of harder mandibles in the drywood termites may be related to lack of access to free water with which to moisten wood. Scratch tests were applied to a set of mandibles. The coefficient of friction for Cryptotermes primus (Kalotermitidae) mandibles, when compared with species from other subfamilies, indicates that zinc-containing mandibles are likely to be more scratch resistant. 相似文献
87.
NaOH溶液对有机相苯酚反萃取的研究 总被引:8,自引:0,他引:8
本文系统进行了NaOH溶液对负载苯酚的TBP+煤油溶剂的反萃取平衡实验。考虑苯酚的支萃取平衡和解离平衡,建立了反萃取的计算模式,并证明了模型的可行性。本文还讨论了NaOH溶液浓度,油水相比,萃取平衡分配系数,溶剂中的负载苯酚浓度和NaOH溶液中初始酚含量对反萃取率的影响。 相似文献
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Xie Qiaoling Wang Dandan Han Zhichao Tao Huchun Liu Sitong 《Journal of Material Cycles and Waste Management》2023,25(1):62-73
Journal of Material Cycles and Waste Management - A ball milling pretreatment with additives for fly ash and the combined use of reagents as flotation collectors in fly ash flotation were... 相似文献
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