Enhanced catalytic complete oxidation of 1,2-dichloroethane over mesoporous transition metal-doped γ-Al2O3

High-surface-area mesoprous powders of γ-Al₂O₃ doped with Cu²⁺, Cr³⁺, and V³⁺ ions were prepared via a modified sol-gel method and were investigated as catalysts for the oxidation of chlorinated organic compounds. The composites retained high surface areas and pore volumes comparable with those of undoped γ-Al₂O₃ and the presence of the transition metal ions enhanced their surface acidic properties. The catalytic activity of the prepared catalysts in the oxidation of 1,2-dichloroethane (DCE) was studied in the temperature range of 250-400℃. The catalytic activity and product selectivity were strongly dependent on the presence and the type of dopant ion. While Cu²⁺- and Cr³⁺-containing catalysts showed 100% conversion at 300℃ and 350℃, V³⁺-containing catalyst showed considerably lower conversion. Furthermore, while the major products of the reactions over γ-alumina were vinyl chloride (C₂H₃Cl) and hydrogen chloride (HCl) at all temperatures, Cu- and Cr-doped catalysts showed significantly stronger capability for deep oxidation to CO₂.     

Synthesis of magnetite-based nanocomposites for effective removal of brilliant green dye from wastewater

Environmental Science and Pollution Research - The present study aims at evaluating the batch scale potential of cotton shell powder (CSP), Moringa oleifera leaves (ML), and magnetite-assisted...     

A Stage-Structured Pest-Natural Enemy Dynamics with Holling Type-II Interaction and Maturation Delay for Pest Species

In this paper, a pest-natural enemy dynamics with maturation delay for pest species is proposed. Here, pest is categorized into two stages, namely immature and mature and the natural enemy only harvest mature pest population with Holling type-II interaction. The boundedness and positivity of the solution of the system are presented. The asymptotic behavior of the system is studied and analyzed for all feasible equilibrium points. Sensitivity analysis of the system at interior equilibrium point for the system parameters is performed, and respective sensitive indices of the variables are identified. Finally, numerical simulations are presented to support our analytic results.

     

Ecotoxicological assessment of oil-based paint using three-dimensional multi-species bio-testing model: pre- and post-bioremediation analysis

The present study validates the oil-based paint bioremediation potential of Bacillus subtilis NAP1 for ecotoxicological assessment using a three-dimensional multi-species bio-testing model. The model included bioassays to determine phytotoxic effect, cytotoxic effect, and antimicrobial effect of oil-based paint. Additionally, the antioxidant activity of pre- and post-bioremediation samples was also detected to confirm its detoxification. Although, the pre-bioremediation samples of oil-based paint displayed significant toxicity against all the life forms. However, post-bioremediation, the cytotoxic effect against Artemia salina revealed substantial detoxification of oil-based paint with LD₅₀ of 121 μl ml^?1 (without glucose) and >?400 μl ml^?1 (with glucose). Similarly, the reduction in toxicity against Raphanus raphanistrum seeds germination (%FG?=?98 to 100%) was also evident of successful detoxification under experimental conditions. Moreover, the toxicity against test bacterial strains and fungal strains was completely removed after bioremediation. In addition, the post-bioremediation samples showed reduced antioxidant activities (% scavenging?=?23.5?±?0.35 and 28.9?±?2.7) without and with glucose, respectively. Convincingly, the present multi-species bio-testing model in addition to antioxidant studies could be suggested as a validation tool for bioremediation experiments, especially for middle and low-income countries.

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Impact of storm water on groundwater quality below retention/detention basins

Groundwater from 33 monitoring of peripheral wells of Karachi, Pakistan were evaluated in terms of pre- and post-monsoon seasons to find out the impact of storm water infiltration, as storm water infiltration by retention basin receives urban runoff water from the nearby areas. This may increase the risk of groundwater contamination for heavy metals, where the soil is sandy and water table is shallow. Concentration of dissolved oxygen is significantly low in groundwater beneath detention basin during pre-monsoon season, which effected the concentration of zinc and iron. The models of trace metals shown in basin groundwater reflect the land use served by the basins, while it differed from background concentration as storm water releases high concentration of certain trace metals such as copper and cadmium. Recharge by storm water infiltration decreases the concentration and detection frequency of iron, lead, and zinc in background groundwater; however, the study does not point a considerable risk for groundwater contamination due to storm water infiltration.     

Investigating motivating factors for sound hospital waste management

Sustainable management of hospital waste requires an active involvement of all key players. This study aims to test the hypothesis that three motivating factors, namely, Reputation, Liability, and Expense, influence hospital waste management. The survey for this study was conducted in two phases, with the pilot study used for exploratory factor analysis and the subsequent main survey used for cross-validation using confirmatory factor analysis. The hypotheses were validated through one-sample t tests. Correlations were established between the three motivating factors and organizational characteristics of hospital type, location, category, and size. The hypotheses were validated, and it was found that the factors of Liability and Expense varied considerably with respect to location and size of a hospital. The factor of Reputation, however, did not exhibit significant variation. In conclusion, concerns about the reputation of a facility and an apprehension of liability act as incentives for sound hospital waste management, whereas concerns about financial costs and perceived overburden on staff act as disincentives.

Implications: This paper identifies the non economic motivating factors that can be used to encourage behavioral changes regarding waste management at hospitals in resource constrained environments. This study discovered that organizational characteristics such as hospital size and location cause the responses to vary among the subjects. Hence a policy maker must take into account the institutional setting before introducing a change geared towards better waste management outcomes across hospitals. This study covers a topic that has hitherto been neglected in resource constrained countries. Thus it can be used as one of the first steps to highlight and tackle the issue.     

Economic potential of recycling business in Lahore, Pakistan

The state of household waste recycling in Lahore city, Pakistan with a population of 7.2 million was analyzed. Data on solid waste recycling were gathered from residents of low-, middle- and high-income groups, as well as from scavengers and junkshops. The recycling activities in Lahore exert a significant impact on resource conservation, creation of jobs, provision of economic opportunity and reduction in the magnitude of waste disposal problems. A cost analysis is presented to show the income that can be generated through a well-planned recycling program. It is shown that 21.2% of all recyclable waste in Lahore is recycled, and it generates an amount of Rs. 271 million (US dollars 4.5 million) per year through the informal sector. However, if the recycling practice is owned by the formal sector, it can save an amount of Rs. 65 million by reducing the collection cost. If recycling is adopted as an industry, it can generate revenues of Rs. 530 million (US dollars 8.8 million) per year and can also save enormous amount of energy, as well as the natural resources.     

Spatial distribution of drinking and irrigation water quality indices of Ghizer River Basin,northern Pakistan

Environmental Science and Pollution Research - Determining the water contamination of a river that threatens the dependent ecological community is a pillar for sustainable management. For this...     

Barbecued desi chicken: an investigation on the impact of polluted milieu upon formation and ingestion of polycyclic aromatic hydrocarbons (PAHs) in commercial versus laboratory barbecued organs along with stochastic cancer risk assessments in people from an industrial district of Punjab,Pakistan

Environmental Science and Pollution Research - 8∑PAHs in 2- and 4-month-old desi chicken organs collected from Faisalabad district, Punjab, Pakistan, were examined via high-performance liquid...     

Effects of anthropogenic nitrogen deposition on soil nitrogen mineralization and immobilization in grassland soil under semiarid climatic conditions

Earlier studies by the authors on English soils under grassland strongly supported their hypothesis that soil/plant systems have naturally evolved to conserve nitrogen (N) by having a close match between the dynamics of mineral-N production in soils and the dynamics of plant N requirements. Thus, maximum mineral-N production in soils occurred in spring when plant N requirements were greatest and were very low in mid to late summer. Low temperature and a high C:N ratio of senescing material helped to conserve N in winter, but mobile N was associated with pollution inputs. We test the hypothesis that under the much more arid conditions of Pakistan, soil/plant systems naturally have evolved to conserve mineral-N, especially over the very dry and cooler months between October and February. When soils from a grassland site were incubated at ambient temperatures after removal of plant roots and exclusion of atmospheric N inputs, there was consistent evidence of immobilization of nitrate and immobilization and possibly volatilization of ammonia/ammonium. In the wetter months of July and August, the soil at 0–10 cm depth showed no evidence of significant ammonium-N production in July and only small ammonium production at 10–20 cm depth in August, but was associated with significant nitrate-N immobilization in August. Nitrate leaching only appeared likely towards the end of the rainy season in September. The results strongly suggest that, under grass, the retention of atmospheric N inputs over the long dry periods is regulating the pools of available N in the soils, rather than the N produced by mineralization of soil organic matter.