全文获取类型
收费全文 | 1258篇 |
免费 | 8篇 |
国内免费 | 28篇 |
专业分类
安全科学 | 14篇 |
废物处理 | 61篇 |
环保管理 | 150篇 |
综合类 | 105篇 |
基础理论 | 213篇 |
污染及防治 | 446篇 |
评价与监测 | 229篇 |
社会与环境 | 74篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 36篇 |
2022年 | 80篇 |
2021年 | 70篇 |
2020年 | 12篇 |
2019年 | 26篇 |
2018年 | 46篇 |
2017年 | 37篇 |
2016年 | 57篇 |
2015年 | 30篇 |
2014年 | 54篇 |
2013年 | 157篇 |
2012年 | 66篇 |
2011年 | 70篇 |
2010年 | 54篇 |
2009年 | 51篇 |
2008年 | 68篇 |
2007年 | 46篇 |
2006年 | 49篇 |
2005年 | 38篇 |
2004年 | 34篇 |
2003年 | 30篇 |
2002年 | 21篇 |
2001年 | 20篇 |
2000年 | 10篇 |
1999年 | 10篇 |
1998年 | 4篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 8篇 |
1986年 | 4篇 |
1984年 | 2篇 |
1982年 | 5篇 |
1980年 | 2篇 |
1978年 | 4篇 |
1976年 | 6篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1972年 | 3篇 |
1969年 | 6篇 |
1968年 | 4篇 |
1965年 | 2篇 |
1959年 | 2篇 |
1957年 | 3篇 |
1956年 | 3篇 |
排序方式: 共有1294条查询结果,搜索用时 62 毫秒
51.
Monu Jariyal V. K. Gupta Kousik Mandal Vikas Jindal Geetika Banta Balwinder Singh 《Environmental science and pollution research international》2014,21(3):2214-2222
Based upon 16S rDNA sequence homology, 15 phorate-degrading bacteria isolated from sugarcane field soils by selective enrichment were identified to be different species of Bacillus, Pseudomonas, Brevibacterium, and Staphylococcus. Relative phorate degradation in a mineral salt medium containing phorate (50 μg ml?1) as sole carbon source established that all the bacterial species could actively degrade more than 97 % phorate during 21 days. Three of these species viz. Bacillus aerophilus strain IMBL 4.1, Brevibacterium frigoritolerans strain IMBL 2.1, and Pseudomonas fulva strain IMBL 5.1 were found to be most active phorate metabolizers, degrading more than 96 % phorate during 2 days and 100 % phorate during 13 days. Qualitative analysis of phorate residues by gas liquid chromatography revealed complete metabolization of phorate without detectable accumulation of any known phorate metabolites. Phorate degradation by these bacterial species did not follow the first-order kinetics except the P. fulva strain IMBL 5.1 with half-life period (t½) ranging between 0.40 and 5.47 days. 相似文献
52.
Hanwant Bir Singh L. J. Salas L. A. Cavanagh 《Journal of the Air & Waste Management Association (1995)》2013,63(4):332-336
Based on two comprehensive field studies conducted in California, background concentration (parts per trillion) of N2O (296.0 X 103), SF6 (0.16), CCI2F2 (180.8), CCI3F (103.8), CCI2FCCIF2 (16.3), CCI4 (114.2), CH3CI (952.9), CHCI3 (23.4), CH3I (2.4), CH3CCI3 (84.0), CCI2CCI2 (43.1), CHCICCI2 (14.5) and CH3Br (—) have been reported. These trace constituents were identified using retention data on eight GC columns, their electron attachment properties, and their EC thermal response. All but CHCICCI2 and CH3Br were measurable 100% of the time at both sites. Cryogenic procedures for SF6 ambient measurement were developed and successfully used. By an analysis of worldwide emissions of these trace constituents, their ambient levels, and their atmospheric lifetimes, it was possible to determine their origin (natural or anthropogenic). Our results indicate that 27% of organic chlorine contribution to the troposphere comes from fluorocarbons as opposed to a 73% contribution from the chloro-carbons. Further, the anthropogenic organic content in the troposphere was found to be about twice the natural content. Very high CHCI3 concentrations in onshore ocean waters were measured. Ambient data supporting the anthropogenic origin of CCI4 have been presented. 相似文献
53.
Walter F. Dabberdt Hanwant B. Singh 《Journal of the Air & Waste Management Association (1995)》2013,63(9):876-881
Emergency plans for oxidant controls provide the basis for taking preventive action to protect public health. Historic oxidant data (1970 to Sept. 1974) from the South Coast Air Basin (SCAB), were evaluated to assess episode characteristics in an area where emergency strategies are most likely to be enforced. These findings, together with an objective study of a test case episode (June 1974) using a photochemical air quality simulation model, suggest that the currently conceived emergency plans for oxidant control are unlikely to be effective. It is concluded that, because of the chemical and mefeorofogfcal complexities of the episodes, they are extremely difficult both to predict and concurrently to control over their short-lived duration. 相似文献
54.
Loha KM Shakil NA Kumar J Singh MK Adak T Jain S 《Journal of environmental science and health. Part. B》2011,46(3):201-206
Controlled release formulations of β-cyfluthrin, a non-systemic, broad spectrum contact insecticide, have been prepared using laboratory synthesized poly(ethylene glycol) (PEG) based amphiphilic copolymers. Copolymers of polyethylene glycols of different molecular weights and various dimethyl esters, viz. dimethyl isophthalate, which self assemble into nano micellar aggregates in aqueous media, have been synthesized. The kinetics of β-cyfluthrin from developed controlled release (CR) formulations were studied in comparison with that of the commercially available 025 SC. Release from the commercial formulation was faster than with the developed CR formulations. The rate of release of encapsulated β-cyfluthrin from nano micellar aggregates is reduced by increasing the molecular weight of PEG. The diffusion exponent (n value) of β-cyfluthrin in water ranged from 0.427 to 0.622 in the tested formulations. The release was diffusion controlled with a half-release time (t(?)) of 3.92 to 7.9 days in water from different formulations, and the period of optimum availability (POA) of β-cyfluthrin ranged from 1.4 to 20.5 days. The results suggest that the application rate of β-cyfluthrin can be optimized to achieve insect control at the desired level and period. 相似文献
55.
Evaluation of hexachlorocyclohexane contamination from the last lindane production plant operating in India 总被引:3,自引:3,他引:0
Jit S Dadhwal M Kumari H Jindal S Kaur J Lata P Niharika N Lal D Garg N Gupta SK Sharma P Bala K Singh A Vijgen J Weber R Lal R 《Environmental science and pollution research international》2011,18(4):586-597
Purpose
??-Hexachlorocyclohexane (HCH), ??-HCH, and lindane (??-HCH) were listed as persistent organic pollutants by the Stockholm Convention in 2009 and hence must be phased out and their wastes/stockpiles eliminated. At the last operating lindane manufacturing unit, we conducted a preliminary evaluation of HCH contamination levels in soil and water samples collected around the production area and the vicinity of a major dumpsite to inform the design of processes for an appropriate implementation of the Convention.Methods
Soil and water samples on and around the production site and a major waste dumpsite were measured for HCH levels.Results
All soil samples taken at the lindane production facility and dumpsite and in their vicinity were contaminated with an isomer pattern characteristic of HCH production waste. At the dumpsite surface samples contained up to 450?g?kg?1 ?? HCH suggesting that the waste HCH isomers were simply dumped at this location. Ground water in the vicinity and river water was found to be contaminated with 0.2 to 0.4?mg?l?1 of HCH waste isomers. The total quantity of deposited HCH wastes from the lindane production unit was estimated at between 36,000 and 54,000?t.Conclusions
The contamination levels in ground and river water suggest significant run-off from the dumped HCH wastes and contamination of drinking water resources. The extent of dumping urgently needs to be assessed regarding the risks to human and ecosystem health. A plan for securing the waste isomers needs to be developed and implemented together with a plan for their final elimination. As part of the assessment, any polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/PCDF) generated during HCH recycling operations need to be monitored. 相似文献56.
Vijgen J Abhilash PC Li YF Lal R Forter M Torres J Singh N Yunus M Tian C Schäffer A Weber R 《Environmental science and pollution research international》2011,18(2):152-162
Purpose
Hexachlorocyclohexane (HCH) isomers (??-, ??- and ??- (Lindane)) were recently included as new persistent organic pollutants (POPs) in the Stockholm Convention, and therefore, the legacy of HCH and Lindane production became a contemporary topic of global relevance. This article wants to briefly summarise the outcomes of the Stockholm Convention process and make an estimation of the amount of HCH waste generated and dumped in the former Lindane/HCH-producing countries.Results
In a preliminary assessment, the countries and the respective amount of HCH residues stored and deposited from Lindane production are estimated. Between 4 and 7 million tonnes of wastes of toxic, persistent and bioaccumulative residues (largely consisting of alpha- (approx. 80%) and beta-HCH) are estimated to have been produced and discarded around the globe during 60 years of Lindane production. For approximately 1.9 million tonnes, information is available regarding deposition. Countries are: Austria, Brazil, China, Czech Republic, France, Germany, Hungary, India, Italy, Japan, Macedonia, Nigeria, Poland, Romania, Slovakia, South Africa, Spain, Switzerland, Turkey, The Netherlands, UK, USA, and former USSR. The paper highlights the environmental relevance of deposited HCH wastes and the related POPs?? contaminated sites and provides suggestions for further steps to address the challenge of the legacy of HCH/Lindane production.Conclusion
It can be expected that most locations where HCH waste was discarded/stockpiled are not secured and that critical environmental impacts are resulting from leaching and volatilisation. As parties to the Stockholm Convention are legally required to take action to stop further POPs pollution, identification and evaluation of such sites are necessary. 相似文献57.
This study presents the first systematic information on the degradation patterns of clandestine drug laboratory chemicals in soil. The persistence of five compounds - parent drugs (methamphetamine, 3,4-methylenedioxymethamphetamine (MDMA)), precursor (pseudoephedrine), and synthetic by-products N-formylmethylamphetamine and 1-benzyl-3-methylnaphthalene) - were investigated in laboratory scale for 1 year in three different South Australian soils both under non-sterile and sterile conditions. The results of the degradation study indicated that 1-benzyl-3-methylnaphthalene and methamphetamine persist for a long time in soil compared to MDMA and pseudoephedrine; N-formylmethylamphetamine exhibits intermediate persistence. The role of biotic versus abiotic soil processes on the degradation of target compounds was also varied significantly for different soils as well as with the progress in incubation period. The degradation of methamphetamine and 1-benzyl-3-methylnaphthalene can be considered as predominantly biotic as no measureable changes in concentrations were recorded in the sterile soils within a 1 year period. The results of the present work will help forensic and environmental scientists to precisely determine the environmental impact of chemicals associated with clandestine drug manufacturing laboratories. 相似文献
58.
The purpose of this paper was to examine trade-offs between elimination and detoxification in rainbow trout and three common bivalve molluscs (clam, oyster, and scallop) exposed to cadmium (Cd), copper (Cu), and zinc (Zn) based on recent reported experimental data. We incorporated metal influx threshold with subcellular partitioning to estimate rate constants of detoxification (kd) and elimination (k2). We found that the relationships between k2 and kd were negative for rainbow trout and positive for bivalve molluscs. However, the relationships between kd and % metal in metabolically detoxified pool were found positive for rainbow trout and negative for bivalve molluscs. Our results also indicated that rainbow trout had higher accumulation (∼60-90%) in metabolically active pool when exposed to essential metals of Cu and Zn and had only 10-50% accumulation in response to non-essential metal of Cd. Based on a cluster analysis, this study indicated that similarity of physiological regulations among study species was found between Cd and Zn. Our study suggested that detoxification can be predicted by an elimination-detoxification scheme with the known elimination rate constant. We concluded that quantification of trade-offs between subcellular partitioning and detoxification provides valuable insights into the ecotoxicology of aquatic organisms and enhances our understanding of the subcellular biology of trace metals. 相似文献
59.
Bajwa Ali Ahsan Zulfiqar Usman Sadia Sehrish Bhowmik Prasanta Chauhan Bhagirath Singh 《Environmental science and pollution research international》2019,26(6):5357-5371
Environmental Science and Pollution Research - Chenopodium album and C. murale are cosmopolitan, annual weed species of notable economic importance. Their unique biological features, including high... 相似文献
60.
Nimisha Singh 《Environmental pollution (Barking, Essex : 1987)》2009,157(2):371-376
Leaching of Cu and Zn from a composite of spent antifouling paint particles, containing about 300 mg g−1 and 110 mg g−1 of the respective metals, was studied in batch experiments. For a given set of simulated environmental conditions, release of Cu was independent of paint particle concentration due to attainment of pseudo-saturation, but Zn was less constrained by solubility effects and release increased with increasing particle concentration. Leaching of Cu increased but Zn decreased with increasing salinity, consistent with mechanisms governing the dissolution of Cu2O in the presence of chloride and Zn acrylates in the presence of seawater cations. Because of complex reaction kinetics and the presence of calcium carbonate in the paint matrix, metal leaching appeared to be greater at 4 °C than 19 °C under many conditions. These findings have important environmental and biological implications regarding the deliberate or inadvertent disposal of antifouling paint residues. 相似文献