Earthworms and in vitro physiologically-based extraction tests: complementary tools for a holistic approach towards understanding risk at arsenic-contaminated sites

The relationship of the total arsenic content of a soil and its bioaccumulation by earthworms (Lumbricus rubellus and Dendrodrilus rubidus) to the arsenic fraction bioaccessible to humans, measured using an in vitro physiologically-based extraction test (PBET), was investigated. Soil and earthworm samples were collected at 24 sites at the former arsenic mine at the Devon Great Consols (DGC) in southwest England (UK), along with an uncontaminated site in Nottingham, UK, for comparison. Analysis of soil and earthworm total arsenic via inductively coupled plasma mass spectrometry (ICP-MS) was performed following a mixed acid digestion. Arsenic concentrations in the soil were elevated (204–9,025 mg kg⁻¹) at DGC. The arsenic bioaccumulation factor (BAF) for both earthworm species was found to correlate positively with the human bioaccessible fraction (HBF), although the correlation was only significant (P ≤ 0.05) for L. rubellus. The potential use of both in vitro PBETs and earthworms as complementary tools is explored as a holistic and multidisciplinary approach towards understanding risk at contaminated sites. Arsenic resistant earthworm species such as the L. rubellus populations at DGC are presented as a valuable tool for understanding risk at highly contaminated sites.     

Management of dredge material in the Republic of Ireland - A review

As an island nation the Republic of Ireland's ports and harbours are key to the economic wellbeing of the country as they are the primary transport link to the United Kingdom, mainland Europe and beyond. This paper examines the main aspects of the Irish dredging industry with comparison to international practice and standards, including the source of the dredge material and volumes generated annually, the dredging plant employed and the management processes currently practised. Relevant European and Irish legislation governing dredging, disposal at sea and waste licensing are presented. The potential impacts of disposal at sea are discussed with the implications for the Irish dredging industry of recently introduced European Directives assessed. Beneficial use rates for dredge material and the techniques implemented in Ireland are examined and compared with international practice. Recent notable beneficial use projects for dredge material and proposed innovative dredge material management techniques for specific dredging projects in Ireland are presented. Proposals to encourage greater beneficial use of dredge material and minimise disposal at sea for Ireland are presented including the introduction of environmental credits, tax breaks and a grant system for pilot schemes. An alternative disposal at sea charge fee structure is also recommended to encourage alternative dredge material management practices. Ireland's management of contaminated sediment is also presented with recent projects described highlighting the current practice of primarily exporting contaminated sediment to mainland Europe. Alternative methods of treatment of contaminated sediment are assessed in an Irish context. Future issues and challenges facing the Irish dredging industry are assessed and a critical analysis of the current approaches to dredge material management is presented.     

PLATE JUNCTIONS AND HYDROCARBON ACCUMULATIONS IN THE INDIAN REGION

This article relates the productive and potential oil fields in India to plate junctions and other major tectonic features. High geothermal gradients are known to accelerate the expulsion of petroleum from the source bed, as well as its migration and accumulation in favourable reservoir rocks, resulting in high yield. Some of the world's major petroleum deposits occur along ‘failed arms’ associated with the plume generated triple junctions. Seven triple junctions have been located in the Indian region, and two more are identified here. Interestingly, India's off-shore petroleum prospects coincide with some of these triple junctions. Cet article établit la relation entre les champs de pétrole en production et potentiels en Inde à la théorie des plaques et à d'autres traits tectoniques importants. L'on sait que des gradients géothermiques élevés accélèrent l'expulsion du pétrole à partir de la roche-mère et favorisent la migration et l'accumulation dans des réservoirs convenables. Quelques-uns des plus grands champs de pétrole du monde se rencontrent en liaison avec des ‘bras morts’ associés avec un système triple de fossés d'effondrement. Sept systèmes triples ont été repérés en Inde et deux autres sont reconnus ici. II est intéressant de remarquer que les possibilités pétrolières de l'offshore indien coïncide avec certains de ces systèmes triples. Este artículo establece la relación entre los campos petrolíferos en producción y potenciales de India a la teoría de placas y otros aspectos tectónicos. Es sabido que una gradiente térmica alta ascelera la expulsión del petróleo desde la roca madre y favorece su migración y acumulación en rocas reservorio favorables. Algunos de los mayores depósitos de petróleo se encuentran a lo largo de los “brazos muertos” asociados a un sistema triple de unión de placas. Siete uniones de este tipo habia sido localizadas en India y otros dos más son identificados aquí. Es interesante notar que las posibilidades petroleras en la zona marítima de India coinciden con alguna forma de sistemas triple de placas.