Bioremediation of Chlorobenzene-Contaminated Groundwater on Granular Activated Carbon Barriers

During the past decade, various promising technologies have been developed for the decontamination of groundwater insitu which do not require long-term pumping or high energy consumption. One approach is to use funnel and gate technology. In the case described here, the combination of adsorption of contaminants on granular activated carbon (GAC) and its biodegradation is applied to considerably extend the operating time of the filling material in the barrier system. Monochlorobenzene (MCB), a recalcitrant groundwater contaminant under anaerobic conditions, undergoes high-capacity adsorption on GAC up to about 450 mg per gram. Aerobic enrichment cultures, obtained from a contaminated aquifer, were able to mineralize initially adsorbed MCB. In respirometer experiments the rate of carbon dioxide formation was dependent on the equilibrium concentration of MCB. The oxygen consumption of activated carbon by means of autoxidative reactions may delay aerobic biodegradation in GAC filters. The oxygen uptake of pristine activated carbon amounted to 5.6 mg per gram GAC in laboratory column experiments. When GAC was pre-loaded with MCB, autoxidation rates were considerably reduced. Hence, it is advisable not to stimulate the biodegradation of MCB by oxygen supply in GAC biobarriers until after an initial period of solely sorptive MCB removal from the groundwater flow.     

Regional assessment of climate change impacts on maize productivity and associated production risk in Switzerland

A simple model of yield was used along with climate scenarios to assess the impact of climate change on grain maize productivity and associated economic risk in Switzerland. In a first application, changes in the precipitation regime alone were shown to affect the distribution of yield considerably, with shifts not only in the mean but also in the standard deviation and the skewness. Production risk was found to respond more markedly to changes in the long-term mean than in the inter-annual variability of seasonal precipitation amounts. In a further application, yield projections were generated with respect to a full climate scenario, with the emission pathway as specified in the IPCC A2 scenario. Anticipation of the sowing date was found to reduce the negative impact of climate change on yield stability, but was not sufficient to ensure average productivity levels comparable to those observed at present. We argued that this was caused by the reduction in the duration of the growing season, which had a stronger impact than suggested by previous studies. Assuming no change in price relations, the results also revealed a strong increase in production risk with climate change, with more than a doubling in the probability of yield falling short of a critical threshold as compared to today’s situation.     

Waste Management in the European Union: National Self-Sufficiency and Harmonization at the Expense of Economic Efficiency?

/ Since 1975, the European Union (EU) has developed an impressive body of waste management legislation, although, according to the principle of subsidiarity, responsibilities belong to the most local level at which the tasks can be carried out effectively. Using economic theory, this paper examines several factors that influence the efficient distribution of regulatory authority among the EU and the member states. We specifically analyze the role of harmonization that, in our opinion, will often lead to an overcentralization. Within this context, a second issue is becoming more important, as ongoing discussions show. If no consensus can be reached about harmonization, should member states be allowed to stop cross-border shipments of waste, or should the EU strive for a common market for waste? We take the position that most objections against waste shipments are not convincing, especially if the member states implement minimum standards for landfills and waste processing facilities and common information and control systems. Competition between different national regulations within adequate constraints that, e.g., control transboundary externalities leads to more efficient waste management structures in Europe than national self-sufficiency or centralized decision-making at the EU level. KEY WORDS: Waste management; European Union; Subsidiarity; Institutional competition; Harmonization; Cross-border shipments of waste     

The international toxicity equivalency factor (I‐TEF) method for estimating risks associated with exposures to complex mixtures of dioxins and related compounds∗

The International Toxicity Equivalency Factor (I‐TEF) method of risk assessment is a revised interim procedure for assessing the risks associated with exposures to complex mixtures of chlorinated dibenzo‐p‐dioxins and dibenzofurans (CDDs and CDFs). This updated scheme was developed by a working group of the North Atlantic Treaty Organization's Committee on the Challenges of Modern Society and has been officially adopted by the U.S. Environmental Protection Agency (EPA), Canada, Ontario Ministry of the Environment, the Nordic countries, the Netherlands, and the United Kingdom. Prior to the development of the I‐TEF method, at least ten slightly different schemes had been used throughout the world which complicated communication among scientists and regulatory agencies concerning the toxicological significance of complex mixtures of CDDs and CDFs. The I‐TEF approach facilitates risk communication internationally by reducing large volumes of analytical data into a single number‐International Toxicity Equivalents (I‐TEQ). As a result, the I‐TEF method represents an improvement in an already useful risk assessment/regulatory tool.