CHEMICAL COMPOSITION OF SOFTWATER FLORIDA LAKES AND THEIR SENSITIVITY TO ACID PRECIPITATION1

ABSTRACT: Based on alkalinity data for 596 lakes, 31 percent of Florida's 7300 lakes have < 100 μeq/l alkalinity and are sensitive to acid depostion. More than two-thirds of the lakes in 12 northern Florida counties fit this criterion. Increasing aluminum and decreasing nutrient and chlorophyll a concentrations were observed with decressing pH in a survery of 20 softwater lakes. Maximum measured aluminum values (100-150 μg/L) are below levels asociated with fish toxicity. Factor analysis showed that lake chemistry was related to three principal factors, representing three major processes: watershed weathering, acidification, and nutrient inputs. An acidification index defined as the difference between excess SO₄^2- and excess (Ca²⁺+Mg²⁺) accounted for 74 percent of the variance in lake pH. Comparison of historical (late 1950a) and present data for pH, alkalinity, and excess SO₄^2- indicated loss of alkalinity (>25 μeq/L) and increase in excess SO₄^2- (16-34 μeq/L) in several softwater lakes.     

Patterns of shell repair in articulate brachiopods indicate size constitutes a refuge from predation

The cost of overcoming prey defenses relative to the value of internal tissues is a key criterion in predator/prey interactions. Optimal foraging theory predicts: (1) specific sizes of prey will result in the best returns to predators, and (2) there will often be a size at which the cost/benefit balance is low enough to effectively exclude predation. Data presented here on styles of repaired shell damage and size at which injury had been sustained was collected from samples of terebratulide brachiopods from the Antarctic Peninisula (Liothyrella uva), Falkland Islands (Magellania venosa and Terebratella dorsata) and Chile (M. venosa). The predominant form of damage on shells was indicative of predators attacking the valve margins. The modal size for repaired damage was more than 10 mm smaller than the modal size for the overall size distribution in each species and there were no repaired attacks in the largest size classes of any species. These data suggest that size forms a refuge from predation, as would be predicted by optimal foraging theory. The optimal sizes that predators appeared to attack vary between species, as do the sizes that provided a refuge from predation. High levels of multiple repairs (19% of the M. venosa population from the Falkland Islands sampled had 2 or more repairs) suggest that the mortality following attack is low, suggesting that many predators abandon their attacks.     

Development and Evaluation of a Method to Determine Indicator Microorganisms in Air Emissions and Residue from Medical Waste Incinerators

To allow testing of microbial destruction in medical waste incinerators, methods were developed to determine indicator microorganisms (Bacillus Stearothermophilus spores) in incinerator air emissions and residue. The emission trapping train consisted of a water cooled glass probe and impingers containing a neutral phosphate buffer. In field tests, spores were injected directly into the probe, and results showed that approximately 60 percent of the spores were recovered. Spores were analyzed with adequate precision using a microbial membrane filter unit. Lab experiments indicated that spores were stable in neutral pH phosphate buffer for up to 20 days, and heat shocking samples (heating to 80°C for 20 minutes) reduced spore numbers in acidic or basic buffer. Laboratory tests also showed that 60 to 70 percent of spores initially added to ash were recovered up to 22 days after addition of the spores. In addition, lab tests showed that spores can be effectively recovered from residue test pipes spiked with indicator spores.     

Quantifying uranium complexation by groundwater dissolved organic carbon using asymmetrical flow field-flow fractionation

The long-term mobility of actinides in groundwaters is important for siting nuclear waste facilities and managing waste-rock piles at uranium mines. Dissolved organic carbon (DOC) may influence the mobility of uranium, but few field-based studies have been undertaken to examine this in typical groundwaters. In addition, few techniques are available to isolate DOC and directly quantify the metals complexed to it. Determination of U-organic matter association constants from analysis of field-collected samples compliments laboratory measurements, and these constants are needed for accurate transport calculations. The partitioning of U to DOC in a clay-rich aquitard was investigated in 10 groundwater samples collected between 2 and 30 m depths at one test site. A positive correlation was observed between the DOC (4-132 mg/L) and U concentrations (20-603 microg/L). The association of U and DOC was examined directly using on-line coupling of Asymmetrical Flow Field-Flow Fractionation (AsFlFFF) with UV absorbance (UVA) and inductively coupled plasma-mass spectrometer (ICP-MS) detectors. This method has the advantages of utilizing very small sample volumes (20-50 microL) as well as giving molecular weight information on U-organic matter complexes. AsFlFFF-UVA results showed that 47-98% of the DOC (4-136 mg C/L) was recovered in the AsFlFFF analysis, of which 25-64% occurred in the resolvable peak. This peak corresponded to a weight-average molecular weight of about 900-1400 Daltons (Da). In all cases, AsFlFFF-ICP-MS suggested that相似文献   

Exorbitant mortality of hatchery-reared Atlantic salmon smolts Salmo salar L., in the Meuse river system in the Netherlands

Stocking Atlantic salmon Salmo salar L. in the Meuse river system is unsuccessful, since hardly any adults return upstream. To investigate problems during seaward migration, individual salmon smolts were tracked in the Dutch part of the river Meuse, using the Nedap Trail® system. The study included a comparison for two seasons, one with high (2010) and one with low (2011) discharge conditions. Cultivated smolts (Loire-Allier strain, n = 100 per year) were implanted with telemetry tags and released in the tributary Roer in March, at the beginning of the natural smolt run. The study area was split into four river sections each characterized by different conditions: tributary Roer, main river Meuse extensively dammed, main river Meuse free flowing and the estuary. Mortalities differed considerably between sections. In the free flowing river Meuse the mortalities were relatively low (10 and 25 %). Mortalities were high in the tributary (44 and 45 %), the dammed river (46 and 49 %) and in the estuary (89 and 90 %). Only 2 and 3 % of the smolts escaped into the North Sea. Results are discussed in relation to environmental factors light and discharge and the presence of man-made obstacles: weirs, hydropower plants and a sea lock. A lack of current and delays at man-made obstacles result in disorientation of fish, a higher risk of predation and disturbance of the smolt run timing. Mortality causes must decrease for sustaining a salmon population in the Meuse.