Collaborative Testing of Methods to Measure Air Pollutants

A collaborative test was conducted to determine the precision of the chemiluminescent method which has been specified for measuring ozone, to determine photochemical oxidant. Ten laboratories participated in a test involving the analysis of an urban atmosphere containing a photochemical smog mixture. Ozone generators were used to increase the O₃ level over that naturally occurring, in order to cover an adequate range of concentrations. The range tested was 0 to 0.5 ppm.

A statistical analysis of the data obtained was used to derive equations for within laboratory and between laboratory standard deviations. In order to evaluate sampling data, these equations can be used in various statistical procedures to estimate repeatability, reproducibility, lower detectable limit, and other measures that establish the precision of the method.

Using specific definitions for repeatability and reproducibility, the following approximate estimates were obtained in the range of zero to 0.5 ppm:

Repeatability—0.01 to 0.04 ppm (varies with concentration, linear).

Reproducibility—0.01 to 0.09 ppm (varies with concentration, non-linear).

The lower detectable limit depends on instrumental and other variables, and cannot be specified precisely. Under typical assumptions, this limit can be estimated at between 0.006 and 0.009 ppm.     

Perceived Conflicts Between Pastoralism and Conservation of the Kiang Equus kiang in the Ladakh Trans-Himalaya, India

An emerging conflict with Trans-Himalayan pastoral communities in Ladakh’s Changthang Plateau threatens the conservation prospects of the kiang (Equus kiang) in India. It is locally believed that Changthang’s rangelands are overstocked with kiang, resulting in forage competition with livestock. Here, we provide a review and preliminary data on the causes of this conflict. Erosion of people’s tolerance of the kiang can be attributed to factors such as the loss of traditional pastures during an Indo-Chinese war fought in 1962, immigration of refugees from Tibet, doubling of the livestock population in about 20 years, and increasing commercialization of cashmere (pashmina) production. The perception of kiang overstocking appears misplaced, because our range-wide density estimate of 0.24 kiang km⁻² (± 0.44, 95% CL) is comparable to kiang densities reported from Tibet. A catastrophic decline during the war and subsequent recovery of the kiang population apparently led to the overstocking perception in Ladakh. In the Hanle Valley, an important area for the kiang, its density was higher (0.56 km⁻²) although even here, we estimated the total forage consumed by kiang to be only 3–4% compared to 96–97% consumed by the large livestock population (78 km⁻²). Our analysis nevertheless suggests that at a localized scale, some herders do face serious forage competition from kiang in key areas such as moist sedge meadows, and thus management strategies also need to be devised at this scale. In-depth socioeconomic surveys are needed to understand the full extent of the conflicts, and herder-centered participatory resolution needs to be facilitated to ensure that a sustainable solution for livelihoods and kiang conservation is achieved.     

Comment on Long Term Ozone Trends

Under Title III of SARA, companies must provide information about chemicals that they manufacture, store, or process. Communities will use data about potential accidental releases to develop local emergency plans. Data about routine chemical releases will be made available to the public on a computer data base. Simply having such data available does not ensure consensus about reducing potential chemical risks. Laboratory and field research are summarized, indicating that people tend to edit small risks to zero as being too small to worry about, or to adjust them imperfectly from an anchor equal to the potential loss. These results suggest recommendations for communicating about the risks posed by accidental or routine releases of chemicals.     

Validation and global uncertainty of a gas chromatographic with mass spectrometry method for fenamidone analysis in grapes and wines

Fenamidone is an imidazolinone fungicide recently introduced in viticulture practices. This work reports the validation and assessment of global uncertainty of a gas chromatographic with mass spectrometry method to analyze fenamidone in grapes and wines. This method consists in a simple and fast liquid-liquid extraction step followed by chromatographic determination. Limits of detection for fenamidone in grapes and wines were, respectively, 0.05 mg/kg and 0.06 mg/L, precision was below 9.4% and average recovery was 89 ± 5%. In the concentration range from 0.05 to 1.00 mg/kg (or mg/L) of fenamidone, global uncertainty calculated following the EURACHEM/CITAC rules, and also by the Horwitz function, was below 25%. The EURACHEM/CITAC global uncertainty budget used gave lower estimates than those obtained from the Horwitz function.     

Accumulation and metal fluxes in the central Venice Lagoon during the last century

Samples from 18 short sediment cores were analyzed for major and trace metals (Al, Fe, Ca, K, Mg, Mn, Si, Ti, Pb, Zn, Cu, Ni, and Cr), ²¹⁰Pb, ¹³⁷Cs, total organic carbon, grain size, and mineralogical composition to find the record of major environmental changes, either natural or anthropogenic, and to establish their chronologies. Some sediments are characterized by nearly constant composition over time, but others clearly show signs of an increasing marine influence, as an increase of the carbonate contents, after the opening of the Malamocco-Marghera Canal in 1969. These changes sometimes obscure the real pattern of pollutants and tracers, which is revealed by normalization against Al. Zn is the most important contaminant, with concentration factors up to 9.3 times the background level, and the most contaminated sediments are those within a few kilometers from the industrial district of Porto Marghera. ²¹⁰Pb activity-depth profiles were used to calculate apparent accumulation rates that provide a basis for the assessment of metal fluxes. The sediments of several sites show a significant increase in anthropogenic metal contamination starting from the second decade of last century, with maximum inputs from 1930 to 1970. The decrease of heavy metal concentrations observed in surficial sediments of some sampling sites could be related to a recent reduction of pollutant inputs.     

Description and evaluation of a sampling system for long-time monitoring of PAHs wet deposition

In this paper a new electronically controlled year-round wet-only sampler for wet deposition of trace organic compounds (e.g. airborne PAHs) is described. The sampler provides in situ filtration of the precipitation as well as preconcentration of nonpolar organic compounds by means of a C18-PAH modified silica gel cartridge. The whole assembly is insulated and equipped with heating elements which permit collection of wet deposition as ice or snow and insure correct function of the sampling system even during cold weather. Concurrent chemical analysis of both the particulate and the dissolved phases is performed by high resolution gas chromatography with flame ionization detection or HPLC with fluorescence detection. The reliability of the method was proved by analyzing PAH spiked water (simulated rain) and using NIST SRM 1649 ('urban dust') as certified material for particle-bound PAHs in precipitation. This study proved satisfactorily recoveries of as both particle-bound and unbound aqueous PAH, with only small losses to collector surfaces. It was proved that this new wet-only precipitation sampler can successfully be used for long-time monitoring of PAH in wet depositions in urban areas.