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51.
Hideo Okamura Masahiro Yagi Masanobu Kawachi Takeaki Hanyuda Hiroshi Kawai Iain Walker 《毒物与环境化学》2013,95(3):545-556
The environmental impact of two biocide-free antifouling paints, fluoropolymer and silicone types, painted on a test cylinder was assessed using a battery of ecotoxicity test and chemical analyses for organic micro-pollutants such as perfluoroalkyl substances (PFAS). A biocide paint containing zinc pyrithione (ZnPT2) and cuprous oxide was assessed as a positive control. A standardized laboratory rotating-cylinder method using each test cylinder with artificial seawater was performed for 45 days. After 1?h rotation, the leaked seawater was subjected for bioassay and chemical analyses twice weekly. The seawater extracts from the biocide paint showed adverse effects on bacteria, algae, and crustaceans, but those from the biocide-free paints did not. The leakage seawater from biocide-free paints, after 7-day continuous rotation, contained the same concentration levels of PFAS as blank seawater used to conduct the tests. Thus, no significant toxicities of the biocide-free paints were found under the conditions of this study. Simultaneous analysis of ZnPT2 and copper pyrithione (CuPT2) was developed using an HPLC with a polymeric resin column, showing that ZnPT2 was converted to CuPT2 by trans-chelation in the leakage seawater from the positive control paint. The experimental results using a laboratory rotating-cylinder method demonstrated that biocide-free paints did not markedly affect three species tested and no PFAS was detected. In contrast, biocide paint was significantly toxic to test species and toxicity of the extract on bacteria was partly responsible for CuPT2 produced in leakage seawater. Thus, a laboratory rotating-cylinder method may be applied for ecotoxicological assessment of antifouling paints. 相似文献
52.
In this study, limestone powder was directly added to synthetic MSW, which was fed into a small‐scale fluidized bed incinerator. The concentration of CBzs and CPs in the flue gas were measured before and after a secondary combustion air injection. Finally, the PCDDs and PCDFs concentrations were also measured in the flue gas after the secondary combustion zone. The CaCO3 added to synthetic MSW not only controls HCl in the flue gas, but suppresses the formation of chlorinated aromatic compounds like CBzs, CPs, PCDDs, and PCDFs. The main mechanisms to control the formation of chlorinated aromatic compounds was more likely related to the suppression of catalytic capability of flyash than the HCl reduction in the flue gas. However, the NO concentration was increased by catalytic reaction of limestone in the fluidized bed. 相似文献
53.
Shunitz Tanaka Masayuki Kawai Yosuke Nakata Motoki Terashima Hideki Kuramitz Masami Fukushima 《毒物与环境化学》2013,95(4-6):95-102
The photo-Fenton reactions, which could yield hydroxyl radicals via the catalytic degradation of H2O2 by Fe(II), were focused as one of the abiotic degradation processes of bisphenol A (BPA) in surface waters. At pH 6, in the presence of H2O2 only, 32% of BPA was degraded after 120?min of irradiation. However, 97% of BPA was degraded in the presence of both H2O2 and Fe(II). Without light irradiation, no BPA degradation was observed even in the presence of Fe(II) and H2O2. These results show that photo-Fenton processes are effective in the natural attenuation of BPA in surface water. In addition, the presence of humic acids (HAs), which were of more aliphatic nature, resulted in enhancing BPA degradation via the photo-Fenton processes. Therefore, HAs can be one of the important factors in enhancing the degradation of BPA in surface water via the photo-Fenton processes. 相似文献
54.
Sean M. Richards Todd A. Anderson Michael J. Hooper Scott T. McMurry Steven B. Wall Hiroshi Awata 《毒物与环境化学》2013,95(3-4):215-234
European starling (Sturnus vulgaris) nestlings were used as a surrogate to study the effect of chlorpyrifos application to a corn agroecosystem on songbird reproduction. Chlorpyrifos was applied in a T‐band at 1.3 kg AI/ha, and residues were measured in soil, earthworms, ground‐dwelling insects, and diet items collected from the crop of starling nestlings. Chlorpyrifos levels in soil peaked at 34.2 μg/g, 4 days post‐application, and dissipated to trace levels by 64 days post‐application. Concentrations of chlorpyrifos in earthworms and ground‐dwelling insects reached 0.9 and 0.7 ug/g, respectively. Starling nestling diet items included invertebrates from eight orders with chlorpyrifos concentrations ranging from trace levels to 10.6 μg/g in earthworms. Nestling brain and plasma cholinesterase (ChE) activity and body mass measurements were taken at 3, 8, and 13 days post‐hatch (DPH). Adult starling fecundity was also measured. Body mass differences between treatment and reference site nestlings at 3 and 13 DPH were not significant at α = 0.05. However, 8 DPH nestlings from the Treatment Site had a transient reduction in weight (p = 0.03) when compared with 8 DPH reference nestlings. There were no significant differences in brain or plasma ChE activities of 3, 8, or 13 DPH nestlings. Further, multiple measures of fecundity (i.e., clutch size, hatching percentage, and fledging percentage) indicated that chlorpyrifos application did not affect starling nestling survival to fledging, as the values from the Treatment and Reference Site were nearly identical. This screening‐level study suggests that although one age group of starling nestlings from the Treatment Site weighed less than their Reference Site counterparts, a single T‐band application of chlorpyrifos did not impair starling nesting success. 相似文献
55.
Ueda Hiroyuki Moriyama Akihiro Iwahashi Hitoshi Moritomi Hiroshi 《Journal of Material Cycles and Waste Management》2021,23(2):505-515
Journal of Material Cycles and Waste Management - Carbon fiber-reinforced plastics (CFRP) are used for structural materials in the aircraft and automotive industries due to their lightweight and... 相似文献
56.
Fang Yiming Sakai Hiroshi 《Environmental science and pollution research international》2022,29(7):9923-9931
Environmental Science and Pollution Research - Natural organic matter (NOM), commonly found in surface and ground waters, form disinfection by-products in drinking water. Generally, advanced... 相似文献
57.
Hiroe Yasui Toshiharu Akino Midori Fukaya Sadao Wakamura Hiroshi Ono 《Chemoecology》2008,18(4):233-242
Summary. We conducted a series of experiments with the white-spotted longicorn beetle Anoplophora malasiaca (Thomson), and its host plant, Citrus unshiu, to examine the origin of the sesquiterpene hydrocarbons (SHCs; including β-elemene, β-caryophyllene, α-humulene, α-farnesene,
and several unidentified compounds) that are contained in the elytra of the beetles and act as an attractant. In the laboratory,
mechanically wounded citrus branches, as well as those fed upon by A. malasiaca, attracted males more frequently than intact branches. Solid phase microextraction (SPME) and subsequent analyses by gas
chromatography (GC) analyses detected measurable SHCs from the air around both mechanically wounded and beetle-infested branches,
as well as trace amounts from intact branches. The SHCs were also detected for a certain time from beetles that had fed on
the citrus branches, but the amounts decreased rapidly after they were removed from the host. This decrease generally corresponded
with a reduction of attractiveness of the beetles in a behavioural assay. Isolated females acquired the SHCs after exposure
to, but not upon contact with, other females that had fed on C. unshiu branches. We hypothesize that the citrus SHCs are adsorbed in, retained on, and released from the wax layer of the beetle
elytra. Since these compounds are released from branches when beetles feed, they may indirectly signal the presence of beetles
to others in the field. The high response rate to SHCs by males is likely representing mate searching behavior. The SHCs act
as kairomones with a releaser effect in the communication system of A. malasiaca.
Hiroe Yasui, Toshiharu Akino, Midori Fukaya: These authors contributed equally to this article. 相似文献
58.
Kobayashi T Hirose J Sano K Hiro N Ijiri Y Takiuchi H Tamai H Takenaka H Tanaka K Nakano T 《Chemosphere》2008,72(4):659-665
We recently reported a system for inactivating antineoplastics in which sodium hypochlorite is supplied by the electrolysis of sodium chloride solution. In this study, we designed an electrolysis apparatus for inactivating the cytotoxicity of antineoplastics in clinical wastewater using the system. The apparatus consists of an electrolysis cell with platinum-iridium electrodes, a pool tank, a circulating system for wastewater, a safety system for explosive gas and overflow, and an exhaust duct. The free chlorine concentration increased linearly up to 6500 mg l(-1), and pH also increased to 9.0-10.0 within 2h, when 0.9% sodium chloride solution was electrolyzed. We examined its efficacy with model and clinical wastewaters. The reciprocal of dilution factor for disappearance of cytotoxicity using Molt-4 cells was compared before and after electrolysis. In the model wastewater, that was 9.10 x 10(4) before electrolysis, and 3.56 x 10(2) after 2h of electrolysis. In the clinical wastewater (n=26), that was 6.90 x 10(3)-1.02 x 10(6) before electrolysis, and 1.08 x 10(2)-1.45 x 10(4) after 2h of electrolysis. Poisonous and explosive gases released by the electrolysis were measured; however, they were found to be negligible in terms of safety. The environmental load was evaluated by carbon dioxide generation as an index and it was found that the carbon dioxide generated by the electrolysis method was 1/70 lower than that by the dilution method with tap water. Moreover, the cost of the electrolysis method was 1/170 lower than that of the dilution method. This method was found to be both effective and economically valuable. 相似文献
59.
Oguntimehin I Nakatani N Sakugawa H 《Environmental pollution (Barking, Essex : 1987)》2008,154(2):264-271
Polycyclic aromatic hydrocarbons (PAHs) have been widely studied with respect to their carcinogenic and mutagenic effects on animals and human cells. Phenanthrene (PHE) and fluoranthene (FLU) effects on the needle photosynthetic traits of 2-year-old Japanese red pine (Pinus densiflora Sieb. et. Zucc.) seedlings were investigated. Three months after fumigation of foliage with solutions containing these PAHs (10 microM each), FLU had negative effects on net photosynthesis at near-saturating irradiance, stomatal conductance, initial chlorophyll fluorescence, and the contents of total chlorophyll, magnesium, and ribulose 1,5-bisphosphate carboxylase (rubisco) of current-year needles. PHE had similar negative effects to FLU but in lesser magnitude. The effects of the PAHs were mitigated by the addition of an OH-radical scavenger (mannitol) into the PAH solutions. PAHs deposited on the surface of pine needles may induce the generation of reactive oxygen species in the photosynthetic apparatus, a manner closely resembling the action of the herbicide paraquat. 相似文献
60.