Causes of accidents by soy sauce squeezing residue and fish meal

Recently, a demand for the reuse, recycling and reduction of waste has arisen. In the food industry, efforts are being made to recycle the waste produced and use resources more efficiently. However, some industrial food waste or recycled waste materials generate heat as a result of fermentation and oxidation, which leads to an increase in temperature during storage and transport, ultimately resulting in spontaneous ignition. In this study, we examined the fermentation and heat generation by soy sauce squeezing residue (SSSR) produced during the brewing of soy sauce and by the fish meal produced during the processing of fish residue. The objective of this study was to investigate the causes of fires using various heat analysis methods and to understand the processes of fermentation and oxidation of food industry waste that lead to spontaneous ignition.     

Formation of mutagens by photochemical reaction of biphenyl in nitrate aqueous solution

Biphenyl was found to be converted to mutagenic compounds by UV irradiation with a high-pressure mercury lamp in nitrate aqueous solution under neutral conditions. The mutagenicity of the reaction mixture increased in proportion to the nitrate ion concentration. The most mutagenic product was dinitro dihydroxy biphenyl, and the main products in this reaction were 2-hydroxy-3-nitrobiphenyl and 4-hydroxy-3-nitrobiphenyl.     

Substance flow analysis of coplanar PCBs released from waste incineration processes

Previous reports have focused on the emission of coplanar polychlorinated biphenyls (Co-PCBs) which have a toxic mechanism similar to that of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/DFs) released from municipal solid waste (MSW) incineration. Such emissions accounted for a small percentage of all the dioxins (PCDDs/DFs and Co-PCBs) recorded at the toxicity equivalent (TEQ) level. There is, however, very little information about Co-PCBs, such as the quantities being released and their effect on overall environmental pollution. The aim of this research has been to clarify the substance flow of Co-PCBs from MSW incineration processes. The results reveal that whereas the input of Co-PCBs into the MSW incineration facilities in Kyoto City was 0.13–0.29 μg-TEQ per ton waste, the total output of Co-PCBs (the sum of Co-PCBs released from emission gas, fly ash, and bottom ash) was 4.9 μg-TEQ per ton waste. The total output was therefore found to be higher than the total input. Over 90% of the total PCBs were decomposed in the incineration process. In comparing the profiles of congeners and homologues, those in the MSW were found to be similar to those detected in the atmosphere and products containing PCBs, but different from those in the MSW incineration gas. Received: August 26, 1998 / Accepted: March 2, 1999     

Simultaneous determination of 2-phenylbenzotriazole-type mutagens, PBTA-1 through -8, in river water by liquid chromatography-tandem mass spectrometry

We describe a method for the simultaneous determination of eight kinds of phenylbenzotriazole-type mutagens (PBTA-1, -2, -3, -4, -5, -6, -7 and -8) in river water based on liquid chromatography-tandem mass spectrometry (LC/MS/MS). The application of dopant-assisted atmospheric pressure photoionization (APPI) for the detection of the PBTAs was studied. The APPI technique provided higher PBTA signal intensities than those obtained with an electrospray ionization (ESI) source, and the APPI method was used for the determination of the PBTAs. A solid-phase extraction procedure was used for the extractions of PBTA-1 through -8 from river water. The procedure was rapid and the relative standard deviations were below 15%. The detection limits of PBTA-1 through -8 in river water using the proposed method were found to range from 0.04 to 0.5 ng L(-1) and PBTAs were successfully detected in river water at sub-ng L(-1) levels.     

Concentrations of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in vacuum cleaner dust collected in Japanese homes

Perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) are shown to be globally distributed, environmentally persistent and bioaccumulative. Although there is evidence that these compounds exist in the serum of non-occupationally exposed humans, the pathways leading to the presence of PFOS and PFOA are not well characterized. The concentrations of PFOS and PFOA in the vacuum cleaner dust collected in Japanese homes were measured. The compounds were detected in all the dust samples and the ranges were 11-2500 ng g(-1) for PFOS and 69-3700 ng g(-1) for PFOA. It was ascertained that PFOS and PFOA were present in the dust in homes, and that the absorption of the dust could be one of the exposure pathways of the PFOS and PFOA to humans. With regard to risk management, it is important to consider the usage of PFOS and PFOA in the indoor environment in order to avoid further pollution.     

Thermal decomposition kinetic of liquid organic peroxides

This study demonstrates the application of isothermal calorimeter for investigating the thermal decomposition of several liquid organic peroxides, such as t-Butyl peroxy acetate (TBPA), Di-tert butyl peroxide (DTBP), and Cumene hydroperoxide (CHP). The decomposition mechanism and kinetic can be identified from case to case. TBPA and DTBP undergo first order reaction, whereas CHP occurs autocatalysis. Accurate kinetic can be assessed on the basis of discerning these various schemes of given samples. Consequently, the thermal runaway or reactive hazards potential of organic peroxides can be determined, for instance as a self accelerating decomposition temperature (SADT).     

Carbon accounting for Japanese petrochemicals

This paper discusses two bottom-up models for the estimation of carbon storage and CO₂ emissions related to the nonenergy use of fossil energy carriers. The models show how material flow accounting can be applied to policy making. The nonenergy use emission accounting tables model is a static model, while the chemical industry environmental strategy assessment program (CHEAP) model is a dynamic model of the flows of synthetic organic materials. Both models provide detailed and more accurate estimates of carbon storage in materials than the accounting method that is currently used in the framework of the Intergovernmental Panel on Climatic Change (IPCC) guidelines. The results for both models suggest that carbon storage in synthetic organic materials has been overestimated, and consequently CO₂ emissions have been underestimated. Japanese CO₂ emissions in 1996 were at least 1.9% higher than reported previously. The CHEAP model results indicate that the net carbon storage (storage − emissions in waste incineration) will decrease during the next few decades. This decrease is mainly driven by changing waste management practice. Received: December 8, 2000 / Accepted: August 15, 2001     

e-JIKEI Network using e-JIKEI Cameras: Community security using considerable number of cheap stand-alone cameras

The e-JIKEI Network, a concept for realizing a safer and more comfortable community, and the e-JIKEI Camera, a stand-alone camera developed for the e-JIKEI Network, are reviewed. The concept of the e-JIKEI Network is that residents view their surroundings using cheap cameras, which act as their eyes, and home computers, which act as their brains, using the free software provided by us through the Internet. For the complete protection of the privacy of ordinary citizens, we propose a second concept supporting the concept of the e-JIKEI Network; in this concept, those who own and manage images (owners) and those who have the right to view these images (viewers) are separated by means of image encryption. Since 2004, the “Dairi-EYE” series, a free software for a personal computer (PC)-based system, has been distributed through our website. However, the use of PCs is not very user-friendly. Therefore, an all-in-one device called the “e-JIKEI Camera” has been developed. A social experiment of the e-JIKEI Network using e-JIKEI Cameras has been carried out.