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171.
A biofilter using granular activated carbon with immobilized Paracoccus sp. CP2 was applied to the elimination of 10–250 ppm of trimethylamine (TMA), dimethylamine (DMA), and methylamine (MA). The results indicated that the system effectively treated MA (>93%), DMA (>90%), and TMA (>85%) under high loading conditions, and the maximum degradation rates were 1.4, 1.2, and 0.9 g-N kg−1 GAC d−1. Among the three different amines treated, TMA was the most difficult to degrade and resulted in ammonia accumulation. Further study on TMA removal showed that the optimal pH was near neutral (6.0–8.0). The supply of high glucose (>0.1%) inhibited TMA removal, maybe due to substrate competition. However, complete TMA degradation was achieved under the co-immobilization of Paracoccus sp. CP2 and Arthrobacter sp. CP1 (96%). Metabolite analysis results demonstrated that the metabolite concentrations decreased by a relatively small 27% while the metabolite apparently increased by heterotrophic nitrification of Arthrobacter sp. CP1 in the co-immobilization biofilter. 相似文献
172.
PCDD/F and dioxin-like PCB in Hong Kong air in relation to their regional transport in the Pearl River Delta region 总被引:3,自引:0,他引:3
PCDD/F and dioxin-like PCB were measured in 142 air samples of Hong Kong. The annual average PCDD/F and dioxin-like PCB concentrations obtained for Hong Kong air at Tap Mun (PCDD/F: 1724+/-1984; dioxin-like PCB: 1572+/-1170 fg m(-3)), Yuen Long (PCDD/F: 2927+/-2695; dioxin-like PCB: 4331+/-1962 fg m(-3)) and Tsuen Wan (PCDD/F: 1875+/-1502; dioxin-like PCB: 2972+/-1510 fg m(-3)) from January 2004 to March 2005 were comparable to other urban centers around the world and were within the Japanese and USA ambient air quality guidelines. A clear seasonal pattern was observed for PCDD/F, generally with a 50-60 times higher air concentration in winter when background northerly wind was weaker and land-sea breeze prevailed, resulting in regional transport; and a lower concentration in summer, due to the inflow of clean oceanic southeasterly wind from the South China Sea. A higher WHO-TEQ value of dioxin-like PCB (mainly attributed to the relatively higher WHO-TEQ value of PCB 126) in Yuen Long during winter, compared with other months, could also be related to the regional transport by the winter monsoon wind and the low mixing height in winter. Spatially, air concentrations of PCDD/F and dioxin-like PCB demonstrated a west-to-east gradient (with Yuen Long>Tsuen Wan>Tap Mun). It is suggested that PCDD/F and dioxin-like PCB were transported into the western airshed of Hong Kong from the Pearl River Delta by land-sea breeze circulation and confined to the northwestern part, due to the blocking effect of the northwestern airshed in Hong Kong. 相似文献
173.
Gang-Woo Lee Byung-Hyun Shon Jong-Hyeon Jung Won-Joon Choi Kwang-Joong Oh 《Journal of Material Cycles and Waste Management》2010,12(3):204-211
The effect of mixing of NH3 and NO on the selective noncatalytic reduction (SNCR) reaction was investigated using a bench-scale reactor. Three different experimental conditions were compared for the removal of NO in the bulk gas with NH3, a reducing agent, by means of mixing and contacting. The temperature that gave the highest NO removal efficiency was about 800°C when NH3 was injected with air or NH3 was premixed and air was injected. It is suggested that control of mixing of the reducing agent and the injection conditions could be a good way to increase NO removal efficiency as well as to lower the reaction temperature. When NH3 was injected with air, the NO removal efficiency increased with increasing injected air flow if the initial NO concentration was low, whereas for high NO concentrations, the NO removal efficiency slightly increased up to an injected air flow rate of 100 ml/min. A proposed mixed-flow model can be used as a prediction tool for the NO removal efficiency covering various conditions of the real SNCR process. 相似文献
174.
The fate of multiple cyanobacterial metabolites was assessed in two Australian source waters. The saxitoxins were the only metabolites shown to be non-biodegradable in Myponga Reservoir water, while microcystin-LR (MCLR) and geosmin were biodegradable in this water source. Likewise, cylindrospermopsin (CYN) was shown to be biodegradable in River Murray water. The order of ease of biodegradability followed the trend: MCLR > CYN > geosmin > saxitoxins. Biodegradation of the metabolites was affected by temperature and seasonal variations with more rapid degradation at 24 °C and during autumn compared with 14 °C and during winter. A microcystin-degrading bacterium was isolated and shown to degrade four microcystin variants within 4 h. This bacterium, designated as TT25, was shown to be 99% similar to a Sphingopyxis sp. based on a 16S rRNA gene fragment. Isolate TT25 was shown to contain a homologue of the mlrA gene; the sequence of which was 99% similar to that of a previously reported microcystin-degrader. Furthermore, isolate TT25 could degrade the microcystins in the presence of copper sulphate (0.5 mg L−1 as Cu2+) which is advantageous for water authorities dosing such algicides into water bodies to control cyanobacterial blooms. 相似文献
175.
A sensitive and reliable quantification method for Bisphenol A based on modified competitive ELISA method 总被引:1,自引:0,他引:1
Kim A Li CR Jin CF Lee KW Lee SH Shon KJ Park NG Kim DK Kang SW Shim YB Park JS 《Chemosphere》2007,68(7):1204-1209
Bisphenol A (BPA), generally known as bisphenols, has been identified as a potential estrogenic substance. BPA must be conjugated to carrier protein and BSA was commonly used. 4,4-Bis(4-hydroxyphenyl) valeric acid (BHPVA) has a bisphenolic structure and a long carbon chain with a reactive carboxyl group on the end. In this study, BHPVA-BSA was used to produce polyclonal antibody against bisphenolic structure, and a modified competitive ELISA method for quantification of BPA was developed. This system was based on BHPVA-BSA for polyclonal antibody production against bisphenolic structure, and BHPVA-HRP for determination of BPA substituting detection antibody in competitive reaction. Recovery was assessed at 10 different concentrations (2-1000 ng/ml) of BHPVA, and the recovery range was from 96.3% to 107.2%. The variation was from 6.2% to 9.8% for intra assay and from 10.1% to 12.6% for inter assay. The quadratic was used to establish the curve regression. The range was found to be between 2 and 1000 ng/ml. This modified competitive ELISA method has proven to be a very useful tool for quantification of BPA without the unexpected interaction of BSA and anti-BSA polyclonal antibody. 相似文献
176.
Carbonyl emissions from commercial cooking sources in Hong Kong 总被引:2,自引:0,他引:2
Ho SS Yu JZ Chu KW Yeung LL 《Journal of the Air & Waste Management Association (1995)》2006,56(8):1091-1098
Cooking fumes are an important carbonyl emission source, especially in a highly urbanized city, such as Hong Kong. Cooking exhaust from 15 commercial kitchens of a variety of cooking styles was sampled and analyzed for a suite of 13 carbonyl compounds. Carbonyl compositions were varied among the different cooking styles. Formaldehyde was generally the most abundant carbonyl, and its contribution to the total carbonyl amount on a molar basis ranged from 12 to 60%. Acrolein was also found to be an abundant carbonyl in the cooking exhaust. The highest contribution by acrolein to the total carbonyls was found to be 30% in the exhaust of a western-style steak restaurant. Long-chain saturated carbonyls, that is, heptanal, octanal, and nonanal, accounted for a significant fraction (> 40%) of the total carbonyls in kitchens that always used heated cooking oils. Two dicarbonyls, glyoxal and methylglyoxal, had a various presence in the cooking emissions, ranging from negligible to 10%. The presence of benzaldehyde and tolualdehyde was mostly negligible in the sampled kitchen exhaust. Annual emission rates of both individual carbonyls and total carbonyls were estimated for various types of commercial kitchens. Local-style fast-food shops contributed the highest total carbonyl emissions per year mainly because of the large number of this kind of restaurant in Hong Kong. The citywide annual emission rates of the three most toxic carbonyls, formaldehyde, acetaldehyde, and acrolein, were estimated assuming that the limited number of sampled restaurants were representative of the average restaurants. Such estimates of carbonyl emission rates were comparable to the estimated carbonyl emissions from vehicular sources, suggesting the importance of commercial cooking as a source for carbonyls in Hong Kong. 相似文献
177.
Characteristics of malodor pollutants and aromatic VOCs around an urban valley in Korea 总被引:2,自引:0,他引:2
Song SK Shon ZH Kim YK Kim CH Yoo SY Park SH 《Environmental monitoring and assessment》2009,157(1-4):259-275
In this study, the environmental behavior of malodor pollutants (MPs) [including reduced sulfur compounds (RSCs)] and aromatic volatile organic compounds (AVOCs) were investigated around urban valley areas during several field campaigns (February through December 2006). The MPs measured in the study area include the RSCs (H(2)S, CH(3)SH, DMS, and DMDS), ammonia (NH(3)), and styrene (STY); the AVOCs include benzene (BEN), toluene (TOL), ethylbenzene (EB), m,p-xylene (MPX), and o-xylene (OX). The variation of most MP concentrations (except for DMDS) was found to be larger than that of AVOCs. It was found that STY (2,346 +/- 4,867 ppbv) was the most dominant MP followed by NH(3) (447 +/- 285), CH(3)SH (16 +/- 41), and the others (<8). The magnitude of AVOCs was found in the following descending order: TOL (1.4 +/- 2.2 ppbv), EB (1.0 +/- 2.1), MPX (0.9 +/- 2.0), and the others (<0.8). The concentration levels of most MPs on industrial (I) and downwind (D) sites were up to an order of magnitude higher than those at non-industrial (N) and upwind (U) sites. For most AVOCs, the former was ~3 times higher than the latter. For malodor intensity in RSCs, CH(3)SH was the dominant contributor. The concentration difference in target compounds between the sites/periods is likely to be caused by the combined effects such as emission sources, geographical features (e.g., semi-closed topography), and meteorological conditions (e.g., wind directions) in and outside the urban valley. 相似文献
178.
Karlesky DL Ramelow G Ueno Y Warner IM Ho CN 《Environmental pollution (Barking, Essex : 1987)》1987,43(3):195-207
Air samples in and around refinery areas were collected over a 3-year period. The results of the analysis for polynuclear aromatic compounds listed as priority pollutants by the United States Environmental Protection Agency are presented. The particulate matters in the air were collected on glass fiber filters using high volume samplers. These samples were later Soxhlet extracted with cyclohexane, and then extracted with DMSO/pentane for isolation of the polynuclear aromatic compounds. These extracts were then analyzed using gas chromatography-mass spectrometry for specified polynuclear aromatic compounds. It was found that much higher concentrations of these aromatic compounds were found in one refinery compared to another one. In general, the number of these priority pollutants detected and their concentrations were higher in sites inside the refineries relative to a site outside the refineries. 相似文献
179.
UASB和EGSB反应器中厌氧颗粒污泥生物学特性的比较 总被引:10,自引:0,他引:10
测定了实验室规模的2L EGSB和UASB反应器中培养的厌氧颗粒污泥在不同基质中的比产甲烷活性、辅酶F420含量和胞外多聚酶物含量,结果表明,EGSB反应器颗粒污泥在葡萄糖上的比产甲烷活性、利用乙酸的甲烷菌和产氢产乙酸菌的活怀和胞外多聚物/含量高于UASB反应器颗粒污泥,而UASB反应器颗粒污泥中利用甲酸和氢的甲烷菌的活性以及辅酶F420的含量较EGSB反应器颗粒污泥更高,辅酶F420可以指示同种 相似文献
180.
Ho Ngo Anh Dao Babel Sandhya 《Environmental science and pollution research international》2021,28(45):63480-63494
Environmental Science and Pollution Research - A large amount of silver-rich wastewater is generated from different industrial processes. This wastewater is not considered a waste, but a valuable... 相似文献