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541.
利用ICP-AES分析了潞城市采暖期和非采暖期4个不同功能区PM10样品中16种化学元素,对不同元素的时空分布特征进行了研究,并采用富集因子和主成分分析初步研究了潞城市PM10中元素的主要来源。结果表明,潞城市PM10中重金属污染较为严重,且各元素在采暖期的平均浓度均明显高于非采暖期。PM10中Ca、V、Cr、As、Ni、Mn、Cu、Zn、Al和Pb的富集因子EF〉10,主要来源于人为污染;而Na、Mg、Si、Fe和K的EF〈10,除部分来自人为活动外,主要来自土壤风沙等自然来源。主成分分析结果显示,潞城市PM10中元素的主要来源按贡献率大小依次为:煤烟尘和工业粉尘50.39%,自然源34.37%和机动车尾气15.24%。 相似文献
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大气污染治理是环境保护的重要内容。十二五时期,我国大气污染控制指标需根据国情调整。本研究针对我国目前主要大气污染物SO2、NOX及日益严重的大气复合污染问题,分析了近20年排放量、空气质量变化、控制状况。结果表明:SO2排放总量控制取得一定成效,但缺乏质量指标控制约束;NOX排放增加引发了多种复合型环境问题,部分抵消了SO2控制效果,总体上空气质量并未大幅度提升。对此,借鉴国外控制方法,提出十二五期间应进一步改善控制措施建议:SO2在总量控制基础上加入质量控制,分三类区域以不同标准和手段控制;NOX纳入约束性考核指标;选定重点行业和重点区域,对SO2、NOX采取总量与质量双重控制,并建立相应的政策支撑体系。 相似文献
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As a new threat to environment all through the world, perchlorate (ClO(4)(-)) was predominantly a thyrotoxin, and its toxic manifestations in non-thyroid were also documented. However, little is known about the effects of ClO(4)(-) on cell and organelle. Therefore, the present study was designed to investigate the effects of ClO(4)(-) on hepatocytes and mitochondria isolated from Carassius auratus from the direct viewpoint of energy by using the microcalorimetric method. The metabolic thermogenic curves of hepatocytes and mitochondria at 25°C were obtained. And the thermokinetic parameters, such as growth rate constant (k), inhibitory ratio (I), maximum thermal power (P(max)) and total thermal effect (Q(total)) have been calculated. The results indicated that the toxicity of ClO(4)(-) on hepatocytes was relevant to the concentration of ClO(4)(-). However, 10-100mgL(-1)ClO(4)(-) stimulated the metabolic activity of mitochondria and the toxicity of ClO(4)(-) on mitochondria only occurrenced when treated with higher concentration of ClO(4)(-). This study shown that mitochondria has a major impact on the metabolic thermogenic of hepatocytes, but not the only factor. Meanwhile, it demonstrated that microcalorimetry was a powerful tool for understanding biological processes and studying on the toxic action of environmental contaminants in cell or subcellular level. 相似文献
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Biota-sediment accumulation factors (BSAFs) for Dechlorane Plus (DP), a highly chlorinated flame retardant, were determined in three bottom fish species, i.e., crucian carp, mud carp, and northern snakehead from an electronic waste recycling site in South China. The average BSAFs are 0.007, 0.01, and 0.06 for syn-DP, and 0.003, 0.025, and 0.001 for anti-DP in crucian carp, mud carp, and northern snakehead, respectively, suggesting low bioaccumulation potential of DP isomers in these fish. However, the bioaccumulation factors (BAFs) determined previously in the same sample set indicated that both DP isomers were highly bioaccumulative (BAFs>5000) in most of the samples. This implies that BSAF values may be inherently inconsistent affecting their reliability as a bioaccumulation indicator. The BSAFs for DP isomers are two orders of magnitude lower than those (average of 0.43-2.28) for extremely hydrophobic polychlorinated biphenyls (CBs 199, 203, 207 and 208), but are comparable to those (average of 0.0001-0.009) for decabromodiphenyl ether (BDE 209) determined in the same sample set. Despite of the different chemical structures of the three compound classes, significantly negative correlations between logarithm of octanol-water partition coefficients (log K(OW)s) and BSAFs of these chemicals were found, indicating that hydrophobicity is one of the key factors influencing the bioaccumulation of these compounds. 相似文献
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近些年来,伴随着我国科技体制改革的进程,一些地方科研院所先后经历了体制转型和经费缩减等变革。这些改革和调整,一方面使得科研院所的市场竞争能力不断提高,院所的经济实力有所增强,锻炼培养了一批企业经营管理人才等等;而另一方面,科技人员为了适应体制变革带来的生存与发展中的新情况,在企业化、市场化的过程中,逐利行为占据主导地位, 相似文献
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Uptake of polycyclic aromatic hydrocarbons by Trifolium pretense L. from water in the presence of a nonionic surfactant 总被引:1,自引:0,他引:1
A greenhouse study examined plant uptake of phenanthrene and pyrene, as representatives of polycyclic aromatic hydrocarbons (PAHs), from an aqueous solution containing a nonionic surfactant Tween 80. The uptake was conducted with 1.0 mg l(-1) phenanthrene and 0.12 mg l(-1) pyrene under a wide range of Tween 80 concentrations (0-105.6 mg l(-1)). Tween 80 at the test concentrations did not show any apparent phytotoxity toward the growth of red clover (Trifolium pretense L.). At concentrations generally lower than 13.2 mg l(-1), Tween 80 enhanced the plant uptake based on the concentrations and PCFs (plant concentration factors) of these two PAHs. When present at higher concentrations, Tween 80 inhibited the uptake of both PAH compounds by the tested plant. The maximal plant uptake was observed at 6.6 mg l(-1) Tween 80, in which PAH concentrations and PCFs were 18-115% higher than those in Tween 80-free controls. The total mass removal (off-take) of phenanthrene and pyrene by root or shoot increased initially and decreased thereafter with the increase in Tween 80 concentrations. Although shoot biomass was evidently larger than root, the off-take was much higher in root than shoot because of the larger root concentrations of these chemicals. Results from this study show promises for the potential efficacy of enhanced phytoremediation in PAH contaminated sites using surfactant amendment. 相似文献