应用膜生物反应器处理冷轧含油废水

冷轧含油废水做为最难处理的一种废水,一般需经两级气浮或超滤处理,而后再需其他的处理;文章通过生化处理与膜生物反应器的结合,克服了"油封"对膜表面的污染,获得了一个稳定的膜通量和高效的生化处理效果,生化处理效率稳定高于97%,出水CODcr始终低于70 mr/L.     

Molecular characterization of transformation and halogenation of natural organic matter during the UV/chlorine AOP using FT-ICR mass spectrometry

UV/chlorine process, as an emerging advanced oxidation process (AOP), was effective for removing micro-pollutants via various reactive radicals, but it also led to the changes of natural organic matter (NOM) and formation of disinfection byproducts (DBPs). By using negative ion electrospray ionization coupled with Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS), the transformation of Suwannee River NOM (SRNOM) and the formation of chlorinated DBPs (Cl-DBPs) in the UV/chlorine AOP and subsequent post-chlorination were tracked and compared with dark chlorination. In comparison to dark chlorination, the involvement of ClO^?, Cl^?, and HO^? in the UV/chlorine AOP promoted the transformation of NOM by removing the compounds owning higher aromaticity (AI_mod) value and DBE (double-bond equivalence)/C ratio and causing the decrease in the proportion of aromatic compounds. Meanwhile, more compounds which contained only C, H, O, N atoms (CHON) were observed after the UV/chlorine AOP compared with dark chlorination via photolysis of organic chloramines or radical reactions. A total of 833 compounds contained C, H, O, Cl atoms (CHOCl) were observed after the UV/chlorine AOP, higher than 789 CHOCl compounds in dark chlorination, and one-chlorine-containing components were the dominant species. The different products from chlorine substitution reactions (SR) and addition reactions (AR) suggested that SR often occurred in the precursors owning higher H/C ratio and AR often occurred in the precursors owning higher aromaticity. Post-chlorination further caused the cleavages of NOM structures into small molecular weight compounds, removed CHON compounds and enhanced the formation of Cl-DBPs. The results provide information about NOM transformation and Cl-DBPs formation at molecular levels in the UV/chlorine AOP.     

板料成形过程数值模拟中的动态接触条件处理

为了解决板料成形过程数值模拟中非线性边界条件问题,本文提出并建立了控制约束的描述方法、接触结点、确定的新方法——垂足法、计算接触应力的剪应力法、以及处理非线性滑动接触边界条件的降阶-摩擦载荷迭代法.经实际模拟计算,证明了这些方法的正确性.     

钢铁联合企业固体废物综合利用分析

阐述了钢铁联合企业固体废物的分类和来源,以柳钢生产实践为例,分析高炉煤气除尘灰、转炉除尘污泥等固体废物的化学成分,探讨冶金固体废物处理方式和综合利用途径,对钢铁企业固体废物综合利用发展方向提出建议。     

Chromosomal and subchromosomal anomalies associated to small for gestational age fetuses with no additional structural anomalies

Objectives: To assess the chromosomal and subchromosomal anomalies in small for gestational age (SGA) fetuses with no additional structural anomalies and their clinical outcomes. Methods: This study retrospectively reviewed the 128 SGA fetuses with no additional anomalies and underwent genetic testing with karyotyping and chromosomal microarray analysis (CMA). Stratified analysis was performed according to the existence of maternal risk factors for SGA (yes or no), gestational age at onset (before or after 32 weeks), presence of oligohydraminos (yes or no), and umbilical artery Doppler flow (normal or abnormal). Results: Chromosomal anomalies were identified in 6 (4.7%) SGA fetuses and pathogenic subchromosomal anomalies in 4 (3.1%) by microarray analysis. Chromosomal and subchromosomal anomalies were more frequently observed in cases with oligohydraminos (P = .017) and with early-onset SGA (P = .042). No differences were observed in relation to the existence of maternal risk factors and abnormal umbilical artery Doppler flow. Overall survival rate was 75.0% with different rates in the early and the late onset group (P < .001). Conclusions: There is a 3.3% incremental yield of subchromosomal anomalies in CMA above karyotyping in SGA fetuses. Chromosomal microarray analysis is recommended in SGA fetuses with no additional structural anomalies, especially coexisting with oligohydraminos and being early onset.     

刚果红的零价铁还原脱色条件及机理研究

零价铁使直接大红4BS还原脱色,其主要机理包括了电化学作用、铁粉的还原作用、铁离子的絮凝吸附作用、铁粉表面的物理吸附等。其中电化学还原与化学还原为主。当铁粉的投加量在2 g/50 ml、pH=3、摇床转速在140 rmp时,5 min内脱色率分别达到了100%、90%和80%以上。结果表明,通过改变染料的pH值、铁粉的投加量和摇床的转速都可以很好地提高脱色效果。     

组合人工湿地工艺微生物群落结构及脱氮效果研究

将复合垂直流、表面流、潜流3种不同类型的人工湿地串联起来,研究每种人工湿地的脱氮微生物及其脱氮效果.结果表明,各种人工湿地池填料表面微生物数量丰富,组合人工湿地系统形成两个串联的A/O单元,脱氮效果良好,其中总氮去除率达82.61%.     

括苍山地区火山构造

括苍山火山岩区是由不同阶段、不同火山机构组成的火山构造组合体。总体的构造格局是隆起和断块。不同旋回具有不同的火山构造组合,同一旋回的火山构造类型也不甚相同。第一旋回是火山喷发一侵入穹窿;第二旋回发育三类破火山口;第三旋回由上叠式火山沉积洼地和破火山口组成;第四旋回主要为较完整的锥火山和小别破火山口。这四个旋问的火山机构呈叠瓦式和复合继承式组合,尤以叠瓦式组合为主。     

地形起伏地区管道水联运充水排气过程分析

针对油气长输管道投产前通常会进行充水清管、调试和吹扫(常规称:水联运),由于埋地管道随地形起伏经过无数个相对高点和低点,管道充水前处于自然状态,一旦管内充水,就会将管内空气归聚成封闭空间,形成多个带压气团随水头移动,时而被压缩,时而被膨胀,从而造成管道断流,影响泵站正常工作,严重的还会导致管道泄压装置受损、爆管事故等问题,分析了管道水联运过程中不同地形起伏高点和低点带压气团的成因和状态,用实例计算了带压气团对管道水联运的影响及排除方法,从而为长输管道投产前正常的水联运作业提供借鉴。     

粉末金属压制过程建模方法(3)--微观力学方法

介绍了建立描述粉末金属压制过程数学模型的难点，详细论述了目前4种主要的建模方法，分析、比较了各种方法的优劣，并对建模工作提出了展望和指导性意见。