隧道掘进爆破振动对围岩影响的HHT分析

为了探究隧道掘进爆破振动信号在围岩等级改变处的传播衰减特性,以新建铁路北京至沈阳客运专线（辽宁段）TJ-1标三棱山隧道为工程背景,采用理论分析与现场试验相结合的方法,基于TC-4850监测试验数据,对爆破质点振速时程曲线进行EMD分解和Hilbert变换。依据测点3个方向的边际谱和瞬时能量谱,分析爆破振动能量在时域和频域的分布规律,进而可以得出各频带的能量百分比以及总能量与距离的关系曲线。通过分析地震波信号沿隧道围岩传播衰减性质可以得出:爆破振动能量在频域上分布具有各向异性,而且在垂直方向上具有数量比例高、所占频带低的特点;隧道掘进爆破振动总能量在围岩等级改变处出现“断崖式”衰减,且在Ⅳ级围岩中相对衰减率更高,衰减更为迅速。     

Aging effect on the mobility and bioavailability of copper in soil

Aging effect on the mobility and bioavailability of copper (Cu) was investigated using a spiked soil with different incubation periods from 3 to 56 d. Wheat was planted and earthworm was cultured separately in the incubated soils. The mobility of Cu in soil was evaluated by a chemical fractionation scheme and the toxicity and bioavailability were assessed by measuring the biomass and Cu concentration in tissues. Results showed that aging had a significant effect on Cu fraction distribution, of which Cu tended to incorporate from the exchangeable into more stable fractions such as the reducible and oxidisable fractions. However, aging had little effect on Cu bioavailability to wheat and earthworms. Comparing the soil being incubated for 3 d and 56 d, Cu concentration in wheat roots decreased from 14.5 to 12.8 mg/kg, and no significant changes in Cu concentration were observed in both wheat shoots and earthworms. The Cu concentration was around 2.0 and 50 mg/kg for wheat shoots and earthworms, respectively, irrespective of soil incubation time. The CaCl2-extractable Cu had a linear relationship with Cu concentration in wheat roots (R2 = 0.65, P < 0.05), but no linear relationship can be found for wheat shoots and earthworms. Biological control may be more crucial for Cu accumulation in organism than the changes in soil Cu fraction caused by aging.     

城市污水二级出水中溶解性有机物特性分析

分别采用凝胶色谱、亲疏水性组分分离、荧光色谱等方法,研究了城市污水处理厂二级出水中溶解性有机物的分子量分布、亲疏水组分含量以及荧光光谱特性。结果表明,二级出水中疏水性组分较亲水性组分多,疏水性组分约占总有机物的64.3%,而亲水性组分占35.7%左右;二级出水及其不同亲/疏水组分中溶解性有机物分子量分布基本集中在4.5 kDa以下,其中弱疏水性组分和亲水性组分中主要为分子量小于1.5 kDa的有机物;二级出水溶解性有机物中含有腐殖酸类、富里酸类以及蛋白质类物质,其中含量以腐殖酸类为主。     

The geostatistic-based spatial distribution variations of soil salts under long-term wastewater irrigation

The purpose of this study was to determine and evaluate the spatial changes in soil salinity by using geostatistical methods. The study focused on the suburb area of Beijing, where urban development led to water shortage and accelerated wastewater reuse to farm irrigation for more than 30 years. The data were then processed by GIS using three different interpolation techniques of ordinary kriging (OK), disjunctive kriging (DK), and universal kriging (UK). The normality test and overall trend analysis were applied for each interpolation technique to select the best fitted model for soil parameters. Results showed that OK was suitable for soil sodium adsorption ratio (SAR) and Na⁺ interpolation; UK was suitable for soil Cl^? and pH; DK was suitable for soil Ca²⁺. The nugget-to-sill ratio was applied to evaluate the effects of structural and stochastic factors. The maps showed that the areas of non-saline soil and slight salinity soil accounted for 6.39 and 93.61 %, respectively. The spatial distribution and accumulation of soil salt were significantly affected by the irrigation probabilities and drainage situation under long-term wastewater irrigation.     

重庆市排污权交易现状分析及对策研究

排污权交易作为一种基于市场的环境经济政策,在环境容量资源配置中发挥着重要作用。重庆市率先在我国西部启动排污权交易试点,进行了有益探索。在对重庆市排污权交易试点现状全面阐述的基础上,提炼出了排污权交易“重庆模式”的六大特点,分析了试点存在的主要问题,研究提出了对策建议。