Nonylphenol photodegradation by novel ternary MIL-100（Fe）/ZnFe2O4/PCN composite under visible light irradiation via double charge transfer process

Nonylphenol（NP） residues, as a typical endocrine disrupting chemical（EDC）, frequently exist in sewage, surface water, groundwater and even drinking water, which poses a serious threat to human health due to its bioaccumulation. In order to remove NP, a series of MIL-100（Fe）/Zn Fe₂O₄/flake-like porous carbon nitride（MIL/ZC） was synthesized through in-situ synthesis at room temperature. High performance of ternary MIL/ZC is used to degrade NP under visible light irradiation. ...     

铁路专用线装卸安全问题AHP分析

铁路专用线装卸安全问题严重影响着专用线的安全运营,对其进行定性定量分析具有重要意义.本文利用层次分析法对某省88条铁路专用线装卸安全存在的问题进行了分析,并采用MATLAB编程计算得到对铁路装卸安全影响较大的因素,以督促企业进行整改,指导企业的安全生产.     

MEA-MDEA-DETA三元复合胺溶液吸收烟气中CO2

采用乙醇胺-N-甲基二乙醇胺-二乙烯三胺(MEA-MDEA-DETA)三元复合胺溶液吸收模拟烟气中CO_2。实验结果表明:MEA-MDEA-DETA 三元复合胺溶液的CO_2吸收速率明显大于DETA溶液和MEA-MDEA复合胺溶液的CO_2吸收速率,但低于DETA溶液与MEA-MDEA复合胺溶液CO_2吸收速率之和;350 mL0.5 mol/L MEA-0.5 mol/L MDEA-0.3 mol/L DETA三元复合胺溶液的CO_2吸收量为0.327 2 mol,小于相同体积0.3 mol/L DETA溶液与0.5 mol/L MEA-0.5 mol/L MDEA复合胺溶液的CO_2吸收量之和;MEA-MDEA-DETA三元复合胺溶液吸收CO_2达到饱和时,溶液pH约为8.0,溶液电位约为-80 mV。MEA-MDEA-DETA三元复合胺溶液吸收CO_2饱和后的再生温度为103℃,一次再生率约为87.5%。     

江苏省农业旅游发展演化研究

发展农业旅游是推动农村经济发展、优化农业产业结构、拓宽农民增收渠道和改善农村生态环境的有效途径。基于已有研究,以439个星级农业旅游景点和102件农业旅游节庆活动为研究变量,运用偏离份额法来动态分析和比较2000—2006年和2006—2012年江苏省农业旅游发展演化状况,结果表明：2000—2012年星级农业旅游景点和农业旅游节庆活动均为推动江苏省农业旅游发展的贡献要素;星级农业旅游景点是地区农业旅游吸引力最重要的内容,对区域农业旅游发展起主导作用,且其贡献率呈不断上升趋势;相对于提升农业旅游竞争力的贡献,农业旅游节庆活动对优化农业旅游资源结构贡献更突出,成为苏中和苏北农业旅游资源富矿区实现农业旅游综合发展的新突破。基于动态偏离份额分析结果,将江苏省农业旅游发展划分为农业旅游优势发展型、农业旅游滞后发展型、农业旅游结构突破型和农业旅游竞争突破型4类。通过类型演化分析得到：2000—2012年江苏省各地农业旅游均有所发展,但地区间农业旅游发展速度存在较大差异,苏北和苏中地区发展相对迅速,后发优势明显,苏南地区发展相对滞后,但仍保持了在全省农业旅游发展中的重心地位。最后,针对江苏省农业旅游发展状况从资源开发、统筹发展、社会参与等方面提出今后提升建议。     

基于主成分分析与Fisher判别分析法的矿井突水水源识别方法

为有效地预防矿井突水事故,及早识别突水水源是关键工作之一。根据矿井各含水层水化学成分的差异性,选取7种水化学成分指标作为突水水源识别的样本变量。在此基础上,采用主成分分析(PCA)与Fisher判别分析相结合的方法建立突水水源判别模型。以新庄孜煤矿不同水层的水化学特征资料中的33个为学习样本,12个为预测样本,对该模型进行检验和应用,并与传统Fisher判别分析模型的结果进行比较。研究结果表明:利用PCA与Fisher突水水源判别模型能够有效地消除样本变量指标间的相互影响,使突水水源判别结果更加准确。     

Factors affecting HCH and DDT in soils around watersheds of Beijing reservoirs,China

The factors that influence the dynamics of hexachlorocyclohexane (HCH) and dichlorodiphenyltrichloroethane (DDT) in soils around the watersheds of Beijing reservoirs were examined. Compared with other studies on HCH and DDT in soils and established reference values, the concentrations of HCH and DDT in soils around our study area were relatively low. The relationships between HCH and DDT concentrations and land use, soil texture, and soil properties were discussed. HCH and DDT concentrations were higher in arable soils than those in uncultivated fallow soils. Although land use was the most important factor affecting HCH and DDT residues, additional factors such as soil texture and soil total organic carbon were also involved in pesticide retention in soils. The results indicated that the historical agricultural applications of HCH and DDT were the major source of their residues. Atmospheric deposition, as well as long-distance transportation and inputs from surrounding weathered agricultural soils may also serve as important sources of HCH and DDT residues in the watersheds.     

Photolytical property of L(+)-α-phenylglycine in aqueous solution

A wide range of pharmaceutical compounds have been identified in the environment, and their existence is a topic of growing concern, both for human and ecological health. The work described here has investigated the photolytic properties of L(+)-α-phenylglycine (L-α-PG-H) in aqueous solution as it can be degraded by photo-catalysis. In 266 nm laser flash photolysis of aqueous solution of L-α-PG-H saturated with nitrogen, two transient absorption bands are observed at 280–330 nm and 450–800 nm, respectively, due to L-α-PG-H radical cation and hydrated electrons (e_aq⁻). Then e_aq⁻ reacts with L-α-PG-H to form the L-α-PG-H radical anion. Decaying rate constants of e_aq⁻ observed at 720 nm is to be 8.9 × 10⁸ dm³ mol⁻¹ s⁻¹. The rate constant for oxidation of L-α-PG-H by SO₄ ⁻ is calculated as 4.5 × 10⁸ and 4.3 × 10⁸ s⁻¹ mol⁻¹ dm³, respectively. The dissociation constants (pKa) of L-α-PG-H is 3. Excited triplet of L-α-PG-H in solution is formed by laser flash photolysis. The quench rate constant of L-α-PG-H excited triplet (k _s) is determined to be 1.3 × 10⁷ dm³ mol⁻¹ s⁻¹ and k ₀ is equal to 1.7 × 10⁵ s⁻¹.     

高压输电线路抗冰灾的研究现状与发展趋势

从导地线和输电塔的覆冰模型、覆冰断线倒塔破坏机理、覆冰气象条件下塔-线体系可靠性等方面,全面分析了高压输电塔-线体系抗冰灾的研究现状和发展趋势,系统总结了国内外有关高压输电线路抗冰灾的研究成果。指出了目前高压输电塔-线体系抗冰灾研究中存在的问题和不足,具体从导地线和输电塔的覆冰模型、覆冰断线冲击的动力学分析理论、模型实验和数值模拟方法、塔-线体系覆冰可靠性等方面提出了当前迫切需要进行研究的内容与方向,以揭示高压输电线路覆冰断线以及倒塔破坏的机理,增强抵抗冰荷载灾害性破坏的能力及完善高压架空输电线路设计的标准。     

论如何加强自然保护区的管理--以新疆奇台荒漠类草地自然保护区为例

随着我国经济的高速发展,经济活动也开始向自然保护区延伸,这就必然导致各种破坏自然保护区的现象不断出现。因此,加强自然保护区依法严格的科学管护,刻不容缓。     

反向工程在工业领域的研究和应用

此文对反向工程的概念和特点进行了阐述,对它在工业领域的研究现状及其有关应用进行了论述,并提出了今后的研究方向和难点内容。