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71.
为探究露天矿不同高度边坡卸荷破坏模式的异同,以辽宁鞍山大孤山铁矿某岩质边坡为背景,利用边坡岩体内优势裂隙组产状、迹长和密度等随机分布参数,构建与边坡结构面具有相似分布规律的二维网络模型,借助PFC数值计算软件,探讨不同开采水平下坡体位移场和裂隙发展的时空演化规律以及边坡的破坏模式。研究结果表明:在边坡开挖过程中,出现的裂隙以张拉裂隙为主;裂隙主要出现在靠近坡面一定范围内,从坡面向里,裂隙数量减小,裂隙初始出现在坡脚区域,而后向坡顶发展;边坡开挖后,水平位移由负变为正,且突然增大,而后呈现阶跃型增长;边坡水平和竖向位移最大值发生在坡脚区域和靠近坡面位置,远离坡面,位移逐渐减小。 相似文献
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Aihua Zhang Shihao Fang Huan Xi Jianke Huang Yongfu Li Guangyuan Ma Jianfeng Zhang 《Frontiers of Environmental Science & Engineering》2023,17(10):120
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电流密度对BDD电极电化学矿化吲哚的影响与机制 总被引:1,自引:1,他引:1
掺硼金刚石膜(BDD)电极电化学氧化法是去除难降解有机污染物的有效手段.与总有机碳(TOC)等的测定相比,气态中间产物的逸出量能够更直观有效地反映有机物的矿化程度与去除效果.本研究以吲哚为代表性污染物,通过对比不同电流密度(10、20和30 m A·cm-2)下BDD电极对吲哚的去除率与矿化率,结合降解过程中碳和氮形态的变化与守恒情况,分析吲哚的降解机制.结果表明,BDD电极对吲哚有良好的去除效果,电流密度为10、20、30 m A·cm-2时,吲哚达到100%去除的时间分别为8、5和4 h;TOC去除率、CO_2产生量均随电流密度的增加而增大,证明矿化率与电流密度成正相关;电解产生的CO_2气体与TOC、无机碳(TIC)构成了碳守恒体系.4~5 h时,体系TOC、TON和CO_2产生量均没有变化,表明电解产生的靛红具有较高的稳定性,此时为中间产物积累阶段;XPS表征进一步证实了中间产物靛红、苯醌等在电极表面的吸附,随着电解时间的延长,这些吸附的中间产物可进一步被降解.本研究从气态产物检测及碳氮形态分析与守恒的角度阐释吲哚矿化过程,对于辅助揭示有机物的电解过程有重要意义. 相似文献
74.
Zhao Chuanyu Wang Wanyue Wen Haoxuan Huang Zenghui Wang Xiaodie Jiao Kuizhuang Chen Qihao Feng Huan Wang Yizhe Liao Jingling Ma Lu 《Environmental science and pollution research international》2023,30(6):14402-14412
Environmental Science and Pollution Research - Increasing research suggested that green spaces are associated with many health benefits, but evidence for the quantitative relationship between green... 相似文献
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Bing PEI Hongyang CUI Huan LIU Naiqiang YAN 《Frontiers of Environmental Science & Engineering》2016,10(3):559-568
The chemical characteristics of fine particulate matter (PM2.5) emitted from commercial cooking were explored in this study. Three typical commercial restaurants in Shanghai, i.e., a Shanghai-style one (SHS), a Sichuan-style one (SCS) and an Italian-style one (ITS), were selected to conduct PM2.5 sampling. Particulate organic matter (POM) was found to be the predominant contributor to cooking-related PM2.5 mass in all the tested restaurants, with a proportion of 69.1% to 77.1%. Specifically, 80 trace organic compounds were identified and quantified by gas chromatography/mass spectrometry (GC/MS), which accounted for 3.8%–6.5% of the total PM2.5 mass. Among the quantified organic compounds, unsaturated fatty acids had the highest concentration, followed by saturated fatty acids. Comparatively, the impacts of other kinds of organic compounds were much smaller. Oleic acid was the most abundant single species in both SCS and ITS. However, in the case of SHS, linoleic acid was the richest one. ITS produced a much larger mass fraction of most organic species in POM than the two Chinese cooking styles except for monosaccharide anhydrides and sterols. The results of this study could be utilized to explore the contribution of cooking emissions to PM2.5 pollution and to develop the emission inventory of PM2.5 from cooking, which could then help the policymakers design efficient treatment measures and control strategies on cooking emissions in the future. 相似文献
77.
Huan HE Qian SUI Shuguang LU Wentao ZHAO Zhaofu QIU Gang YU 《Frontiers of Environmental Science & Engineering》2015,9(6):962-969
The influence of three effluent organic matter (EfOM) model compounds, humic acid (HA), bovine serum albumin (BSA), and sodium alginate (AGS), on the ozonation of bezafibrate (BF), a typical pharmaceutical and personal care product (PPCP), was investigated. The results show that ozonation efficiently removed BF from aqueous solution with removal efficiencies>95% within 8 min for all conditions. The reaction rate of BF decreased with increasing model compounds concentrations and the influence was more pronounced for HA and BSA, while less pronounced for AGS. Although BF concentration was significantly reduced, the degree of mineralization achieved was only approximately 11%. The addition of HA and BSA improved the mineralization of the solution, while the influence of AGS was minor. The acute toxicity of BF solution during ozonation was determined using the Luminescent bacteria test, and the toxicity exhibited an initial increase and a successive reduction. An overall decreased acute toxicity was observed with an increase of HA. The presence of BSA increased the formation rate of toxicity intermediates and resulted in inhibition peak forward. 相似文献
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以北京南部城市发展新区典型代表———房山、大兴、通州3处作为研究区,运用马尔科夫转移矩阵和景观格局指数的方法,进行土地利用变化和景观格局分析。通过对2001—2006年、2006—2011年两个时段的对比分析,发现2001—2006年研究区存在草地、林地、耕地等非建设用地类型面积下降,建设用地面积上升的趋势,且2006—2011年该趋势更加明显。结果表明研究区自然景观向人文景观变革迅速,并面临着后备土地资源不足等问题,亟需调整土地利用方式并优化景观系统空间格局。 相似文献