The effect of fluorescent tracers on droplet spectrum,viscosity, and density of pesticide formulations

The most important factor affecting efficacy and drift of pesticide applications is the droplet spectrum. To measure pesticide drift, researchers utilize fluorescent tracers to rapidly quantify spray deposition. Although fluorescent tracers have been used for more than 50 years, no experiments have been performed on the effect they have on the properties of pesticide formulations (density and viscosity) or droplet spectrum, which affect the drift of pesticides. Therefore, we examined the effect of an oil- and water-based tracer on the volume median diameter (VMD), viscosity, and density of oil- and water-based pesticide formulations. In addition, we experimentally fit and demonstrate the utility of using distributions to characterize pesticide droplet spectra. The addition of tracers to both water- and oil-based formulations did not significantly alter the VMD, viscosity, and density. Lognormal distributions provided the best fit for the water- and oil-based formulations with and without tracer. Our results demonstrated that the addition of oil- and water-based tracers do not significantly alter pesticide formulations properties and droplet spectrum, and most likely do not alter the movement of pesticide droplets in the environment.     

An environmental assessment of a small shallow lake (Little Black Lake, MI) threatened by urbanization

A limnological survey was conducted of Little Black Lake, MI, and its tributaries during summer 2007. This small, shallow lake is located in a rapidly developing area of west Michigan. As such, our analytical approach and recommendations can serve as a model for other similar systems threatened by urbanization. Soluble reactive phosphorus and nitrate concentrations in both the inflows to (during baseflow) and Little Black Lake itself were low (??0.007 and ??270 mg/L, respectively). Nutrient concentrations increased during stormflow conditions, although the magnitude of the increase depended on the nutrient and sampling location. Macrophyte growth was extensive throughout most parts of the lake, with Chara and Potamogeton spp. present in most sites; based on the coefficient of conservatism, plant composition was indicative of good water quality conditions. Chlorophyll a concentration averaged 1.7 ??g/L in Little Black Lake, with cryptophytes and cyanobacteria being the most dominant members (by biovolume) of the phytoplankton community. The fish community in Little Black Lake was dominated by bluegill (Lepomis macrochirus) and pumpkinseed (L. gibbosus), with no invasive species observed. Overall, abiotic and biotic conditions indicate that Little Black Lake is in good ecological health despite increasing pressures of urbanization in its watershed. To maintain this status, it is recommended that the local municipalities develop a comprehensive watershed management plan and implement best management practices to limit nonpoint source pollutant loading to Little Black Lake.     

Effects of Temperature and Relative Humidity on Polylactic Acid Plastic Degradation

Three high molecular weight (120,000 to 200,000 g mol^–1) polylactic acid (PLA) plastic films from Chronopol (Ch-I) and Cargill Dow Polymers (GII and Ca-I) were analyzed for their degradation under various temperature and relative humidity (RH) conditions. Two sets of plastic films, each containing 11 samples, were randomly hung in a temperature/humidity-controlled chamber by means of plastic-coated paper clips. The tested conditions were 28, 40, and 55°C at 50 and 100% RH, respectively, and 55°C at 10% RH. The three tested PLA films started to lose their tensile properties when their weight-average molecular weight (M _w) was in the range of 50,000 to 75,000 g mol^–1. The average degradation rate of Ch-I, GII, and Ca-I was 28,931, 27,361, and 63,025 M _w/week, respectively. Hence, GII had a faster degradation rate than Ch-I and Ca-I under all tested conditions. The degradation rate of PLA plastics was enhanced by the increase in temperature and relative humidity. This trend was observed in all three PLA plastics (Ca-I, GII, and Ch-I). Of the three tested films, Ch-I was the first to lose its mechanical properties, whereas Ca-I demonstrated the slowest loss, with mechanical properties under all tested conditions.     

Microtox assay to determine the toxicity of degradation products from degradable plastics

Six types of starch-polyethylene degradable plastics were evaluated for the release of water-soluble toxic compounds under accelerated degradation conditions. A plastic strip (2.5×15.2 cm) was placed in a 250-ml Erlenmeyer flask with 100 ml of ASTM type I water with or without trace element solutions and shaken at 65°C and 110 rpm for 20 weeks in replicates of two. High temperature was used to accelerate the oxidative degradation of polyethylene. Plastic degradation was measured by loss of tensile strength, percentage elongation, strain energy, and weight-average molecular weight. The most rapid period of polyethylene thermal degradation was complete for most materials by day 28. Ten-milliliter aqueous samples were removed from each flask at days 1, 7, 28, 56, 84, and 140 (water volumes were maintained at 100 ml with fresh type I water), filtered through glass filters, then evaluated by using the Microtox Toxicity Analyzer (Microbics Corporation, Carlsbad, CA). No water-soluble toxic compounds were detected during the period of rapid film degradation. Toxicity was observed at day 28 for one film and at day 84 for all films, which could possibly correlate with the release of small oxidative compounds such as formaldehyde and acetaldehyde. Because of the sensitivity of this assay, positive results must be confirmed by otherin vitro studies.Journal Paper No. J-14851 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa. Projects No. 2889 and 0178.     

Comparing theoretical and actual feasibility of transferring management of river lift irrigation systems in Sudan

This article focuses on agricultural production in lift irrigation schemes along the White Nile in the Sudan. A comparison is drawn between the theoretical forecast and actual practical experience regarding the feasibility of transferring management from government-run parastatal organizations to private farmer organizations. Although the theoretical model indicates that farmers should be able to cover the cost of managing the river lift irrigation systems, field data show, however, that farmers growing wheat are barely able to break even. Even assuming a doubling of the present wheat yields, the cash surplus earned would only suffice for fuel to operate the pumps. Under these circumstances, it is not surprising that, contrary to government expectations, the private sector has been unenthusiastic about taking over management of White Nile river lift schemes. The lessons that emerge from this study indicate that unplanned and rapid withdrawal of state management can lead to negative results. The transfer of management responsibility for the river pumps does not appear to influence economic performance considerably, which depends on the wider context of the country's economic, political and institutional environment, within which the agricultural sector functions.     

Degradation studies of novel degradable starch-polyethylene plastics containing oxidized polyethylene and prooxidant

Linear low-density polyethylene films were prepared that contained native corn starch (7, 14, or 28%), low or high molecular weight oxidized polyethylene (15%), and a prooxidant mixture (18% POLYCLEAN II) that contains manganese and vegetable oil. For each mixture all components were first mixed at high temperatures in a twin-screw extruder and pelletized. The pellets were cast into films using a single-screw extruder. Oxidized-polyethylene addition did not impair the transparency and thickness of the films and did not reduce the percentage elongation, whereas significant reductions in film mechanical properties were observed. Thermal and photodegradation properties of each film were evaluated by 70°C forced-air oven treatment (20 days), by high-temperature, high-humidity treatment in a steam chamber (20 days), and by exposure to ultraviolet light (365 nm; 4 weeks). Changes in the mechanical properties of the films were determined by an Instron Universal Test Machine; in the carbonyl index, Fourier transform infrared spectroscopy; and in molecular weight, by high-temperature gel-permeation chromatography (HT-GPC). The addition of oxidized polyethylene, especially high molecular weight oxidized polyethylene, and up to 14% starch to the films significantly increased the rate of thermal and photodegradation.Journal Paper No. J-15363 of the Iowa Agriculture and Home Economics Experiment Station, Ames. Project No. 0178 and 2889.     

A first alternative for estimating the physical carrying capacities of natural areas for recreation

Utilizing an adaptation of the Universal Soil Loss Equation, this article discusses a method for approximating the physical carrying capacity of natural areas for outdoor recreation. Classification of forested woodland and field environments is based upon the conversion of ground cover coefficients to the percentage of ground cover required to maintain soil productivity over time. Four canopy types, three canopy densities, and two general types of ground cover are recognized in the equation as well as soil characteristics, topographical variations, and rainfall velocities and intensities. The method requires that the areal distribution of soils occurring within natural areas be mapped. Approximations will vary according to the intensity of the planning desired, and may range from a general classification of large land areas to highly site-specific evaluations. Data generated from over 40 years of cooperative research form the basis for classifying natural areas according to their relative physical capacities to accommodate outdoor recreation.     

A GEOGRAPHICAL ANALYSIS OF VOTING PATTERNS FOR WATER RELATED CONSTITUTIONAL AMENDMENTS IN TEXAS, 1957-19811

ABSTRACT: Country level electoral data were used to analyze the voting patterns of eight water related constitutional amendment elections. Both water quality enhancement amendments (1971, 1976), and three of six water development amendments (1957, 1962, 1966) have been ratified, thus establishing a statewide policy of reservoir development, a funding mechanism to implement such a policy, and the creation of a water management agency. Begining with the 1969 election, a West Texas-East Texas regionalized voting pattern has emerged, resulting in the defeat of three amendments (1969, 1976, 1981) intended to provide additional funding for water development. This regionalization reflects different climatic, physiographic, economic, and locational factors, and represents a potential obstacle to coordinated water management in Texas.     

Cognitive and motivational frameworks in U.S. research on participation: a meta-analysis of primary effects

In this paper we classify 86 published studies of participation conducted in the U.S. according to whether they are based on cognitive or motivational conceptual frameworks, then conduct a meta-analysis of 124 correlation coefficients obtained from them to determine whether distinguishing between conceptual frameworks portends differences in the findings of U.S. research on the effects of participatory processes on performance and satisfaction. Results reveal noticeable differences in the findings of participation–satisfaction research, but also indicate that these differences diminish substantially upon elimination of research based on single-source self-reports. If interpreted as evidence of percept–percept inflation, these findings are wholly consistent with those of other recent analyses. If interpreted as evidence of the greater accuracy of self-report measures of intra-psychic phenomena, they suggest that research on the relationship between participation and satisfaction has been influenced by the conceptual frameworks used to design studies and formulate conclusions. © 1997 John Wiley & Sons, Ltd.