Validation of predicted exponential concentration profiles of chemicals in soils

Multimedia mass balance models assume well-mixed homogeneous compartments. Particularly for soils, this does not correspond to reality, which results in potentially large uncertainties in estimates of transport fluxes from soils. A theoretically expected exponential decrease model of chemical concentrations with depth has been proposed, but hardly tested against empirical data. In this paper, we explored the correspondence between theoretically predicted soil concentration profiles and 84 field measured profiles. In most cases, chemical concentrations in soils appear to decline exponentially with depth, and values for the chemical specific soil penetration depth (d(p)) are predicted within one order of magnitude. Over all, the reliability of multimedia models will improve when they account for depth-dependent soil concentrations, so we recommend to take into account the described theoretical exponential decrease model of chemical concentrations with depth in chemical fate studies. In this model the d(p)-values should estimated be either based on local conditions or on a fixed d(p)-value, which we recommend to be 10cm for chemicals with a log K(ow)>3.     

Photocatalytic degradation of trinitrotoluene and other nitroaromatic compounds

The photocatalytic degradation of 2,4,6-trinitrotoluene and ten other nitroaromatic compounds in aerated TiO₂ suspensions has been studied. The following order of reactivity was observed: nitrotoluenes > nitrobenzene > dinitrotoluenes . dinitrobenzenes > 2,4,6-trinitrotoluene > 1,3,5-trinitrobenzene, which reflects the known influence of nitro groups towards the attack of electrophilic reagents on the aromatic molecule.     

Disinfection of surfaces by photocatalytic oxidation with titanium dioxide and UVA light

Particularly in microbiological laboratories and areas in intensive medical use, regular and thorough disinfection of surfaces is required in order to reduce the numbers of bacteria and to prevent bacterial transmission. The conventional methods of disinfection with wiping are not effective in the longer term, cannot be standardized, are time- and staff-intensive and use aggressive chemicals. Disinfection with hard ultraviolet C (UVC) light is usually not satisfactory, as the depth of penetration is inadequate and there are occupational medicine risks. Photocatalytic oxidation on surfaces coated with titanium dioxide (TiO2) might offer a possible alternative. In the presence of water and oxygen, highly reactive OH-radicals are generated by TiO2 and mild ultraviolet A (UVA). These radicals are able to destroy bacteria, and may therefore be effective in reducing bacterial contamination. Direct irradiation with UVC however can produce areas of shadow in which bacteria are not inactivated. Using targeted light guidance and a light-guiding sheet (out of a UVA-transmittant, Plexiglas, for example), as in the method described in the present study, bacterial inactivation over the entire area is possible. The effectiveness of the method was demonstrated using bacteria relevant to hygiene such as Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Enterococcus faecium. For these bacteria, a reduction efficiency (RE) more than 6log10 steps in 60 min was observed. Using Candida albicans, a RE of 2log10 steps in 60 min was seen. Light and scanning electron microscopic examinations suggest that the germ destruction achieved takes place through direct damage to cell walls caused by OH-radicals.     

Nachhaltigkeit in der Pflanzenproduktion

Zusammenfassung  Teil I gibt einen überblick über den Ursprung und die Entwicklung des Begriffes “Nachhaltigkeit” im allgemeinen und für die Landwirtschaft im speziellen. Demnach wird Nachhaltigkeit zwar unter ?kologischen, sozialen und ?konomischen Aspekten diskutiert; eine allgemein anerkannte Definition des Begriffes existiert bisher jedoch weder für die jeweiligen Einzelaspekte noch unter Zusammenführung aller drei Aspekte. Dies erschwert die Ermittlung und Umsetzung der Nachhaltigkeit in der Praxis. Ausgehend von der Begriffsentwicklung und den wesentlichen heute definierten Begriffsinhalten wird deshalb für eine nachhaltige Pflanzenproduktion aus prim?r ?kologischer Sicht eine Definition vorgeschlagen. Sie dient als Grundlage für einen methodischen Ansatz, der eine Operationalisierung und damit eine Umsetzung der Nachhaltigkeit der Pflanzenproduktion in der Praxis erm?glichen soll (?Teil II).      

Risk and mitigation of self-heating and spontaneous combustion in underground coal storage

While the self-heating and spontaneous combustion of coal is a known challenge at coal mines and storage sites, there are known methods for mitigating this challenge for typical open stockpile storage. However, closing the storage will reduce access for corrective action, and it is then important to manage the storage and its transport system with added attention without unduly adding cost or hindering availability. This paper aims to discuss the risk, prevention and extinguishing of fires in closed coal storage facilities, particularly in light of the experience with the Salmisaari underground rock storage facility in Finland. The observed autoignition events have indicated an array of contributing factors, some of which are unique to underground silo storage facilities. On the other hand, many features of the storage facilities can be compared with other extant closed storage systems. The factors affecting fire risk are described and the associated fault and event trees are outlined for autoignition at underground storage. Drawing upon the experiences with past events of self-heating and spontaneous combustion, recommendations are given on cost-effective preventive, corrective and other mitigating action for minimising fire risk and promoting storage availability.     

Sustainable Food Consumption: Exploring the Consumer “Attitude – Behavioral Intention” Gap

Although public interest in sustainability increases and consumer attitudes are mainly positive, behavioral patterns are not univocally consistent with attitudes. This study investigates the presumed gap between favorable attitude towards sustainable behavior and behavioral intention to purchase sustainable food products. The impact of involvement, perceived availability, certainty, perceived consumer effectiveness (PCE), values, and social norms on consumers’ attitudes and intentions towards sustainable food products is analyzed. The empirical research builds on a survey with a sample of 456 young consumers, using a questionnaire and an experimental design with manipulation of key constructs through showing advertisements for sustainable dairy. Involvement with sustainability, certainty, and PCE have a significant positive impact on attitude towards buying sustainable dairy products, which in turn correlates strongly with intention to buy. Low perceived availability of sustainable products explains why intentions to buy remain low, although attitudes might be positive. On the reverse side, experiencing social pressure from peers (social norm) explains intentions to buy, despite rather negative personal attitudes. This study shows that more sustainable and ethical food consumption can be stimulated through raising involvement, PCE, certainty, social norms, and perceived availability.