A comparative study of modified and unmodified maize tassels for removal of selected trace metals in contaminated water

Powdered maize tassels were studied and found to exhibit metal sorption properties due to the availability of functional groups. The tassels have a high amount of soluble organic substances that can dissolve in aqueous media, contributing to secondary pollution during a water treatment process. A chelating agent was chemically attached on the maize tassels with a view to increase the sorption capacity, minimize leaching, and enhance the tassels’ stability. Thermogravimetric analysis confirmed that modification improved their thermal stability to withstand temperatures above 600°C as well as reduced the “secondary pollution”. The modified sorbent was employed for the sorption of lead, copper, and cadmium ions in both the model solutions and the real samples. The contact time and pH were optimized after which Langmuir and Freundlich isotherms were applied to the data. The sorption capacities for Cu²⁺, Cd²⁺, and Pb²⁺ improved from 3.4, 0.8, and 1.7?g?kg^?1, respectively, to 6.3, 2.6, and 2.6?g?kg^?1 in the same order. The sorbent was shown to remove up to 95% of the metals in less than 10 min. This study has a potential application for the remediation of polluted waters.     

A proposal for environmental indicators towards industrial building sustainable assessment

The construction sector carries out a very important role in the development of society. It is a basic component of economic activity, having a great influence on employment generation and country growth. The sector generates appreciable environmental changes and effects throughout the planet, leading to gradual exhaustion of natural resources and contamination of basic elements, such as air, water and soil. Recently, there have been advances in favour of more environmentally friendly buildings. Basically, sustainable construction has centred on residential and office buildings. It could be said that there is a lack of sustainability in the construction of industrial buildings, as they present characteristics which differ from other building typologies. This article aims to assess and analyze industrial building environmental effects, and considers a set of green study criteria, such as: location, materials, energy and water consumption, construction and deconstruction characteristics, and waste management in industrial building. At the same time, the studies are hierarchically structured into different assessment elements, such as: criteria, subcriteria and, finally, indicators, comprising the assessment model.     

WATER QUALITY IN AGRICULTURAL WATERSHEDS: IMPACT OF RIPARIAN VEGETATION DURING BASE FLOW1

ABSTRACT: Water quality was monitored for 17 months during base flow periods in six agricultural watersheds to evaluate the impact of riparian vegetation on suspended solids and nutrient concentrations. In areas without riparian vegetation, both instream algal production and seasonal low flows appeared to be major determinants of suspended solids, turbidity, and phosphorus concentrations. Peak levels of all parameters were reached during the summer when flows were reduced and benthic algal production was high. Similar summer peaks were reached in streams receiving major point inputs but peaks occurred downstream from the input. Instream organic production was less important in regulating water quality in areas with riparian vegetation and permanent flows. Concentrations of suspended solids remained relatively constant, while phosphorus and turbidity increased in association with leaf fall in autumn. Intermittent flow conditions in summer increased the importance of instream organic production in controlling water quality, even when riparian vegetation was present. Efforts to improve water quality in agricultural watersheds during base flow should emphasize maintenance of riparian vegetation and stable flow conditions.     

FLOODPLAIN ANALYSIS,SIMPLIFIED VS. COMPLEX METHODS: A CASE STUDY1

ABSTRACT: The accurate and reliable determination of floodplains, floodway boundaries, and flood water elevations are integral requirements of Flood Insurance Studies. These studies are intended to be used for determining the flood insurance rates. Therefore, the accuracy of the water surface profiles are important. To ensure the high degree of accuracy, the HUD Flood Insurance Administration has developed standards which must be met in the analysis of water surface profiles. A somewhat less accurate study is required for the preparation of Flood Emergency Plans. As part of the flood insurance studies of eight locations in the State of North Dakota, various flood hazard and floodplain information reports were reviewed. The hydrologic and hydraulic analyses, especially the computation of the 100-year water surface profiles, were completed using both simplified and complex hydraulic computation methods. Significant differences were found (1 to 3 feet) between the profiles computed by the SCS simplified method and those computed by HEC-2 computer program. However, the floodplain boundaries determined by both methods were found to be similar. Approximate methods are recommended for rapid determination of the floodplain, floodway boundaries, and inundation area mapping, while sophisticated computer programs (HEC-2) are recommended to be used for developing areas where the 100-year flood elevation has a significant impact on the cost of land development.     

Explosion temperatures and pressures of metals and other elemental dust clouds

The Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) conducted a study of the explosibility of various metals and other elemental dusts, with a focus on the experimental explosion temperatures. The data are useful for understanding the basics of dust cloud combustion, as well as for evaluating explosion hazards in the minerals and metals processing industries. The dusts studied included boron, carbon, magnesium, aluminum, silicon, sulfur, titanium, chromium, iron, nickel, copper, zinc, niobium, molybdenum, tin, hafnium, tantalum, tungsten, and lead. The dusts were chosen to cover a wide range of physical properties—from the more volatile materials such as magnesium, aluminum, sulfur, and zinc to the highly “refractory” elements such as carbon, niobium, molybdenum, tantalum, and tungsten. These flammability studies were conducted in a 20-L chamber, using strong pyrotechnic ignitors. A unique multiwavelength infrared pyrometer was used to measure the temperatures. For the elemental dusts studied, all ignited and burned as air-dispersed dust clouds except for nickel, copper, molybdenum, and lead. The measured maximum explosion temperatures ranged from 1550 K for tin and tungsten powders to 2800 K for aluminum, magnesium, and titanium powders. The measured temperatures are compared to the calculated, adiabatic flame temperatures.     

Application of the DPSIR framework to environmental degradation assessment in northern Ghana

In many communities in northern Ghana, the environment has been altered by complex natural and human driven forces with significant impact on the lives of their inhabitants. The need to formulate an improved, holistic and consistent methodological approach to assess the problem is critical for sustainable natural resource management. This paper examines the potential of the DPSIR environmental assessment framework utilizing GIS‐based participatory methodology in the assessment of environmental degradation in northern Ghana. Community truthing tools such as key informant interviews, focus group discussions, participant observation and participatory Geographical Information Systems (GIS) were employed as a means of soliciting societal responses integrated to conventional GIS spatial analysis to measure the indicators of the Driving force–Pressure–State–Impacts–Response (DPSIR) assessment framework. Post classification GIS imagery results show a marked natural vegetation decrease of 634 km2 (42%) of the study area with a corresponding increase of 600 km² (39%) of grasses and built‐up and barren environment in the period of 14 years from 1990 to 2004. This is attributed to extreme climatic conditions and human driven causes such as poverty, population growth, migration and land tenure system. Poverty reduction strategies, amendment of the Mining and Mineral Law (PNDC law 153), improvement of the existing land tenure system and the control of migrants and Fulani herdsmen from neighbouring Burkina Faso were some of the solutions selected by the research participants, to be emphasized in the National Environmental Action Plan (EPA Act 490). This paper concludes that the DPSIR environmental assessment framework is an effective means of organizing complex environmental information to facilitate policy decision making.     

Tubular electrostatic precipitators of two-stage design

Although the “two stage” electrostatic precipitator concept was first developed in 1910, until recently most of their use was confined to in-plant air cleaning. In the last decade, plate type designs have been modified to make them suitable for industrial applications involving organic emissions, most notably in asphalt saturating, plastic curing, food processing, printing, textile finishing, and heat treating industries. However, plate type designs are inadequate in applications where very high loading and/or high particulate content are involved.Tubular design with wider spacing and higher voltages incorporates the best features of both the single stage and two stage type precipitators. These units have been used in molybdenum roasting, zirconium calcining, ammonia scrubbing of oxides of sulfur, meat broiling, foundry exhaust, etc.The paper discusses design parameters, field test data, and operating data on these units. Comparisons with single-stage type precipitators are made wherever applicable. Advantages and disadvantages of two stage precipitators are also discussed.     

Disclosure of stigmatized identities at work: An interdisciplinary review and agenda for future research

This review focuses on the disclosure decisions faced by employees with concealable stigmatized identities—one of the most challenging decisions these individuals must make on a day-to-day basis. Indeed, multiple theoretical frameworks have provided a foundation for understanding the antecedents and outcomes associated with the decision to disclose or not to disclose a stigmatized identity. What is less clear, however, is the extent to which these frameworks have been empirically supported. This systematic review serves to unify the extant literature and prompt continued research related to employees with concealable stigmatized identities. Specifically, we draw upon multiple fields of study, including applied psychology, management, social psychology, and occupational health as a means to systematically synthesize the existing empirical research related to disclosure of stigmatized identities at work. In addition to advancing the scholarly knowledge of disclosure, this review also provides practical utility to organizations as they continue to create work environments that foster inclusion of all stigmatized and nonstigmatized employees.     

The unusual suspects? Perception of underlying causes of anthropogenic climate change in coastal communities in Cambodia and Tanzania

Public perception of the underlying causes of anthropogenic climate change is a complex and subjective issue that is critical to effective risk communication. This issue is important to scientists and policymakers because of the role of individual perceptions in influencing their protective behaviour towards risk (e.g., the adoption of climate risk reduction and mitigation strategies). This cross-sectional study elucidated people's perceptions of the underlying causes of human-induced climate change in coastal communities in Cambodia and Tanzania. The multinomial logistic regression model was based on a geographically and demographically stratified national sample of 3,706 individuals conducted between March and September 2013. The distribution of the fundamental causes of anthropogenic climate change in the pooled sample was deforestation (29%), overpopulation – births and immigration (18%), greenhouse gas emissions (12%), illegal resource extraction (14%), and God's will and transgressing cultural norms (26%). Few people in both countries believed that, the usual suspect, greenhouse gas emission was the fundamental cause of anthropogenic climate change. The number of poor rural residents who indicated that deforestation was the major underlying cause of climate change was approximately three times more than members of the same sub-group who noted that greenhouse gas emissions were the underlying cause of climate change. People who had tertiary education were less likely to consider God's will and transgressing cultural norms as the underlying cause of anthropogenic climate change rather than attributing it to greenhouse gas emissions. Therefore, it is imperative to mainstream climate change into educational curricula in both countries.     

Surface and subsurface water quality appraisal for irrigation

Use of irrigation water available from various sources in agriculture is justified on agronomic and economic grounds but care must be taken to minimize its adverse environmental and health impacts. During the study 44 water samples, available from the various resources viz., canal, sewage pipe line, tube wells in confined aquifers, tube wells in unconfined aquifers, and wells in the Chaka block district Allahabad, were chemically analyzed to check its suitability for irrigation and to classify it according to amount of salts present. The analysis reveals that most of the samples were within the lower alkalinity limit (pH 7.17–8.42), except sewage water (pH 7.34–9.04). The electrical conductivity of the samples ranged from 0.26 to 1.37 millimhos/cm. Potassium, sodium, calcium, and phosphorus are all found to be in permissible range except one sample in the village Kuria in which Na percentage was found in doubtful category. The other parameters like sodium adsorption ratio, SAR (1.17–2.74), residual sodium carbonate, RSC (?4.46 to ?1.07), and soluble sodium percentage, SSP (63.97–28.15) were also found below the permissible limit.