全文获取类型
收费全文 | 435篇 |
免费 | 4篇 |
国内免费 | 4篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 29篇 |
环保管理 | 43篇 |
综合类 | 58篇 |
基础理论 | 83篇 |
环境理论 | 1篇 |
污染及防治 | 153篇 |
评价与监测 | 41篇 |
社会与环境 | 27篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 4篇 |
2022年 | 18篇 |
2021年 | 15篇 |
2020年 | 8篇 |
2019年 | 10篇 |
2018年 | 24篇 |
2017年 | 15篇 |
2016年 | 21篇 |
2015年 | 21篇 |
2014年 | 23篇 |
2013年 | 35篇 |
2012年 | 30篇 |
2011年 | 40篇 |
2010年 | 25篇 |
2009年 | 19篇 |
2008年 | 24篇 |
2007年 | 30篇 |
2006年 | 12篇 |
2005年 | 19篇 |
2004年 | 10篇 |
2003年 | 6篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 7篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1989年 | 1篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有443条查询结果,搜索用时 46 毫秒
61.
Study on the toxicity of binary equitoxic mixtures of metals using the luminescent bacteria Vibrio fischeri as a biological target 总被引:3,自引:0,他引:3
Results from two mathematical approaches to predict the toxicity of all the possible binary equitoxic mixtures of Co, Cd, Cu, Zn and Pb were compared to the observed toxicity of these mixtures to Vibrio fischeri bacteria. Combined effect of the metals was found to be antagonistic for Co-Cd, Cd-Zn, Cd-Pb and Cu-Pb, synergistic for Co-Cu and Zn-Pb and merely additive in other cases, revealing a complex pattern of possible interactions. Besides, Cd appears much less toxic to the bacterial model than to animal cells. The synergistic effect of the Co-Cu combination and the strong lowering of Pb toxicity in the presence of Cd deserve much attention when establishing environmental safety regulations. 相似文献
62.
63.
Joseph M. Wunderle Jr. María Santa Castro N. Fetcher 《Behavioral ecology and sociobiology》1987,21(4):249-255
Summary Adult bananaquits on negative energy budgets were presented with a patch containing two flower types with identical mean rewards, but different variances. The flower patch contained a random array of 85 yellow and 85 red artificial flowers. Flowers of one color were filled with the same quantity of nectar (constant flowers); flowers of the other color were filled with variable quantities of nectar (variable flowers). In the first series of experiments the birds were given three presentations, followed by three more presentations with the flower colors reversed, to control for color preferences. Some individuals were occasionally indifferent during a presentation, but overall the birds significantly preferred the constant flowers. In the second series of experiments two birds were give five presentations of the floral patch during a day at a rate less than minimally required to meet all 24-h energy costs. In all experiments, bananaquits on negative energy budgets were either indifferent or risk-averse, but never risk-prone. The absence of risk-prone foraging might be attributed to resource dispersion pattern, reward skew, or a species characteristic. 相似文献
64.
Natalia Yoshida Mariano Castro Cecile du Mortier Alicia Fernández Cirelli 《Environmental Chemistry Letters》2007,5(3):157-160
The increase of intensive bovine production systems in Argentina involves the use of therapeutic agents and growth promoters
that reach the environment through animal excreta. The growth promoter most widely used in Argentina is monensin, an ionophore
polyether antibiotic produced by Streptomyces cinnamoniensis. Here, the behavior of monensin in different solid environmental matrices is analyzed, and preliminary results that suggest
a strong dependence of monensin retention with the organic matter content of the matrix are discussed. 相似文献
65.
A case study of molinate application in a Portuguese rice field: herbicide dissipation and proposal of a clean-up methodology 总被引:1,自引:0,他引:1
This study was designed to monitor molinate losses in surface and underground waters during Ordram application in a rice field situated in central Portugal. Water samples were collected from different sites, before, during and about one month and a half after Ordram application. Molinate quantification was based on a solid-phase microextraction (SPME) method followed by gas chromatography with flame photometric detector (GC-FPD) analysis, and led to the conclusion that the herbicide was dissipated in the environment, reaching levels as high as 3.9 microgl(-1) in underground water and 15.8 microgl(-1) in the river receiving tail waters. The feasibility of the application of treatment methodologies based on adsorption or biodegradation as processes to remove molinate from real-world waters was assessed. These methods seem suitable to reduce molinate concentrations to values in the range of the legally recommended limits (<0.5 microgl(-1)). 相似文献
66.
Valeria Marina Nurchi Costantino Floris Rosalba Pinna Núria Fiol Isabel Villaescusa 《Water environment research》2007,79(11):2363-2367
The use of biomasses that result from the agriculture and food industries in removing heavy metals from wastewaters is attracting increasing interest. We present a joined potentiometric and cross polarization magic angle spinning (CP-MAS) carbon-13 (13C) nuclear magnetic resonance (NMR) study on the interaction of olive stones with copper(II), nickel(II), and cadmium(II). The potentiometric measurements allow both to distinguish two kind of basic sites in the olive stones and to postulate the coordination models for the three studied metals. The NMR spectral analysis allows the attribution of the different signals to the components of the olive stone matrix. A comparison of CP-MAS 13C NMR spectra of the samples after metal treatment suggests a specific complexation between metal ions and hydroxyl groups on guaiacyl and syringyl moieties. 相似文献
67.
68.
Cleia Detry João Luís Cardoso Javier Heras Mora Macarena Bustamante-Álvarez Ana Maria Silva João Pimenta Isabel Fernandes Carlos Fernandes 《Die Naturwissenschaften》2018,105(11-12):63
New finds of bones of the Egyptian Mongoose (Herpestes ichneumon), one from Portugal and one from Spain, were directly 14C dated to the first century AD. While the Portuguese specimen was found without connection to the Chalcolithic occupation of the Pedra Furada cave where it was recovered, the Spanish find, collected in the city of Mérida, comes from a ritual pit that also contained three human and 40 dog burials. The finds reported here show that the Egyptian mongoose, contrary to the traditional and predominant view, did not first arrive in the Iberian Peninsula during the Muslim occupation of Iberia. Instead, our findings are consistent with the hypothesis that the species was first introduced by the Romans, or at least sometime during the Roman occupation of Hispania. Therefore, radiocarbon dating of new archaeological finds of bones of the Egyptian Mongoose (Herpestes ichneumon) in the Iberian Peninsula push back the confirmed presence of the species in the region by approximately eight centuries, as the previously oldest dated record is from the ninth century. With these new dates, there are now a total of four 14C dated specimens of Egyptian mongooses from the Iberian Peninsula, and all of these dates fall within the last 2000 years. This offers support for the hypothesis that the presence of the species in Iberia is due to historical introductions and is at odds with a scenario of natural sweepstake dispersal across the Straits of Gibraltar in the Late Pleistocene (126,000–11,700 years ago), recently proposed based on genetic data. 相似文献
69.
Summary. The capacity of benzoxazolinone metabolization of dicotyledonous species characteristic for the former vegetation classes
Secalietea (grain field weed communities) and Chenopodietea (hoed vegetable communities) was estimated by the production of
BOA-6-OH, BOA-6-β-O-glucoside, and BOA-N-glucoside. Except for Urtica urens, Galinsoga ciliata, and Polygonum aviculare (Chenopodietea), all species tested were able to synthesize BOA-6-OH, its glucoside, and BOA-N-glucoside, but effectiveness
of BOA metabolism differed highly depending on species and plant organ. There was no correlation between bacterial phenoxazinone
production and appearance of metabolites in the plants. Bioassays demonstrated that N-glucosylation is more efficient in BOA
detoxification than O-glucosylation. The intermediate BOA-6-OH, however, is more harmful than BOA itself. It is therefore
assumed that the ability to synthesize BOA-N-glucoside reduces the sensitivity to BOA strikingly. Since the detoxification
capacity did not correlate with the taxonomic position, the affiliation of the species tested with the corresponding plant
communities was taken into consideration. Evidently, the ecobiochemical potential of species to detoxify benzoxazolinone,
regarded as an essential secondary compound in rye and wheat fields, reflects their occurrence in those plant associations.
The ability to cope with the compound could be the result of co-evolutionary processes and presents a hidden aspect of allelopathic
interaction.
Received 4 January 1999; accepted 14 June 1999. 相似文献
70.
Ana P. Gomes João F. Mano João A. Queiroz Isabel C. Gouveia 《Journal of Polymers and the Environment》2012,20(4):1084-1094
The introduction of molecules with biological properties on textile materials is essential for a number of biotechnological applications. With the purpose of testing new processes applied to textiles, in this study, we present the first results on the feasibility of using the Layer-by-Layer (LbL) deposition process in natural fibers such as cotton, with natural polyelectrolytes like chitosan (CH) and alginic acid sodium salt (ALG), the durability of CH/ALG multilayer on cotton were evaluated. The increase of negative charges to the substrate cotton was made with NaBr and TEMPO, to ensure the success of the process of LbL. Three characterization methods to assess electrostatic LbL deposition were performed: the contact angle between a liquid (water) and the sample surface, in order to characterize the wettability of the samples with the different layers of CH and ALG; dyeing of the CH/ALG assembled cotton fabric with cationic methylene blue that shows regular changes in terms of color depth (K/S value), which indicate that the surface were alternately deposited with CH and ALG layers and, finally, the analysis by infrared spectroscopy using Fourier Transform with Attenuated Total Reflection (ATR-FTIR), to assess the changes in the interaction between CH and ALG deposited on cotton samples. 相似文献